A modified stratification index method to assess reservoir water quality trends.

Harmful algal blooms (HABs) have been a harm to reservoir health for decades and it is believed that as climate changes and temperatures rise, frequency and severity of HABs are likely to increase as well. Understanding the relationships between physical factors in a reservoir and bloom trends could be key for keeping rising blooms at bay. A modified stability index based on temperature dependent water density at multiple depths was adapted into a code to process high frequency reservoir monitoring data. Metrics and visual tools were developed to use this stability index to objectively analyze how stratification - including intensity, start date, and turnover point - and water quality characteristics are changing, and how they are likely to change in the coming decades. This code was then used to analyze the relationships between physical and environmental reservoir characteristics, a generated stratification index, and algal bloom behavior for several United States Army Corps of Engineers (USACE) reservoirs, with specific focus on Shenango reservoir. Surface temperature, maximum temperature difference, and depth were found to correspond with strength of stratification. The calculated stratification index showed significant strength of correlation to algae when compared to other commonly collected reservoir parameters. Bettering our understanding of when stratification is occurring within reservoirs, as well as when blooms are occurring, will lead to more informed management decisions and better HAB control. For Shenango reservoir, it was determined that a hydrodynamic management strategy that maintains stability (horizontal flushing, epilimnetic withdrawals) during peak periods, while removing epilimnetic biomass and reducing nutrient availability, would be the most practical management strategy for bloom reduction.

A critical review of operational strategies for the management of harmful algal blooms (HABs) in inland reservoirs.

Occurrences of freshwater harmful algal blooms (HABs) are increasing on a global scale, largely in part due to increased nutrient input and changing climate patterns. While reservoir management strategies that can influence phytoplankton are known, there is no published guideline or protocol for the management of harmful algal blooms. There is a need to establish what factors are the predominant drivers of blooms, and how common reservoir management strategies specifically influence each factor. The following literature review seeks to establish the benefits and drawbacks of operational management strategies that currently exist. The main focus is altering hydrodynamic conditions (hypolimnetic withdrawals, surface flushing, pulsed inflow, artificial mixing), in order to induce environmental changes within the reservoir itself. Since excess nutrients are one of the biggest contributors to worsening bloom conditions, internal nutrient dynamics and reduction are also discussed. Additionally, we review the predominant seasonal factors (stratification, light, temperature, and wind) that affect likelihood of bloom occurrence and duration. The ultimate objective of this review is to increase understanding of the relationships between HAB drivers and reservoir operations in order to inform the development of data, modeling, and management strategies for the prevention and mitigation of blooms.

Wettability hysteresis and its implications for DNAPL source zone distribution.

Subsurface heterogeneity at sites contaminated with nonaqueous phase liquids (NAPLs) reduces the effectiveness of traditional remediation measures. One cause may be the increased proportion of NAPL that is hydraulically isolated due to capillary trapping in heterogeneously-wetted materials. This study examines the wettability of ten materials, ranging from minerals, such as calcite and dolomite, to carbonaceous materials, such shale and coal, in air and water, NAPL and air, and NAPL and water systems. The wettability differed depending on which phase the solid material was initially immersed in: the less crystalline solids, if initially contacted by water were water-wet, but if initially contacted by NAPL were NAPL-wet. This difference, termed here wettability hysteresis, was observed for a suite of halogenated NAPLs and was independent of equilibration time. The degree of wettability hysteresis was greatest in the NAPL and water systems, with the magnitude of the difference increasing with the carbonaceous materials. Since the degree of capillary trapping in subsurface materials is related to wettability, the phenomenon of wettability hysteresis suggests that system history is a factor that may increase the heterogeneity of NAPL source zones.

Pilot-scale demonstration of surfactant-enhanced PCE solubilization at the Bachman Road site. 2. System operation and evaluation.

A pilot-scale demonstration of surfactant-enhanced aquifer remediation (SEAR) was conducted during the summer of 2000 at the Bachman Road site in Oscoda, MI. Part two of this two-part paper describes results from partitioning and nonpartitioning tracer tests, SEAR operations, and post-treatment monitoring. For this field test, 68 400 L of an aqueous solution of 6% (wt) Tween 80 were injected to recover tetrachloroethene-nonaqueous phase liquid (PCE-DNAPL) from a shallow, unconfined aquifer. Results of a nonreactive tracer test, conducted prior to introducing the surfactant solution, demonstrate target zone sweep and hydraulic control, confirming design-phase model predictions. Partitioning tracer test results suggest PCE-DNAPL saturations of up to 0.74% within the pilot-scale treatment zone, consistent with soil core data collected during site characterization. Analyses of effluent samples taken from the extraction well during SEAR operations indicate that a total of 19 L of PCE and 95% of the injected surfactant were recovered. Post-treatment monitoring indicated that PCE concentrations at many locations within the treated zone were reduced by as much as 2 orders of magnitude from pre-SEAR levels and had not rebounded 450 days after SEAR operations ceased. Pilot-scale costs ($365 900) compare favorably with design-phase cost estimates, with approximately 10% of total costs attributable to the intense sampling density and frequency. Results of this pilot-scale test indicate that careful design and implementation of SEAR can result in effective DNAPL mass removal and a substantial reduction in aqueous concentrations within the treated source zone under favorable geologic conditions