Your browser doesn't support javascript.
loading
Mostrar: 20 | 50 | 100
Resultados 1 - 1 de 1
Filtrar
Mais filtros

Base de dados
Ano de publicação
Tipo de documento
Intervalo de ano de publicação
1.
Artif Cells Nanomed Biotechnol ; 41(5): 344-51, 2013 Oct.
Artigo em Inglês | MEDLINE | ID: mdl-23305558

RESUMO

In this study, immobilized lipase-catalyzed esterification reaction between fructose and stearic acid was examined for the synthesis of a useful compound, fructose stearate, using response surface methodology. The increase of water content in the reaction medium was the negative effect while the increase in initial stearic acid/fructose molar ratio was the greatest positive effect on the yield. The highest fructose stearate yield was obtained as 65% in tert-butanol. The product yield was enhanced in 1-butyl-3-methylimidazolium trifluoromethanesulfonate obtained as 74% under the optimized conditions. The spectroscopic and elemental analysis methods showed that the esterification reaction is regioselective and the product is fructose monostearate.


Assuntos
Frutose/síntese química , Estearatos/síntese química , Ácidos Esteáricos/síntese química , terc-Butil Álcool/síntese química , Análise de Variância , Enzimas Imobilizadas/metabolismo , Esterificação , Imidazóis , Lipase/metabolismo , Mesilatos , Modelos Estatísticos , Estabilidade Proteica , Análise Espectral
SELEÇÃO DE REFERÊNCIAS
DETALHE DA PESQUISA