Physico-chemical characteristics and biodegradability of primary effluent and particulate matter removed by microscreens.

In this study, the physical, chemical, and biological characteristics of raw wastewater were compared with the liquid and solid streams generated by a primary clarifier (PC), a rotating belt filter (RBF, 350 µm), and a drum filter (DF, 60 µm) and series (SER) combination of an RBF with a PC or a DF using pilot-scale primary treatment units. The RBF removed about 36% of the influent total suspended solids. The DF and PC yielded an influent total suspended solid removal of 47% to 55% in both individual (parallel) and SER configurations. The size fractionation and chemical characterizations of the liquid fractions indicated a significant change in the wastewater composition in both filter configurations with no variation in the biodegradability of liquid fractions. The solids recovered by RBF had a higher total solids (TS) concentration and a higher volatile solids (VS) content (0.92 g VS/g TS) than that of DF and PC treatments (0.58 to 0.84 g VS/g TS). DF and PC sludge demonstrated a higher biodegradability rate (k1 ; 0.11 d-1 < k1 < 0.20 d-1 ) than solids recovered by RBF (0.09 d-1 ). The retained solids in the SER configuration demonstrated a significantly lower theoretical biochemical methane potential than the parallel configuration, likely due to the presence of smaller particles with a significantly higher ratio of particulate chemical oxygen demand over volatile suspended solids (1.86 to 2.40 g chemical oxygen demand/g volatile suspended solids). These results indicated that the physical, chemical, and biological characteristics of liquid and solids from different filter configurations are required to determine design criteria to upgrade or retrofit water resource recovery facilities using an RBF or a DF. PRACTITIONER POINTS: A rotating belt filter (RBF) removed less solids than a drum filter (DF) or a primary clarifier (PC). A series configuration of an RBF with either a DF or PC resulted in an effluent with a lower proportion of slowly biodegradable organic matter than in a parallel configuration. Solids from an RBF, a DF, or a PC had similar theoretical biochemical methane potential.

Combined sewer overflow treatment: Assessing chemical pre-treatment and microsieve-based filtration in enhancing the performance of UV disinfection.

Disinfection of combined sewer overflow (CSO) is necessary to reduce the amount of microorganisms discharged into surface waters. In this study, an efficient and cost-competitive treatment for CSO, employing UV disinfection, was developed. High suspended solids content in CSO poses a significant challenge for UV disinfection so laboratory experiments were carried out to asses the effect of chemical pre-treatment followed by micro-sieve filtration on the reduction of total suspended solids (TSS) and the increase of UV transmittance (UVT). The efficiency of UV, with and without pre-treatment, was investigated and a microbial inactivation model was developed to describe the fecal coliforms (FC) inactivation kinetics. Finally, the environmental impacts of the proposed treatment were simulated at the large-scale by stormwater management model (SWMM), and the cost of the proposed treatment train was evaluated and compared with current CSO treatment strategies. Experimental results showed that UV alone achieved 3.6-log reduction of FC at a UV fluence of 80 mJ/cm2, while a 4-log reduction of FC was achieved at a much lower UV fluence of 10 mJ/cm2, when the UV disinfection was preceded by chemical pre-treatment and microsieving filtration using a 32 µm mesh. Under these conditions, the TSS removal achieved was 73%, and the UVT increased from 14% to 32%.The SWMM showed that the proposed CSO treatment achieved a reduction in TSS by one order of magnitude and a decrease in number of FC from 1.05 × 1014 to 1.24 × 1010 CFU. The cost analysis performed herein suggests that the proposed treatment train is competitive to current CSO treatment strategies in terms of cost-effectiveness. The study demonstrates the potential of the innovative CSO treatment scheme to quickly and effectively treat a large amount of wastewater flow thus providing municipalities with a low footprint treatment unit for CSO.

Enhancing sludge dewaterability and phosphate removal through a novel chemical dosing strategy using ferric chloride and hydrogen peroxide.

In this study, we replicated full-scale centrifuge dewatering utilized in water resource recovery facilities (WRRFs) by using the Higgins modified centrifuge technique and demonstrated that analogous cake solid content and centrate suspended solids were attainable while applying a lower polymer dosage. Furthermore, we demonstrated a dramatic reduction in the concentration of phosphate (P) in anaerobically digested sludge (ADS) under various reaction conditions. H2 O2 was employed to convert embedded iron in ADS, in the form of FeS, to Fe (II) and Fe (III), which subsequently reacted to precipitate phosphate compounds, dropping the in situ P concentration by nearly 50%. Adding ferric chloride (220 mg/L) in ADS enhanced the P-removal to more than 80%. Finally, simultaneous dosing of Fe and H2 O2 boosted P-removal efficiency to higher than 90%. The role of Fe in strengthening the flocs and increasing the dewaterability was also substantiated by demonstrating a 2% growth in the cake solid content when ADS was conditioned with Fe + H2 O2 preceding polymer treatment. The outcome of this work confirms that a deeper understanding of centrifuge operational parameters and physico-chemical properties of wastewater sludge would result in improved performance of municipal WRRFs. PRACTITIONER POINTS: Dosing hydrogen peroxide effectively converted iron embedded in sludge from Fe (II) to Fe (III). Simultaneous dosing of iron and hydrogen peroxide boosted P removal efficiency. The role of iron in strengthening flocs and enhancing dewaterability was observed, as it increased cake solid content in centrifuged sludge. An advanced bench-scale test protocol was employed to optimize polymer dose, simultaneously reducing polymer consumption while maximizing cake solid content and centrate quality.

Performic Acid Disinfection of Municipal Secondary Effluent Wastewater: Inactivation of Murine Norovirus, Fecal Coliforms, and Enterococci.

Performic acid (PFA) is an emerging disinfectant to inactivate bacterial and viral microorganisms in wastewater. In this study, the inactivation kinetics of murine norovirus (MNV) by PFA, in phosphate buffer and municipal secondary effluent wastewater, are reported for the first time. PFA decay followed first-order kinetics and the inactivation of MNV was governed by the exposure of microorganisms to PFA, i.e., the integral of the PFA concentration over time (integral CT or ICT). The extension of the Chick-Watson model, in the ICT domain, described well the reduction of MNV by PFA, with determined ICT-based inactivation rate constants, kd, of 1.024 ± 0.038 L/(mg·min) and 0.482 ± 0.022 L/(mg·min) in phosphate buffer and wastewater, respectively, at pH 7.2. Furthermore, the simultaneous PFA inactivation of MNV and fecal indicators indigenously present in wastewater such as fecal coliforms and enterococci showed that 1-log reduction could be achieved with ICT of 2, 1.5, and 3.5 mg·min/L, respectively. When compared with the most commonly used peracid disinfectant of municipal wastewater, peracetic acid (PAA), the ICT requirements determined using the fitted ICT-based kinetic models were ∼20 times higher for PAA than PFA, indicating a much stronger inactivation power of the PFA molecule.

Inactivation of Murine Norovirus and Fecal Coliforms by Ferrate(VI) in Secondary Effluent Wastewater.

Ferrate(VI) (FeVIO42, Fe(VI)) is an emerging oxidant/disinfectant to treat a wide range of contaminants and microbial pollutants in wastewater. This study describes the inactivation of murine norovirus (MNV) by Fe(VI) in phosphate buffer (PB) and secondary effluent wastewater (SEW). The decay of Fe(VI) had second-order kinetics in PB while Fe(VI) underwent an initial demand followed by first-order decay kinetics in SEW. The Chick-Watson inactivation kinetic model, based on integral CT (ICT) dose, well fitted the inactivation of MNV in both PB and SEW. In PB, the values of the inactivation rate constant (kd) decreased with an increase in pH, which was related to the reaction of protonated Fe(VI) species (HFeO4-) with MNV. Higher kd was observed in SEW than in PB. The inactivation of indigenous fecal coliforms (FC) in SEW was also measured. A two-population double-exponential model that accounted for both dispersed and particle-associated FC well fitted the inactivation data with determined kd and particle-associated inactivation rate constant (kp). Results show that Fe(VI) was more effective in inactivating dispersed FC than MNV. The MNV inactivation results obtained herein, coupled with the detailed modeling, provide important information in designing an Fe(VI) wastewater disinfection process.

A microsieve-based filtration process for combined sewer overflow treatment with nutrient control: Modeling and experimental studies.

Combined sewer overflows contain a highly variable, wide range of contaminants, both in particulate and soluble form, making conventional water treatment processes unable to offer adequate public health protection. In this study, an integrated treatment process designed to simultaneously remove typical combined sewer overflow pollutants (suspended solids, chemical oxygen depends, turbidity) in conjunction with nutrient (nitrogen and phosphorus), was developed. The removal of particulates as well as dissolved nitrogen and phosphorus was achieved by first adsorbing soluble pollutants on zeolite and powdered activated carbon, and subsequently applying filtration carried out by polymer-enhanced microsieving. Laboratory experiments were designed using design-of-experiment techniques and carried out to assess the effects of the various treatment variables (cationic polymer, zeolite, powder activated carbon and microsieve size) in the designed combinations. A response surface model was fitted to the experimental dataset in order to capture and describe the non-linear relationships between treatment variables and treatment objectives. Finally, an optimization study was carried out using Pareto analysis showing that cationic polymer, zeolite, and powdered activated carbon, followed by fine mesh microsieving, worked synergistically in the integrated treatment process. Several optimal process conditions emerged, in particular, a treatment combination consisting of 1.1 mg/L of the cationic polymer, 250 mg/L of zeolite, 5 mg/L of powdered activated carbon, and a 370 µm mesh size. Under this condition, expected performance would be reductions of 72%, 56%, 35%, and 75% for turbidity, total Kjeldahl nitrogen, total chemical oxygen demand, and total phosphorous, respectively. The findings presented in this paper demonstrate the possibility of achieving multiple treatment objectives in a single and integrated treatment step, hence providing municipalities with viable treatment options where the issues of combined sewer overflow and nutrient management are simultaneously tackled.

Inactivation kinetics of antibiotic resistant Escherichia coli in secondary wastewater effluents by peracetic and performic acids.

While disinfection processes have been central for public health protection, new concerns have been raised with respect to their ability to control the spread of antibiotic resistance in the environment. In this study, we report the inactivation kinetics by peracetic and performic acids of a typical indicator, Escherichia coli and its corresponding antibiotic-resistant subpopulation, in secondary settled wastewater effluent. Performic acid always showed greater inactivation efficiency than peracetic acid, whether or not the indicator was Ampicillin-resistant. Observed inactivation data, fitted with an exposure-based inactivation model, predicted very well the inactivation profile of both total and ampicillin resistant Escherichia coli. Notably, the antibiotic resistance percentage decreased significantly in treated wastewater compared to untreated wastewater thus making the peracid-based disinfection processes beneficial in controlling antibiotic resistance in secondary settled wastewater. Moreover, the minimum inhibitory concentration values remained unchanged. Finally, antibiotic-resistant-specific inactivation kinetics were used to predict the disinfection efficiency in continuous-flow reactors under ideal and non-ideal hydraulics thus providing useful information for future design and operation of disinfection process in antibiotic-resistance controlling mode.

Detailed modeling and advanced control for chemical disinfection of secondary effluent wastewater by peracetic acid.

Advanced control of chemical disinfection processes is becoming increasingly important in view of balancing under-treatment (low pathogen inactivation) and over-treatment (excessive consumption of disinfectant and disinfection byproducts formation) thereby providing considerable environmental and economic benefits. Conventional control strategies such as flow pacing or residual trim ignore chemical demand/decay, inactivation kinetics, and other factors governing disinfection performance in continuous-flow reactors such as reactor hydraulics and process variability. This study presents the development, verification, and pilot-scale validation of a novel CT-based real-time disinfection control strategy, derived from first principles, and applied to peracetic acid disinfection of municipal secondary effluent wastewater. Validation experiments were carried out using a 3-m3 pilot contact basin of which the hydraulic performance was first characterized by means of tracer tests and then mathematically modeled using the well-established theoretical framework of continuous stirred-tank reactors in series. The analytical model describing hydraulic performance was subsequently extended to take into account disinfectant demand/decay and microbial inactivation kinetics. The integrated model was successfully used to predict, and control, residual peracetic acid as well as microbial concentration in the pilot effluent. Validation studies conclusively supported that the novel CT-based control strategy was superior in maintaining constant disinfection performance, desired microbial counts, and low residual disinfectant under variable flow and wastewater quality. When compared with flow pacing, the CT-based control required two times less the amount of chemical for the same treatment objective (<100 cfu/100 mL). Remarkably, the CT-based control strategy could be extended to other chemical disinfection processes such as chlorination and ozonation, alone or in combination with physical treatment technologies such as membranes and ultraviolet irradiation.

Effects of total suspended solids, particle size, and effluent temperature on the kinetics of peracetic acid decomposition in municipal wastewater.

In this study, the influence of total suspended solids (TSS) and particle size as well as effluent temperature on peracetic acid (PAA) decomposition kinetics in municipal wastewater was investigated. PAA decomposition was best described following second order kinetics in primary effluent (PE) and first order kinetics in secondary effluent (SE) samples. For synthetic samples prepared by varying TSS levels, PAA demand increased on average by about 0.042 mg/L in PE and 0.034 mg/L in SE for every 10 mg/L increase in TSS. Similarly, the PAA decay rate constant in these samples increased at a rate of 0.0014 L/mg.min and 0.00039 min-1, respectively, per 10 mg/L TSS. To examine the effect of particle size, synthetic samples with narrow size fractions (20-45, 45-75, and 75-90 µm) were prepared. It was found that samples with smaller particle size fractions had a greater PAA demand and decay rate constant. Effluent temperature also enhanced the PAA decomposition rate with the calculated activation energies for PE and SE samples being 29,980 J/mol and 34,860 J/mol, respectively.

Low-temperature thermal pre-treatment of municipal wastewater sludge: Process optimization and effects on solubilization and anaerobic degradation.

The present study examines the relationship between the degree of solubilization and biodegradability of wastewater sludge in anaerobic digestion as a result of low-temperature thermal pre-treatment. The main effect of thermal pre-treatment is the disintegration of cell membranes and thus solubilization of organic compounds. There is an established correlation between chemical oxygen demand (COD) solubilization and temperature of thermal pre-treatment, but results of thermal pre-treatment in terms of biodegradability are not well understood. Aiming to determine the impact of low temperature treatments on biogas production, the thermal pre-treatment process was first optimized based on an experimental design study on waste activated sludge in batch mode. The optimum temperature, reaction time and pH of the process were determined to be 80 °C, 5 h and pH 10, respectively. All three factors had a strong individual effect (p < 0.001), with a significant interaction effect for temp. pH2 (p = 0.002). Thermal pre-treatments, carried out on seven different municipal wastewater sludges at the above optimum operating conditions, produced increased COD solubilization of 18.3 ± 7.5% and VSS reduction of 27.7 ± 12.3% compared to the untreated sludges. The solubilization of proteins was significantly higher than carbohydrates. Methane produced in biochemical methane potential (BMP) tests, indicated initial higher rates (p = 0.0013) for the thermally treated samples (khyd up to 5 times higher), although the ultimate methane yields were not significantly affected by the treatment.

Effects of UV/H(2)O(2) advanced oxidation on chemical characteristics and chlorine reactivity of surface water natural organic matter.

The advanced oxidation process utilizing ultraviolet and hydrogen peroxide (UV/H(2)O(2)) is currently applied in commercial drinking water applications for the removal of various organic pollutants. Natural organic matter (NOM) present in the source water can also be oxidized and undergo changes at the fluence and H(2)O(2) concentrations applied in commercial drinking water UV/H(2)O(2) applications (fluences less than 2000 mJ cm(-2), initial H(2)O(2) concentrations less than 15 mg L(-1)). In this study, the impact of UV/H(2)O(2) on NOM's aromaticity, hydrophobicity, and potential to form trihalomethanes (THMs) and haloacetic acids (HAAs) was investigated for raw surface water and the same water with the very hydrophobic acid (VHA) fraction of NOM removed. During UV/H(2)O(2) treatments, NOM in the raw surface water was partially oxidized to less aromatic and hydrophobic characteristics, but was not mineralized, confirming findings from past research. Below fluences of 1500 mJ cm(-2) UV/H(2)O(2) treatment of the raw water did not lead to reduction in the formation potential of THMs. The formation potential of HAAs was reduced at a fluence of 500 mJ cm(-2) with only small additional reductions as fluence further increased. For the water from which the VHA fraction was removed, UV/H(2)O(2) treatment led to mineralization of NOM suggesting that, when coupled with a pre-treatment capable of removing the VHA fraction, UV/H(2)O(2) could achieve further reductions in NOM. These subsequent reductions in NOM led to continuous reductions in the formation potentials of THMs and HAAs as fluence increased.

The impact of UV/H2O2 advanced oxidation on molecular size distribution of chromophoric natural organic matter.

The impact of hydroxyl radical (*OH) on the molecular weight distribution of natural organic matter (NOM) was investigated. *OH was generated via the photolysis of hydrogen peroxide (H2O2) by ultraviolet (UV) radiation of 254 nm, also known as UV/ H2O2 advanced oxidation (AO). Additionally, the impact of combined membrane and UV/H2O2 treatment on the molecular weight distribution of NOM was studied. High performance size exclusion chromatography (HPSEC) was used to determine the apparent molecular weight (AMW) distribution of chromophoric NOM (CNOM). Prior to AO, 33% of the CNOM in the water had AMW greater than 1400 Da. Meanwhile, lower AMW CNOM made up smaller amounts of the CNOM, with CNOM of AMW less than 450 Da making up 5% of the total. Under the AO conditions typically applied in drinking water treatment applications, NOM was not mineralized but was partially oxidized resulting in significant reduction in aromaticity. *OH preferentially reacted with higher AMW CNOM and the fragmentation of high AMW CNOM led to the formation of smaller AMW CNOM. Ultrafiltration removed all CNOM greater than 1400 Da AMW and a large portion of other high AMW fractions. In the absence of high AMW CNOM, *OH reacted more readily with all AMW fractions leading to a reduction in concentration of most AMW fractions. Whereas *OH reacted nonspecifically with all AMW fractions, the reaction rate between *OH and CNOM was observed to be dependent on molecular size.