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Detailed measurements of the in-plane resistivity were performed in a high-quality Ba([Formula: see text])[Formula: see text] ([Formula: see text]) single crystal, in magnetic fields up to 9 T and with different orientations [Formula: see text] relative to the crystal c axis. A significant [Formula: see text] rounding is observed just above the superconducting critical temperature [Formula: see text] due to Cooper pairs created by superconducting fluctuations. These data are analyzed in terms of a generalization of the Aslamazov-Larkin approach, that extends its applicability to high reduced-temperatures and magnetic fields. This method allows us to carry out a criterion-independent determination of the angular dependence of the upper critical field, [Formula: see text]. In spite of the relatively small anisotropy of this compound, it is found that [Formula: see text] presents a significant deviation from the single-band 3D anisotropic Ginzburg-Landau (3D-aGL) approach, particularly for large [Formula: see text] (typically above [Formula: see text]). These results are interpreted in terms of the multiband nature of these materials, in contrast with other proposals for similar [Formula: see text] anomalies. Our results are also consistent with an effective anisotropy factor almost temperature independent near [Formula: see text], a result that differs from the ones obtained by using a single-band model.
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Recent superconducting transition temperatures (T c) over 100 K for monolayer FeSe on SrTiO3 have renewed interest in the bulk parent compound. In KCl:AlCl3 flux-transport-grown crystals of FeSe0.94Be0.06, FeSe0.97Be0.03 and, for comparison, FeSe, this work reports doping of FeSe using Be-among the smallest of possible dopants, corresponding to an effective 'chemical pressure'. According to lattice parameter measurements, 6% Be doping shrank the tetragonal FeSe lattice equivalent to a physical pressure of 0.75 GPa. Using this flux-transport method of sample preparation, 6% of Be was the maximum amount of dopant achievable. At this maximal composition of FeSe0.94Be0.06, the lattice unit cell shrinks by 2.4%, T c-measured in the bulk via specific heat-increases by almost 10%, the T c versus pressure behavior shifts its peak [Formula: see text] downwards by ~1 GPa, the high temperature structural transition around T S = 89 K increases by 1.9 K (in contrast to other dopants in FeSe which uniformly depress T S), and the low temperature specific heat γ increases by 10% compared to pure FeSe. Also, upon doping by 6% Be the residual resistivity ratio, ρ(300 K)/ρ(T â 0), increases by almost a factor of four, while ρ(300 K)/ρ([Formula: see text]) increases by 50%.
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Quantum materials such as antiferromagnets or superconductors are complex in that chemical, electronic, and spin phenomena at atomic scales can manifest in their collective properties. Although there are some clues for designing such materials, they remain mainly unpredictable. In this work, we find that enhancement of transition temperatures in BaFe2As2-based crystals are caused by removing local-lattice strain and electronic-structure disorder by thermal annealing. While annealing improves Néel-ordering temperature in BaFe2As2 crystal (T N = 132 K to 136 K) by improving in-plane electronic defects and reducing overall a-lattice parameter, it increases superconducting-ordering temperature in optimally cobalt-doped BaFe2As2 crystal (T c = 23 to 25 K) by precipitating-out the cobalt dopants and giving larger overall a-lattice parameter. While annealing improves local chemical and electronic uniformity resulting in higher T N in the parent, it promotes nanoscale phase separation in the superconductor resulting in lower disparity and strong superconducting band gaps in the dominant crystal regions, which lead to both higher overall T c and critical-current-density, J c .
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Combined scanning tunneling microscopy, spectroscopy, and local barrier height (LBH) studies show that low-temperature-cleaved optimally doped Ba(Fe1-xCox)2As2 crystals with x = 0.06, with Tc = 22 K, have complicated morphologies. Although the cleavage surface and hence the morphologies are variable, the superconducting gap maps show the same gap widths and nanometer size inhomogeneities irrelevant to the morphology. Based on the spectroscopy and LBH maps, the bright patches and dark stripes in the morphologies are identified as Ba- and As-dominated surface terminations, respectively. Magnetic impurities, possibly due to Co or Fe atoms, are believed to create local in-gap state and, in addition, suppress the superconducting coherence peaks. This study will clarify the confusion on the cleavage surface terminations of the Fe-based superconductors and its relation with the electronic structures.
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We report a giant, â¼22%, electroresistance modulation for a metallic alloy above room temperature. It is achieved by a small electric field of 2 kV/cm via piezoelectric strain-mediated magnetoelectric coupling and the resulting magnetic phase transition in epitaxial FeRh/BaTiO_{3} heterostructures. This work presents detailed experimental evidence for an isothermal magnetic phase transition driven by tetragonality modulation in FeRh thin films, which is in contrast to the large volume expansion in the conventional temperature-driven magnetic phase transition in FeRh. Moreover, all the experimental results in this work illustrate FeRh as a mixed-phase model system well similar to phase-separated colossal magnetoresistance systems with phase instability therein.
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Fermi-surface topology governs the relationship between magnetism and superconductivity in iron-based materials. Using low-temperature transport, angle-resolved photoemission, and x-ray diffraction, we show unambiguous evidence of large Fermi-surface reconstruction in CaFe2As2 at magnetic spin-density-wave and nonmagnetic collapsed-tetragonal (cT) transitions. For the cT transition, the change in the Fermi-surface topology has a different character with no contribution from the hole part of the Fermi surface. In addition, the results suggest that the pressure effect in CaFe2As2 is mainly leading to a rigid-band-like change of the valence electronic structure. We discuss these results and their implications for magnetism and superconductivity in this material.
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We used angle-resolved photoemission spectroscopy to investigate the electronic structure and the Fermi surface of EuFe2As2, EuFe2As1.4P0.6 and EuFe2P2. We observed doubled core level peaks associated with the pnictide atoms. Using K atoms evaporated at the surface to affect the surface quality, we show that one component of these doubled peaks is related to a surface state. Nevertheless, strong electronic dispersion along the c-axis, especially pronounced in EuFe2P2, is observed for at least one band, thus indicating that the Fe states, albeit probably affected at the surface, do not form pure two-dimensional surface states. We determine the evolution of the Fermi surface as a function of the P content and reveal that the hole Fermi surface pockets enlarge with increasing P content. We also show that the spectral weight near the Fermi level of EuFe2P2 is reduced as compared to that of EuFe2As2 and EuFe2As1.4P0.6. Finally, we identify the electronic states associated with the Eu(2+) f states and show an anomalous jump in EuFe2P2.
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We report on the infrared studies of the interlayer charge dynamics of a prototypical pnictide superconductor Ba(Fe(0.926)Co(0.074))(2)As(2). We succeeded in probing the intrinsic interlayer response by performing infrared experiments on the crystals with a cleaved ac surface. Our experiments identify the coexistence of the suppression of the electronic spectral weight and the development of a coherent Drude-like response in the normal state. The formation of the interlayer condensate is clearly observed in the superconducting state and appears to be linked to coherent contribution to the normal-state conductivity.
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We report on infrared studies of charge dynamics in a prototypical pnictide system: the BaFe2As2 family. Our experiments have identified hallmarks of the pseudogap state in the BaFe2As2 system that mirror the spectroscopic manifestations of the pseudogap in the cuprates. The magnitude of the infrared pseudogap is in accord with that of the spin-density-wave gap of the parent compound. By monitoring the superconducting gap of both P- and Co-doped compounds, we find that the infrared pseudogap is unrelated to superconductivity. The appearance of the pseudogap is found to correlate with the evolution of the antiferromagnetic fluctuations associated with the spin-density-wave instability. The strong-coupling analysis of infrared data further reveals the interdependence between the magnetism and the pseudogap in the iron pnictides.
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We report an infrared optical study of the pnictide high-temperature superconductor BaFe(1.84)Co(0.16)As(2) and its parent compound BaFe(2)As(2). We demonstrate that electronic correlations are moderately strong and do not change across the spin-density wave transition or with doping. By examining the energy scale and direction of spectral weight transfer, we argue that Hund's coupling J is the primary mechanism that gives rise to correlations.
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We report neutron scattering experiments probing the influence of uniaxial strain on both the magnetic and structural order parameters in the parent iron pnictide compound, BaFe2As2. Our data show that modest strain fields along the in-plane orthorhombic b axis can affect significant changes in phase behavior simultaneous to the removal of structural twinning effects. As a result, we demonstrate in BaFe2As2 samples detwinned via uniaxial strain that the in-plane C4 symmetry is broken by both the structural lattice distortion and long-range spin ordering at temperatures far above the nominal (strain-free) phase transition temperatures. Surprising changes in the magnetic order parameter of this system under relatively small strain fields also suggest the inherent presence of magnetic domains fluctuating above the strain-free ordering temperature in this material.
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We report a (75)As single crystal NMR investigation of LaFeAsO, the parent phase of a pnictide high T(c) superconductor. We demonstrate that spin dynamics develop a strong twofold anisotropy within each orthorhombic domain below the tetragonal-orthorhombic structural phase transition at T(TO) ≈ 156 K. This intermediate state with a dynamical breaking of the rotational symmetry freezes progressively into a spin density wave below T(SDW) ≈ 142 K. Our findings are consistent with the presence of a spin nematic state below T(TO) with an incipient magnetic order.
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It is shown that attempts to accurately deduce the magnetic penetration depth λ of overdoped BaFe(1.82)Co(0.18)As2 single crystals by transverse-field muon spin rotation (TF µSR) are thwarted by field-induced magnetic order and strong vortex-lattice disorder. We explain how substantial deviations from the magnetic field distribution of a nearly perfect vortex lattice by one or both of these factors is also significant for other iron-arsenic superconductors, and this introduces considerable uncertainty in the values of λ obtained by TF µSR.
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We report the first NMR investigation of spin dynamics in the overdoped nonsuperconducting regime of Ba(Fe1-xCox)2As2 up to x=0.26. We demonstrate that the absence of interband transitions with large momentum transfer Q{AF} approximately (pi/a,0) between the hole and electron Fermi surfaces results in complete suppression of antiferromagnetic spin fluctuations for x greater than or approximately 0.15. Our experimental results provide direct evidence for a correlation between T{c} and the strength of Q{AF} antiferromagnetic spin fluctuations.
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We demonstrate that the changes in the elastic properties of the FeAs systems, as seen in our resonant ultrasound spectroscopy data, can be naturally understood in terms of fluctuations of emerging nematic degrees of freedom. Both the softening of the lattice in the normal, tetragonal phase as well as its hardening in the superconducting phase are consistently described by our model. Our results confirm the view that structural order is induced by magnetic fluctuations.
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BaFe2As2 exhibits properties that are characteristic of the parent compounds of the newly discovered iron (Fe)-based high-T(C) superconductors. By combining real-space imaging of scanning tunneling microscopy and spectroscopy (STM+STS) with momentum-space quantitative low-energy electron diffraction (LEED), we have identified the surface plane of cleaved BaFe2As2 crystals as the As terminated Fe-As layer-the plane where superconductivity occurs. LEED and STM+STS data on the BaFe2As2(001) surface indicate an ordered arsenic (As) terminated metallic surface without reconstruction or lattice distortion. It is surprising that STM images the different Fe-As orbitals associated with the orthorhombic structure, but not the As atoms in the surface plane.
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We report neutron scattering measurements on single crystals of BaFe1.92Co0.08As2. The magnetic Bragg peak intensity is reduced by 6% upon cooling through TC. The spin dynamics exhibit a gap of 8 meV with anisotropic three-dimensional interactions. Below TC additional intensity appears at an energy of approximately 4.5(0.5) meV, similar to previous observations of a spin resonance in other Fe-based superconductors. No further gapping of the spin excitations is observed below TC for energies down to 2 meV. These observations suggest the redistribution of spectral weight from the magnetic Bragg position to a spin resonance, demonstrating the direct competition between static magnetic order and superconductivity.
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Inelastic neutron scattering measurements on single crystals of superconducting BaFe1.84Co0.16As2 reveal a magnetic excitation located at wave vectors (1/2 1/2 L) in tetragonal notation. On cooling below T_{C}, a clear resonance peak is observed at this wave vector with an energy of 8.6(0.5) meV, corresponding to 4.5(0.3) k_{B}T_{C}. This is in good agreement with the canonical value of 5 k_{B}T_{C} observed in the cuprates. The spectrum shows strong dispersion in the tetragonal plane but very weak dispersion along the c axis, indicating that the magnetic fluctuations are two dimensional in nature. This is in sharp contrast to the anisotropic three dimensional spin excitations seen in the undoped parent compounds.
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The electronic structure in the normal state of CeFeAsO0.89F0.11 oxypnictide superconductors has been investigated with x-ray absorption and photoemission spectroscopy. All of the data exhibit signatures of Fe d-electron itinerancy. Exchange multiplets appearing in the Fe 3s core level indicate the presence of itinerant spin fluctuations. These findings suggest that the underlying physics and the origin of superconductivity in these materials are likely to be quite different from those of the cuprate high-temperature superconductors. These materials provide opportunities for elucidating the role of magnetic fluctuations in high-temperature superconductivity.