Model analysis on effect of temperature on the solubility of recycling of Polyethylene Terephthalate (PET) plastic.

The massive increase in the use of PET plastic bottles has raised the challenge of accumulated waste plastics disposal and its related environmental concerns. Reusing this plastic waste through a solvent-based recycling process seems to be an eco-friendly solution for eliminating waste plastic and converting them into high quality products. The selection of solvent with its temperature requirement for the dissolution of polymeric materials is crucial in the solvent-based recycling process. Therefore, an innovative MATLAB program named HSPs-TPT was designed and constructed in this work to evaluate the dissolving power of solvents. Through this program, the solubility of the waste PET polymer was examined in thirteen (13) different solvents at different temperatures. As a results, the degree of waste PET polymer dissolution in the solvents was presented as the polymer-solvent solubility diagram, which provided the information about the relative energy difference (RED) change with the temperature rise. The program also provided the temperature range effective for the dissolution of PET by indicating the minimum and maximum solubility point for each solvent, which was further validated by the experimental data found in the literature. The proposed MATLAB program can numerically analyse the solubility of a polymer in different solvents in a short time for the recycling process and fabrication of different value-added plastic products such as polymer monoliths and membrane filters.

Challenges and issues with the performance of boron nitride rooted membrane for gas separation.

Various fillers such as zeolites, metal-organic framework, carbon, metal framework, graphene, and covalent organic framework have been incorporated into the polymers. However, these materials are facing issues such as incompatibility with the polymer matrix, which leads to the formation of non-selective voids and thus, reduces the gas separation properties. Recent studies show that hexagonal boron nitride (h-BN) possesses attractive characteristics such as high aspect ratio, good compatibility with polymer materials, enhanced gas barrier performance, and improved mechanical properties, which could make h-BN the potential candidate to replace conventional fillers. The synthesis of materials and membranes is the subject of this review, which focuses on recent developments and ongoing problems. Additionally, a summary of the mathematical models that were utilised to forecast how well polymer composites would perform in gas separation is provided. It was found in the previous studies that tortuosity is the governing factor for the determination of the effectiveness of a nanofiller as a gas barrier enhancer in polymer matrices. The shape of the nanofiller particles and sheets, disorientation and distribution of the nanofillers within the polymer matrix, state of aggregation and rate of reaggregation of the nanofiller particles, as well as the compatibility of the nanofiller with the polymer matrix all played a significant role in determining how well a particular nanofiller will perform in enhancing the gas barrier properties of the nanocomposites. For this purpose, this review has been focused not only on the experimentation work but also on the effect of tortuosity, exfoliation quality, compatibility, disorientation, and reaggregation of nanofillers.