Electromagnetic and optical responses of a composite material comprising individual single-walled carbon-nanotubes with a polymer coating.

The composites and thin films comprising individual single-walled carbon nanotubes with a polymer coating (p-CNTs) have been prepared and their electromagnetic responses have been studied in a wide range from low-frequency (25-107 Hz) up to the infrared region. In spite of the high volume fraction of the nanotubes (up to 3.3%), the polymer coating prevents direct p-CNT contacts and the formation of the percolation network in those composites, so that p-CNTs interact only via the electromagnetic coupling. Thereby it is an ideal model system to verify experimentally the fundamental issues related to carbon nanotube electromagnetics, such as the influence of inter-tube electron tunneling on the localized plasmon resonance in the terahertz range, or the infrared absorption enhancement of polymer molecules attached to the nanotube surface. Along with addressing the fundamentals, applied carbon nanotube electromagnetics got insights important for the applications of p-CNT based composites as dielectric media in the terahertz regime. In particular, we found that the real part of the permittivity of the p-CNT film in the terahertz range is rather competitive, i.e. 8-13, however the loss tangent is not so small (0.4-0.6) as has been predicted. The way to increase p-CNT terahertz performance is also discussed.

Splitting of absorptance peaks in absorbing multilayer backed by a periodically corrugated metallic reflector.

The excitation of modes of an open-face slab waveguide by light incident on a thin-film photovoltaic solar cell with a periodically corrugated metal backreflector is indicated by peaks in the absorptance spectrum. An absorptance peak due to the excitation of a waveguide mode (WGM) can split as the corrugation depth increases. The splitting can be explained in terms of the wavenumbers of the WGMs of two open-face slab waveguides with different thicknesses of the semiconductor layer. The splitting of short-wavelength peaks occurs for smaller corrugation depths than the splitting of long-wavelength peaks, suggesting that the corrugations need not be very deep for optimal absorption of solar photons.

Adequacy of the rigorous coupled-wave approach for thin-film silicon solar cells with periodically corrugated metallic backreflectors: spectral analysis.

The rigorous coupled-wave approach (RCWA) is extensively used to compute optical absorption and photon absorption in thin-film photovoltaic solar cells backed by 1D metallic gratings when the wave vector of the incident light lies wholly in the grating plane. The RCWA algorithm converges rapidly for incident s-polarized light over the entire 400-1100 nm solar spectrum. It also performs well for incident p-polarized light in the 400-650 nm spectral regime, but even with a large number of Floquet harmonics in the solution, the total reflectance is underestimated in the 650-1100 nm spectral regime. Despite that shortcoming, the RCWA underestimates the solar-spectrum-integrated photon absorption rate only by 5%-10% for p-polarized light. As sunlight is almost unpolarized, the RCWA should be considered adequate to design thin-film silicon solar cells with periodically corrugated metallic backreflectors.

The effect of sample holder geometry on electromagnetic heating of nanoparticle and NaCl solutions at 13.56 MHz.

Electromagnetic absorption and subsequent heating of nanoparticle solutions and simple NaCl ionic solutions is examined for biomedical applications in the radiofrequency range at 13.56 MHz. It is shown via both theory and experiment that for in vitro measurements the shape of the solution container plays a major role in absorption and heating.