Modified mesoporous silica derived from bamboo leaf using cetyltrimethylammonium bromide and 3-aminopropyl triethoxysilane as CO2 adsorbent in biogas purification.

The calorific value of post-fermentation biogas is a way down below standard and quite low due to the presence of high amount level of carbon dioxide (CO2) biogas mixture. Therefore, it raises the need to process the biogas, separating it from CO2 in order to obtain high-purity biogas as well as to maximize its calorific value. One widely available material that can be used as a sustainable carbon capture adsorbent is silica extracted from bamboo leaves. However, so that silica can act as CO2 adsorber, it is necessary to modify the surface of silica with CTAB and APTES (3-aminopropyl triethoxysilane). In this study, 2-stage method was carried out, namely preparation of mesoporous silica and surface modification using APTES on the mesoporous silica. Experiments in synthesizing APTES-modified silica were obtained by varying its composition: CTAB (1.5-5%w), (HCl 1.5-5 N), and APTES (10-30%). A central composite design (CCD) was employed in exploring the interaction between all variables and also performed for the optimization. Through analysis of variance, it shows that optimum CO2 adsorption capacity reaches 47.02 mg g-1, by applying 4.98% of CTAB, 4.28 N of HCl and 10.08% of APTES. Pseudo-second-order kinetic and Redlich-Peterson isotherm models are more representative to show the adsorption behavior of CO2 into the modified silica. The results show that the modified silica with APTES shows a prospective application of silica for CO2 removal from biogas.

Correction to "Optimization of the Sound Absorption Coefficient (SAC) from Cellulose-Silica Aerogel Using the Box-Behnken Design".

[This corrects the article DOI: 10.1021/acsomega.2c03734.].

Optimization of the Sound Absorption Coefficient (SAC) from Cellulose-Silica Aerogel Using the Box-Behnken Design.

Noise pollution, which has become a major environmental issue in urban areas, can be minimized using acoustic insulation derived from cellulose-silica aerogel. The raw materials required in the process include waste newspaper-based cellulose, geothermal silica, and NaOH/ZnO solution. Therefore, this study investigates the effect of cellulose, silica, and ZnO concentrations on optimizing the sound absorption coefficient (SAC) using the Box-Behnken design (BBD). The results showed that the optimum conditions were obtained at 39.8578 wt % cellulose, 16.5428 wt % silica, and 0.5684 wt % ZnO. The impedance test for the cellulose aerogel and cellulose-silica aerogel showed SAC values of 0.59 and 0.70, respectively, and were characterized by XRD, FTIR, BET-BJH, SEM-EDX, and TG. The results of XRD and FTIR data indicate that the product was cellulose-silica aerogel, and the SEM micrographs showed that silica particles were attached to the fiber surface. Furthermore, type IV isotherms were observed in the cellulose-silica aerogel, typical of mesoporous materials. The presence of silica strengthened the aerogel structure, improved its thermal stability, and increased the surface area but decreased its pore size.