Ligand-engineering Cu-based catalysts to accelerate the electrochemical reduction of CO2.

Two typical Cu-based complex catalysts with piperazine (PR) and p-phenylenediamine (pPDA) ligands were designed to elucidate whether the ligands can tailor the reduction behavior of the Cu species and thus modulate their electrochemical CO2 reduction reaction (eCO2RR) activity. Specifically, Cu-PR underwent a significant in situ transformation into Cu nanoparticles enriched with a Cuδ+/Cu0 interface for high eCO2RR activity, compared to Cu-pPDA. This finding reveals the importance of ligand engineering in modulating the eCO2RR performance of Cu-based complexes.

Enhanced tetracycline removal using membrane-like air-cathode with high flux and anti-fouling performance in flow-through electro-filtration system.

The membrane-like air-cathodes modified with different polyaniline were prepared using phase inversion method, which possessed dual functions of interception and electrochemical degradation, and showed good conductivity (15.9 ± 0.4 to 25.7 ± 0.5 mS cm-1) and porosity (77.0 ± 0.1 to 87.8 ± 0.1%) compared to the unmodified control one (13.2 ± 0.5 mS cm-1, and 63.1 ± 0.7%). At tetracycline 50 mg L-1, the cathode with 25 wt% polyaniline exhibited the highest rejection rate and final removal (71.1% and 92.9%, 35.9% and 31.4% higher than the control), the highest water flux recovery (97.9%), and the lowest attenuation of porosity and conductivity. The modified cathode also showed an autocatalytic effect on H2O2, an obvious ·OH peak appeared on the electron paramagnetic resonance curves. It also had good anti-fouling performance because it exhibited a high durability (the final removal was decreased by 4.0% after 15 cycles) with a long service life of 124 periods (372 h, 15.5 d). The tetracycline (0.5 mg L-1) removal in the river background was near 100%, and the chemical oxygen demand removal was 91.9%, supporting that it was suitable for treating antibiotics in natural water without adding agents but only for electricity consumption.

A figure of merits-based performance comparison of various advanced functional nanomaterials for adsorptive removal of gaseous ammonia.

The implementation of sustainable industrial development based on energy/cost-effective techniques with zero/low rate of pollutant emission is an ideal strategy for the proper management of a natural environment. Gaseous ammonia released from a variety of anthropogenic sources (e.g., agriculture, pharmaceuticals, commercial cleaning products, and refrigerant) is estimated to be as high as 150 million tons∙year-1. To reduce the negative effects of atmospheric ammonia, the great utility of advanced functional nanomaterials (e.g., metal organic frameworks, covalent organic polymers, metal/metal oxide nanoparticles, and carbon nanostructures) has been recognized. To gain a better understanding of the sorptive removal potential of diverse materials, their performance has been evaluated based on the key performance merits (e.g., initial concentration, sorption capacity, and partition coefficient). Generally, the PC values can be applied to significantly estimate the contaminant adsorption potential of NMs via balancing the biased influences of operating parameters (e.g., initial concentration of pollutants) as perceived for the partitioning of compounds between aqueous phases at equilibrium (e.g., Henry's Law). Therefore, in this work, we have proposed the PC as a prosperous performance merit (in terms of heterogeneity of surface and strength of adsorption process) for the selection of high performance nano-adsorbents for gaseous ammonia. Moreover, the water stability, recyclability, economic aspects, and future perspectives have also been discussed for real-world applications of advanced nanomaterial against gaseous ammonia adsorption. The outcome of this evaluation will be expedient for the classification/selection of the most effectual and cost-effective options for mitigation of environmental pollutants like gaseous ammonia.

Enhanced electricity generation and tetracycline removal of bioelectro-Fenton with electroactive biofilm induced by multi external resistance.

A simple multi electric resistance mode is used to regulate electroactive anode film, which improves the electricity generation, H2O2 production and pollutants removal. This external electron transport path (double cathode with different resistance) exhibits higher H2O2 production (571.9 ± 0.1 mg m-2 h-1), tetracycline removal (71.4 ± 0.4% to 50 mg L-1), and power (615.3 ± 9.9 mW m-2 plus 680.6 ± 10.3 mW m-2), which is 75.4%, 23.1% and 1.25 times higher than that of single cathode mode. The double cathode improves the relative abundance of Geobacter (exoelectrogens), which is 9.45 times higher than that of single cathode mode. The anodic capacitance of double cathode mode is more than 10 times higher than that of single cathode mode. Electrons (generate by exoelectrogens) participate in two- (cathodic chamber) and four- (anodic chamber) electron reaction at cathode surface, and facilitates electricity generation of bioelectro-Fenton. The removal rate of double cathode mode is 342.7 mg L-1 d-1 (50 mg L-1 tetracycline) and 170.1 mg L-1 d-1 (20 mg L-1 tetracycline), which is much higher than that of reported. These results indicate that external electron transport path enhances the electrochemical activity of anode film and performance of bioelectro-Fenton. This paper provides a new power supply method for the future practical application and field experiment of bioelectrio-Fenton.

Enhanced nutrients enrichment and removal from eutrophic water using a self-sustaining in situ photomicrobial nutrients recovery cell (PNRC).

Nutrients removal and recovery from surface water are attracting wide attention as nutrients contamination can cause eutrophication even threaten human health. In this study, a novel in-situ photomicrobial nutrient recovery cell (PNRC) was developed, which employed the self-generated electric field to drive nutrient ions to migrate and subsequent recovery as microalgae biomass. At an external resistance of 200 Ω, the current density of the PNRC reactor reached 2.0 A m-2, more than 92% of ammonium nitrogen (NH4+-N), nitrate nitrogen (NO3--N), and total phosphorus (TP) were separated from eutrophic water, which represented <0.19 mg L-1 of NH4+-N, <0.23 mg L-1 of NO3--N, <0.02 mg L-1 of TP were left in the eutrophic water effluent. Meanwhile these separated NH4+-N, NO3--N, and TP were highly enriched in the cathode and anode chambers, and further removed from the system with the removal efficiencies of 91.8%, 90.6%, and 94.4%. The analysis of microbial communities unraveled that high nitrate removal was attributed to the abundant denitrifying bacteria (Thauera, Paracoccus, Stappia, and Azoarcus). The removal of ammonia was attributed to the algae assimilation (69.3%) and nitrification process (22.5%), and the phosphorus removal was mainly attributed to C. vulgaris. The preliminary energy balance analysis indicated that the electricity generation and biodiesel production could achieve energy neutrality theoretically, further demonstrating the huge potential of the PNRC system in cost-effective nutrients recovery from eutrophic water.