Synthesis, Characterization, and Photocatalytic Evaluation of Manganese (III) Phthalocyanine Sensitized ZnWO4 (ZnWO4MnPc) for Bisphenol A Degradation under UV Irradiation.

ZnWO4MnPc was synthesized via a hydrothermal autoclave method with 1 wt.% manganese (iii) phthalocyanine content. The material was characterized for its structural and morphological features via X-ray diffraction (XRD) spectroscopy, Fourier transform infrared (FTIR) spectroscopy, transmission emission microscopy (TEM), scanning electron microscopy-Energy dispersive X-ray spectroscopy (SEM-EDX), N2 adsorption-desorption at 77K, X-ray photoelectron spectroscopy (XPS), and UV-visible/diffuse reflectance spectroscopy(UV-vis/DRS). ZnWO4MnPc photocatalytic performance was tested on the degradation of bisphenol A (BPA). The ZnWO4MnPc material removed 60% of BPA after 4 h of 365 nm UV irradiation. Degradation process improved significantly to about 80% removal in the presence of added 5 mM H2O2 after 4 h irradiation. Almost 100% removal was achieved after 30 min under 450 nm visible light irradiation in the presence of same concentration of H2O2. The effect of ions and humic acid (HA) towards BPA removal was also investigated.

Controlled deposition of fullerene derivatives within a graphene template by means of a modified Langmuir-Schaefer method.

The scientific and technological potential of graphene's includes the development of light, open 3D hybrid structures with high surface area, tunable pore size and aromatic functionalities. Towards this aim, we describe a scalable and low-cost bottom-up approach that combines self-assembly and Langmuir-Schaefer deposition for the production of fullerene-intercalated graphene oxide hybrids. This method uses graphene oxide (GO) nanosheets as template for the attachment of two types of fullerene derivatives (bromo-fullerenes, C60Br24 and fullerols, C60(OH)24) in a bi-dimensional arrangement, allowing a layer-by-layer growth with control at nanoscale. Our film preparation approach relies on a bottom-up process that includes the formation of a hybrid organo-graphene Langmuir film, which is transferred onto a substrate and then brought in contact with C60(OH)24 molecules in solution to induce self-assembly. In the case of grafting C60Br24 molecules into graphene a further modification of the GO platelets was performed by bringing the surface of the transferred GO Langmuir film in contact with a second amino surfactant solution. Repeating these deposition cycles, pillared structures were fabricated in thin films form. These fullerene-based hybrid thin films were characterized by Raman and X-ray photoelectron (XPS) spectroscopies, X-ray diffraction (XRD), Atomic Force Microscopy (AFM) and contact angle measurements.

Influence of organic phase change materials on the physical and mechanical properties of HDPE and PP polymers.

In this work, the compatibility of four commercially available organic phase change materials, with melting points in the temperature range 44-58 °C and with engineering polymers high density polyethylene (HDPE) and polypropylene (PP), is investigated. These polymers are used for the design and manufacture of hot and cold thermal energy storage tanks or encapsulation media. The study involves interaction of polymer specimens with the four different phase change materials for a period of time up to 40 days under high temperature. The mass change, mechanical strength and properties of the polymers were tested. The wt% uptake reached 6.4 wt% for PP and 5.8 wt% for HDPE. The strength of HDPE is immediately decreased by Day 7 but at a significant level restored after Day 28. No such effect was found for PP. The surface wetting as well as thermal properties measured (DSC) on the specimens provided an insight on the interaction of the absorbed phase change materials with the polymer. An in depth distribution over time was observed with significant decrease in the mechanical strength of the polymers. An epoxy-based resin was also evaluated under the same conditions and is suggested as a protective coating.

Device and materials for in vitro evaluation of forces developed to teeth and periodontal structures during dental practices.

This study aimed at providing a gauge device (Ekontak et al Gauge K-Device) in order to analyze the forces applied to teeth and periodontal tissues during dental practices in vitro. This force gauge device can be used in the investigation of the possible defect generation to tooth structures when overloaded forces are applied during dental procedures in vitro. Ekontak et al Gauge K-Device consists of three units: the specimen's holder, a high-performance digital force gauge, and the support frame. The holder was fabricated by an Al alloy providing a steady detachable attachment between the specimens and the force gauge's pin connector. The clinical simulation was achieved with the use of a proper silicone material, selected to provide similar elastic behavior with the human periodontal ligament and to join the teeth inside a solid matrix of an acrylic resin. The digital force gauge is a high-speed collection and recording (1000 Hz) product coupled with data recording software. The forces developed to 15 specimens' root canals during lateral condensation and vertical compaction of cold gutta-percha obturation procedures were monitored, saved as graphs, CSV, and excel files and presented over time. The forces developed during vertical compaction (mean maximum force per obturation circle = 13.22 N) were more excessive than those during lateral condensation (mean maximum force per obturation circle = 10.14 N). In conclusion, Ekontak et al Gauge K-Device is provided as a modern gauge device, capable of performing clinical simulation in vitro, under the terms of its protocol.