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1.
ACS Appl Mater Interfaces ; 11(4): 4578-4587, 2019 Jan 30.
Artigo em Inglês | MEDLINE | ID: mdl-30582798

RESUMO

A simple, efficient, and repeatable combination of wax printing and hot embossing is reported. This combination yields microfluidic channels in paper, where fluid transport driven by paper-intrinsic capillary forces takes place inside the noncompressed areas, whereas embossed and wax-bonded areas serve as hydrophobic barriers laterally confining the fluid flow. Lab-made paper sheets first coated with a hydrophobic wax were hot-embossed with a tailor-made metal stamp. Both paper-intrinsic (e.g., grammage, fiber type) and paper-extrinsic parameters (e.g., embossing force) were studied for their influence on the geometry of the embossed structures and the resulting redistribution of the wax within the paper matrix. Embossing of wax-printed paper at temperatures above the wax melting point was completed within 15 s. Cotton linters papers required higher embossing forces than eucalyptus papers, which can be explained by their different intrinsic mechanical properties. In summary, both paper-intrinsic and paper-extrinsic parameters were found to have strong impact on resolution and reproducibility of the channels. All in all, the approach yields microfluidic channels in a fast and robust and reproducible manner with comparably low constrains on the precision of manufacturing parameters, such as embossing time, force, or temperature. Most importantly, embossing greatly reduces the lateral spreading of the wax as seen with melting approaches and therefore allows for a much higher feature density than the latter.

2.
Adv Mater ; 30(22): e1707100, 2018 May.
Artigo em Inglês | MEDLINE | ID: mdl-29611238

RESUMO

Fused silica glass is one of the most important high-performance materials for scientific research, industry, and society. However due to its high chemical and thermal resistance as well as high hardness, fused silica glass is notoriously difficult to structure. This work introduces Glassomer, a solid nanocomposite, which can be structured using polymer molding and subtractive technologies at submicrometer resolution. After polymer processing Glassomer is turned into optical grade fused silica glass during a final heat treatment. The resulting glass has the same optical transparency as commercial fused silica and a smooth surface with a roughness of a few nanometers. This work makes high-performance fused silica glass components accessible to high-throughput fabrication technologies and will enable numerous optical, photonic and medical applications in science and industry.

3.
ACS Appl Mater Interfaces ; 10(3): 2929-2936, 2018 Jan 24.
Artigo em Inglês | MEDLINE | ID: mdl-29284257

RESUMO

Development of self-cleaning coatings is of great interest for the photovoltaic (PV) industry, as soiling of the modules can significantly reduce their electrical output and increase operational costs. We fabricated flexible polymeric films with novel disordered microcavity array (MCA) topography from fluorinated ethylene propylene (FEP) by hot embossing. Because of their superhydrophobicity with water contact angles above 150° and roll-off angles below 5°, the films possess self-cleaning properties over a wide range of tilt angles, starting at 10°, and contaminant sizes (30-900 µm). Droplets that impact the FEP MCA surface with velocities of the same order of magnitude as that of rain bounce off the surface without impairing its wetting properties. Additionally, the disordered MCA topography of the films enhances the performance of PV devices by improving light incoupling. Optical coupling of the FEP MCA films to a glass-encapsulated multicrystalline silicon solar cell results in 4.6% enhancement of the electrical output compared to that of an uncoated device.

4.
Lab Chip ; 16(9): 1561-4, 2016 04 26.
Artigo em Inglês | MEDLINE | ID: mdl-27040493

RESUMO

Cyclic olefin copolymer (COC) is widely used in microfluidics due to its UV-transparency, its biocompatibility and high chemical resistance. Here we present a fast and cost-effective solvent bonding technique, which allows for the efficient bonding of protein-patterned COC structures. The bonding process is carried out at room temperature and takes less than three minutes. Enzyme activity is retained upon bonding and microstructure deformation does not occur.


Assuntos
Materiais Biocompatíveis/química , Enzimas Imobilizadas/metabolismo , Dispositivos Lab-On-A-Chip , Microtecnologia/métodos , Modelos Biológicos , Solventes/química , Acetona/química , Adesividade , Cicloexanos/química , Cicloparafinas/química , Estabilidade Enzimática , Enzimas Imobilizadas/química , Heptanos/química , Peroxidase do Rábano Silvestre/química , Peroxidase do Rábano Silvestre/metabolismo , Propriedades de Superfície , Tolueno/química
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