Exploiting the Synergy between Concentrated Polymer Brushes and Laser Surface Texturing to Achieve Durable Superlubricity.

Friction continues to account for the bulk of energy losses in mechanical systems, with an estimated 23% of the world's total energy consumption used to overcome friction. Concentrated polymer brushes (CPBs) have recently attracted significant scientific and industrial attention, given their ability to achieve superlubricity (i.e., coefficients of friction below 0.01); however, understanding the mechanistic interactions underlying their wear performance has been largely overlooked. Herein, we employ a custom-built optical test apparatus to investigate the inter-dependencies between CPBs and laser-produced surface texture (LST), assessing for the first time the friction, film thickness, and wear behavior in situ and simultaneously. Recent developments in picosecond laser etching allowed us to graft CPBs atop the finest laser-etched matrix of micron-sized dimples reported in literature to date. At low sliding speeds, combined CPB-LST reduces the coefficient of friction to 0.0006, while increasing the CPB durability by up to 34% through a lateral support mechanism offered by the textured micro-features. Furthermore, the imaging results shed light on CPB failure mechanisms. Both these mechanisms of lateral support and failure propagation impact the wear resistance of CPBs and are important in the development of CPBs for future applications (e.g., in low-speed bearings functioning under controlled abrasive wear conditions).

Processes of molecular adsorption and ordering enhanced by mechanical stimuli under high contact pressure.

Adsorbed molecular films, referred to as boundary films in tribology, are widely used in various industrial products as a keyway for surface functionalisation, such as lubricity, wettability, and adhesion. Because boundary films are thin nanometre-scale molecular layers and can easily be removed, their formation process cannot be elucidated in detail. In this study, to analyse the growth dynamics of boundary films, the film thickness and molecular orientation of the boundary film of a fatty acid used as an additive in rolling contact as mechanical stimuli were measured in situ. The measurements were performed on simple test lubricants, which were composed of n-hexadecane and stearic acid, at rolling tribological condition between steel and glass (or sapphire) surfaces by ultrathin film interferometry combined with sum-frequency generation spectroscopy according to a unique protocol. The results quantitatively demonstrate shear-induced boundary film formation. The insight gained from these results is anticipated to enable the formulation of high-performance lubricant additives to further reduce friction loss and high-performance glues that can be freely designed for removability.