First-Principles Investigation of Phosphorus-Doped Graphitic Carbon Nitride as Anchoring Material for the Lithium-Sulfur Battery.

The utilization of lithium-sulfur battery is hindered by various challenges, including the "shuttle effect", limited sulfur utilization, and the sluggish conversion kinetics of lithium polysulfides (LiPSs). In the present work, a theoretical design for the viability of graphitic carbon nitride (g-C3N4) and phosphorus-doping graphitic carbon nitride substrates (P-g-C3N4) as promising host materials in a Li-S battery was conducted utilizing first-principles calculations. The PDOS shows that when the P atom is introduced, the 2p of the N atom is affected by the 2p orbital of the P atom, which increases the energy band of phosphorus-doping substrates. The energy bands of PC and Pi are 0.12 eV and 0.20 eV, respectively. When the lithium polysulfides are adsorbed on four substrates, the overall adsorption energy of PC is 48-77% higher than that of graphitic carbon nitride, in which the charge transfer of long-chain lithium polysulfides increase by more than 1.5-fold. It is found that there are powerful Li-N bonds between lithium polysulfides and P-g-C3N4 substrates. Compared with the graphitic carbon nitride monolayer, the anchoring effect of the LiPSs@P-g-C3N4 substrate is enhanced, which is beneficial for inhibiting the shuttle of high-order lithium polysulfides. Furthermore, the catalytic performance of the P-g-C3N4 substrate is assessed in terms of the S8 reduction pathway and the decomposition of Li2S; the decomposition energy barrier of the P-g-C3N4 substrate decrease by 10% to 18%. The calculated results show that P-g-C3N4 can promote the reduction of S8 molecules and Li-S bond cleavage within Li2S, thus improving the utilization of sulfur-active substances and the ability of rapid reaction kinetics. Therefore, the P-g-C3N4 substrates are a promising high-performance lithium-sulfur battery anchoring material.

Double-drying 3D lamellar-structured aerogel membrane for efficient oil-water separation and long-lasting antibacterial activity.

Conventional oil-water separation membranes are difficult to establish a trade-off between membrane flux and separation efficiency, and often result in serious secondary contamination due to their fouling issue and non-degradability. Herein, a double drying strategy was introduced through a combination of oven-drying and freeze-drying to create a super-wettable and eco-friendly oil-water separating aerogel membrane (TMAdf). Due to the regular nacre-like structures developed in the drying process and the pores formed by freeze-drying, TMAdf aerogel membrane finally develops regularly arranged porous structures. In addition, the aerogel membrane possesses excellent underwater superoleophobicity with a contact angle above 168° and antifouling properties. TMAdf aerogel membrane can effectively separate different kinds of oil-water mixtures and highly emulsified oil-water dispersions under gravity alone, achieving exceptionally high flux (3693 L·m-2·h-1) and efficiency (99 %), while being recyclable. The aerogel membrane also displays stability and universality, making it effective in removing oil droplets from water in corrosive environments such as acids, salts and alkalis. Furthermore, TMAdf aerogel membrane shows long-lasting antibacterial properties (photothermal sterilization up to 6 times) and biodegradability (completely degraded after 50 days in soil). This study presents new ideas and insights for the fabrication of multifunctional membranes for oil-water separation.

Anchoring and catalytic insights into bilayer C4N3 material for lithium-selenium batteries: a first-principles study.

In the present work, a theoretical design for the viability of bilayer C4N3 (bi-C4N3) as a promising host material for Li-Se battery was conducted utilizing first-principles calculations. The AA- and AB-stacking configurations of bilayer C4N3 can effectively inhibit the shuttling of high-order polyselenides through the synergistic effect of physical confinement and strong Li-N bonds. Compared to conventional electrolytes, the AA- and AB-stacking bilayer C4N3 demonstrate enhanced adsorption capabilities for the polyselenides. The anchored structures of Se8 or Li2Sen (n = 1, 2, 4, 6, 8) molecules within the bilayer C4N3 exhibit high electrical conductivities, which are beneficial for enhancing the electrochemical performance. The catalytic effects of AA- and AB-stacking bilayer C4N3 were investigated by the reduction of Se8 and the energy barrier associated with the decomposition of Li2Se. The AA- and AB-stacking bilayer C4N3 can significantly decrease the activation barrier and promote the decomposition of Li2Se. The mean square displacement (MSD) curves reveal the pronounceably sluggish Li-ions diffusions in polyselenides within the AA- and AB-stacking bilayer C4N3, which in turn demonstrates the notable prospects in mitigating the shuttle effect.

Unveiling the anchoring and catalytic effect of Co@C3N3 monolayer as a high-performance selenium host material in lithium-selenium batteries: a first-principles study.

Suppressing the shuttle effect of high-order polyselenides is crucial for the development of high-performance host materials in lithium-selenium (Li-Se) batteries. Using first-principles calculations, the feasibility of Co@C3N3 monolayer as selenium cathode host material for Li-Se batteries is systematically evaluated from the aspects of binding energy, charge transfer mechanism, and catalytic effect of polyselenides in the present work. The Co@C3N3 monolayer can effectively prevent the solubilization of high-order polyselenides with large binding energy and charge transfer resulting from the synergistic effect of Li-N and Co-Se bonds. The polyselenides are inclined to adsorb on the surface of Co@C3N3 monolayer instead of interacting with the electrolytes, which effectively inhibits the shuttling of high-order polyselenides and improves cycling stability. The cobalt participation improves the conductivity of C3N3 monolayer, and the semi-metallic characteristics of the Co@C3N3 monolayer are maintained after the adsorption of Li2Sen (n = 1, 2, 4, 6, 8) or Se8 clusters, which is advantageous for the utilization of active selenium material. The crucial catalytic role of the Co@C3N3 monolayer is evaluated by examining the reduction pathway of Se8 and the decomposition barrier of Li2Se, and the results highlight the capability of Co@C3N3 monolayer to enhance the utilization of selenium and promote the transition of Li2Se. Our present work could not only provide valuable insights into the anchoring and catalytic effect of Co@C3N3 monolayer, but also shed light on the future investigation on the high performance C3N3-based host materials for Li-Se batteries.

Enhancing phonon thermal transport in 2H-CrX2 (X = S and Se) monolayers through robust bonding interactions.

Inspired by the groundbreaking discovery of the 2H-MoS2 monolayer with outstanding physical properties, the electronic structure, structural stability, and thermal transport of 2H-CrX2 (X = S and Se) monolayers are theoretically evaluated using density functional theory (DFT) calculations and semiempirical Boltzmann transport theory. The 2H-CrX2 (X = S and Se) monolayers are direct semiconductors with the bandgaps of 0.91 and 0.69 eV. The elastic modulus and phonon dispersion curve analysis show that the 2H-CrX2 (X = S and Se) monolayers possess excellent mechanical and dynamic stabilities on account of elastic constants satisfying the Born-Huang criterion and the absence of negative frequencies. The thermal stabilities of the 2H-CrX2 (X = S and Se) monolayers at 300 K are proved by ab initio molecular dynamics (AIMD) simulations, as evidenced by the slight changes in the structural evolution and small fluctuation in total energy. High thermal conductivities of 131.7 and 88.6 W m-1 K-1 are discovered for 2H-CrS2 and 2H-CrSe2 monolayers at 300 K. Further analysis of the phonon group velocity, phonon relaxation time, and Grüneisen parameter shows that the high lattice thermal conductivities of 2H-CrX2 (X = S and Se) monolayers could be attributed to the great bond strength, large Young's modulus, relatively small atomic mass, high phonon group velocity, and long phonon relaxation time. In addition, the various scattering mechanisms are further considered in the calculations of phonon thermal transport to evaluate the effect of the scattering rates of the 2H-CrS2 and 2H-CrSe2 monolayers on the lattice thermal conductivity, and the determinative role is found for the phonon boundary scattering. Our present study would not only offer a fundamental understanding of the thermal transport properties of the 2H-CrX2 (X = S and Se) monolayers, but also provide theoretical guidelines for the experimental investigation of thermal management materials with 2H-phase.

Insight into the Desolvation of Quaternary Ammonium Cation with Acetonitrile as a Solvent in Hydroxyl-Flat Pores: A First-Principles Calculation.

Supercapacitors have a wide range of applications in high-technology fields. The desolvation of organic electrolyte cations affects the capacity size and conductivity of supercapacitors. However, few relevant studies have been published in this field. In this experiment, the adsorption behavior of porous carbon was simulated with first-principles calculations using a graphene bilayer with a layer spacing of 4-10 Å as a hydroxyl-flat pore model. The reaction energies of quaternary ammonium cations, acetonitrile, and quaternary ammonium cationic complexes were calculated in a graphene bilayer with different interlayer spacings, and the desolvation behavior of TEA+ and SBP+ ions was described. The critical size for the complete desolvation of [TEA(AN)]+ was 4.7 Å, and the partial desolvation size ranged from 4.7 to 4.8 Å. The critical size for the complete desolvation of [SBP(AN)]+ was 5.2 Å, and the partial desolvation size ranged from 5.2 to 5.5 Å. As the ionic radius of the quaternary ammonium cation decreased, the desolvation size showed a positive trend. A density of states (DOS) analysis of the desolvated quaternary ammonium cations embedded in the hydroxyl-flat pore structure showed that the conductivity of the hydroxyl-flat pore was enhanced after gaining electrons. The results of this paper provide some help in selecting organic electrolytes to improve the capacity and conductivity of supercapacitors.

Nacre-inspired biodegradable nanocellulose/MXene/AgNPs films with high strength and superior gas barrier properties.

Super strength and high barrier properties are the bottleneck of the application of cellulose film materials. Herein, it is reported a flexible gas barrier film with nacre-like layered structure, in which 1D TEMPO-oxidized nanocellulose (TNF) and 2D MXene self-assembled to form an interwoven stack structure with 0D AgNPs filling the void space. The strong interaction and dense structure endowed TNF/MX/AgNPs film with mechanical properties far superior to PE films and acid-base stability. Importantly, the film presented ultra-low oxygen permeability confirmed by molecular dynamics simulations and better barrier properties to volatile organic gases than PE films. It is here considered the tortuous path diffusion mechanism of the composite film responsible for the enhanced gas barrier performance. The TNF/MX/AgNPs film also possessed antibacterial properties, biocompatibility and degradability (completely degraded after 150 days in soil). Collectively, the TNF/MX/AgNPs film brings innovative insights into the design and fabrication of high-performance materials.

Fine Tuning of Defects Enables High Carrier Mobility and Enhanced Thermoelectric Performance of n-Type PbTe.

High carrier mobility is critical to improving thermoelectric performance over a broad temperature range. However, traditional doping inevitably deteriorates carrier mobility. Herein, we develop a strategy for fine tuning of defects to improve carrier mobility. To begin, n-type PbTe is created by compensating for the intrinsic Pb vacancy in bare PbTe. Excess Pb2+ reduces vacancy scattering, resulting in a high carrier mobility of ∼3400 cm2 V-1 s-1. Then, excess Ag is introduced to compensate for the remaining intrinsic Pb vacancies. We find that excess Ag exhibits a dynamic doping process with increasing temperatures, increasing both the carrier concentration and carrier mobility throughout a wide temperature range; specifically, an ultrahigh carrier mobility ∼7300 cm2 V-1 s-1 is obtained for Pb1.01Te + 0.002Ag at 300 K. Moreover, the dynamic doping-induced high carrier concentration suppresses the bipolar thermal conductivity at high temperatures. The final step is using iodine to optimize the carrier concentration to ∼1019 cm-3. Ultimately, a maximum ZT value of ∼1.5 and a large average ZT ave value of ∼1.0 at 300-773 K are obtained for Pb1.01Te0.998I0.002 + 0.002Ag. These findings demonstrate that fine tuning of defects with <0.5% impurities can remarkably enhance carrier mobility and improve thermoelectric performance.

Theoretical Prediction of Thermoelectric Performance for Layered LaAgOX (X = S, Se) Materials in Consideration of the Four-Phonon and Multiple Carrier Scattering Processes.

Inspired by the experimental achievement of layered LaCuOX (X = S, Se) with superior thermoelectric (TE) performance, the TE properties of Ag-based isomorphic LaAgOX are systemically investigated by the first-principles calculation. The LaAgOS and LaAgOSe are direct semiconductors with wide bandgaps of ≈2.50 and ≈2.35 eV. Essential four-phonon and multiple carrier scattering mechanisms are considered in phonon and electronic transport calculations to improve the accuracy of the figure-of-merit (ZT). The p-type LaAgOX (X = S, Se) shows excellent TE performance on account of the large Seebeck coefficient originated from the band convergency and low thermal conductivity caused by the strong phonon-phonon scattering. Consequently, the optimal ZTs along the out-of-plane direction decrease in the order of n-type LaAgOSe (≈2.88) > p-type LaAgOSe (≈2.50) > p-type LaAgOS (≈2.42) > n-type LaAgOS (≈2.27) at 700 K, and the optimal ZTs of ≈1.16 and ≈1.29 are achieved for p-type LaAgOS and LaAgOSe at the same temperature. The present work would provide a deep insight into the phonon and electronic transport properties of LaAgOX (X = S, Se), but also could shed light on the way for the rational design of state-of-the-art heteroanionic materials for TE application.

How the built environment affects the spatiotemporal pattern of urban vitality: A comparison among different urban functional areas.

Urban vitality is an essential indicator of an area's capacity to promote lively social and economic activities. Urban functional areas can play different roles throughout the day, and urban vitality may exhibit significant intraday temporal dynamics. However, few studies have evaluated the dynamic vitality throughout the day among various urban functional areas or explored how the built environment influences this attribute. To bridge this gap, we assessed the vitality dynamics in intensity, variability, and night ratio. We then examined the influencing factors of urban vitality in Central Shanghai using heatmap and point of interest (POI) data. We found significant differences in the intensity, variability, and night ratio of urban vitality among different urban functional areas. The difference in vitality intensity was more significant than the variability and night ratio between weekdays and weekends. The built environment significantly affected urban vitality, but its role differed among the various urban functional areas. Overall, describing urban vitality from a dynamic perspective could improve our understanding of the differences in attracting and maintaining human activities among different urban functional areas.

First-Principles Study on Interlayer Spacing and Structure Stability of NiAl-Layered Double Hydroxides.

Interlayer spacing and structure stability of layered double hydroxides (LDHs) on their application performance in adsorption, ion exchange, catalysis, carrier, and energy storage is important. The effect of different interlayer anions on the interlayer spacing and structure stability of LDHs has been less studied, but it is of great significance. Therefore, based on density functional theory (DFT), the computational model with 10 kinds of anions intercalated Ni3Al-A-LDHs (A = Cl-, Br-, I-, OH-, NO3 -, CO3 2-, SO4 2-, HCOO-, C6H5SO3 -, C12H25SO3 -) and four Ni R Al-Cl-LDH models with different Ni2+/Al3+ ratios (R = 2, 3, 5, 8) were constructed to calculate and analyze interlayer spacing, structural stability, and their influence factors. It was found that the interlayer spacing order of Ni3Al-A-LDHs intercalated with different anions is OH- < CO3 2- < Cl- < Br- < I- < HCOO- < SO4 2- < NO3 - < C6H5SO3 - < C12H25SO3 -. The hydrogen bond network between the base layer and the interlayer anions affects the arrangement structure of the interlayer anions, which affects the interlayer spacing. For interlayer monatomic anions Cl-, Br-, and I- and the anion of comparable size in each direction SO4 2-, the interlayer spacing is positively correlated with the interlayer anion diameter. The larger difference between the long-axis and short-axis dimensions of the polyatomic anions results in the long axis of the anion being perpendicular to the basal layer, increasing interlayer spacing. The long-chain anion C12H25SO3 - intercalation system exhibits the largest layer spacing of 24.262 Å. As R value increases from 2 to 8, the interlayer spacing of Ni R Al-Cl-LDHs gradually increases from 7.964 to 8.124 Å. The binding energy order between the interlayer anion and basal layer is CO3 2- > SO4 2- > OH- > Cl- > Br- > I- > HCOO- > NO3 - > C12H25SO3 - > C6H5SO3 -. The smaller the interlayer spacing, the higher the binding energy and the stronger the structural stability of LDHs. The factors affecting structural stability mainly include the bond length and bond angle of the hydrogen bond and the charge interaction between the basal layer and interlayer anion. In the CO3 2- intercalated system, the hydrogen bond length exhibits the shortest of 1.95 Å and the largest bond angle of 163.68°. The density of states and energy band analysis show that the higher the number of charges carried by the anion, the stronger its ability to provide electrons to the basal layer.

MXene-Enhanced Chitin Composite Sponges with Antibacterial and Hemostatic Activity for Wound Healing.

This study shows the effective use of MXene-based nanomaterials to improve the performance of biocomposite sponges in wound healing. In this way, diverse chitin/MXene composite sponges are fabricated by incorporating MXene-based nanomaterials with various morphology (accordion-shaped, intercalated, single-layer, gold nanoparticles (AuNPs)-loaded single-layer) into the network of chitin sponge (CH), which can prevent massive blood losses and promote the healing process of bacterial-infected wounds. With the addition of MXene-based nanomaterials, the hemostatic efficacy of CH is enhanced due to the improved hemophilicity and accelerated blood coagulation kinetics. Furthermore, the composite sponges show a predominant antibacterial activity through the synergy between the capture and the photothermal effects. Importantly, the addition of AuNPs to composite sponges further improves hemostatic performance and promotes normal skin cell migration to heal the infected wound, achieving wound closure rates of 84% on day 9. These initial studies expand the applications of MXene-based nanomaterials in biomedical fields.

Low-cost pentagonal NiX2 (X = S, Se, and Te) monolayers with strong anisotropy as potential thermoelectric materials.

Pentagonal compounds, as a new family of 2D materials, have recently been extensively studied in the fields of electrocatalysis, photovoltaics, and thermoelectrics. Encouraged by the successful synthesis of pentagonal PdSe2, the thermoelectric properties of low-cost pentagonal NiX2 (X = S, Se, and Te) monolayers are theoretically predicted with the help of first-principles calculations and the semiclassical Boltzmann transport theory. The high dynamic and thermal stabilities of pentagonal NiX2 (X = S, Se, and Te) monolayers are confirmed according to the phonon dispersion spectrums and ab initio molecular dynamics (AIMD) simulations. Indirect semiconductor features with wide bandgaps of 2.44, 2.31, and 1.88 eV at the Heyd-Scuseria-Ernzerhof (HSE06) level are discovered for pentagonal NiS2, NiSe2, and NiTe2 monolayers. Combining the Boltzmann transport equation and deformation potential theory, the Seebeck coefficient, power factor, and thermoelectric figure of merit (ZT) of NiX2 (X = S, Se, and Te) monolayers are evaluated from 300 to 600 K. The strongly anisotropic ZT values are discovered, which are attributed to the significant differences in electrical and thermal transport along the x and y directions. In addition, low lattice thermal conductivities are observed at 600 K for the pentagonal NiTe2 monolayer, accompanying higher ZT values of 1.81 and 1.58 along the x and y directions. The predicted thermoelectric properties indicate that the low-cost pentagonal NiSe2 and NiTe2 monolayers are potential anisotropic thermoelectric materials with high performance.

Recent Progress in Ti3C2Tx MXene-Based Flexible Pressure Sensors.

The rapid development of consumer electronics, artificial intelligence, and clinical medicine generates an increasing demand for flexible pressure sensors, whose performance depends significantly on sensitive materials with high flexibility and proper conductivity. MXene, a type of 2D nanomaterial, has attracted extensive attention due to its good electrical conductivity, hydrophilicity, and flexibility. The synthesis methods for MXenes make it relatively easy to control their microstructure and surface termination groups. Hence, MXenes can obtain peculiar microstructures and facilely combine with other functional materials, making them promising prospects for use in flexible pressure sensors. In this Review, recent advances in MXenes are summarized, mainly focusing on the synthesis methods and their application in flexible pressure sensors. Finally, the challenges and potential solutions for future development are also discussed.

Unraveling the superior anchoring of lithium polyselenides to the confinement bilayer C2N: an efficient host material for lithium-selenium batteries.

Carbonaceous materials with pores or bilayer spaces are a kind of potential host material to confine polyselenide diffusion and mitigate the shuttling effect. In the present work, a theoretical design of bilayer C2N (bi-C2N) as an efficient host material for lithium-selenium (Li-Se) batteries was explored by first-principles calculations. AA- and AB-stacking bilayer C2N could alleviate the dissolution of high-order polyselenides through a synergistic effect of physical confinement and strong Li-N bonds. Lithium polyselenides prefer to anchor on AA- and AB-stacking bilayer C2N instead of the commonly used electrolytes, showing their capabilities in suppressing the shuttle effect. Charge transfer occurs from Se8 and Li2Sen molecules (LiPSes) to AA- and AB-stacking bilayer C2N, giving rise to the formation of strong Li-N bonds. The AA- and AB-stacking LiPSes@C2N systems possess high electrical conductivities, which is beneficial for high electrochemical performance. In addition, the reversible conversion mechanisms of Li2Sen in the AA- and AB-stacking bilayer C2N are also investigated through the energy changes and decomposition reaction of the Li2Se molecule, and the results indicate that AA- and AB-stacking bilayer C2N facilitate the formation and decomposition of Li2Se by decreasing the active energy barriers and improving the selenium utilization rates. Our present work could shed some light on a possible strategy for designing highly efficient bilayer host materials for high performance Li-Se batteries.

Understanding the anchoring and catalytic effect of the Co@C2N monolayer in lithium-selenium batteries: a first-principles study.

The practical applications of lithium-selenium (Li-Se) batteries are impeded due to the low utilization of active selenium, sluggish kinetics, and volume change. The development of highly efficient host materials to suppress high-order polyselenide shuttling and accelerate Li2Se conversion is essential for Li-Se batteries. Herein, a theoretical design of a Co@C2N monolayer as a host material for ultra-high areal capacity Li-Se batteries is proposed by first-principles calculations. The investigations of the lowest energy configurations, binding energies, and the charge transfer indicate that the Co@C2N monolayer could alleviate the reciprocating motion of high-order polyselenides and improve the cycling performance. Further electronic property calculations show that the semi-metallic characteristics of the Co@C2N monolayer material are retained even after chemical adsorption with Se8 or Li2Sen molecules, which is beneficial for the utilization of active selenium. In addition, the crucial catalytic role of the Co@C2N monolayer is investigated and the results indicate that the Co@C2N monolayer could facilitate the formation and decomposition of Li2Se molecules during the discharge and charge processes. Our present work would not only provide a deep understanding on the anchoring and catalytic effect of the Co@C2N monolayer, but also demonstrate a general principle for the rational design and screening of advanced materials for high energy density Li-Se batteries.

3D printed nanocellulose-based label for fruit freshness keeping and visual monitoring.

Food packaging systems with a single function of freshness keeping or monitoring may not be able to meet all practical needs. Herein, cellulose nanofibers (CNF)-based labels with dual functions of fruit freshness keeping and visual monitoring were prepared by coaxial 3D printing. CNF-based ink with blueberry anthocyanin was used to create the shell of fibers, exhibiting high formability and print fidelity as well as sensitive visual pH-responsiveness for freshness monitoring. Chitosan containing 1-methylcyclopropene (1-MCP) was loaded into the hollow microchannels of fibers, in which 1-MCP was trapped by the electrostatic effect of chitosan and CNF and exhibited a sustained release behavior. The 3D printed labels prolonged the shelf life of litchis for 6 days, meanwhile, they sensitively indicated the changes in freshness and the accuracy was confirmed by Headspace-Gas Chromatography-Ion Mobility Spectrometry. The CNF-based integrated labels developed in this work provided a new idea for the development of food intelligent packaging.

Insights into the effect of hydroxyl-, epoxy-, and carboxyl-pores on the desolvation of K+with water as a solvent: a first-principles study.

The oxygen-containing functional group is particularly effective at the capacity and cycle performance of porous carbon, but there are few reports on the influence of ionic desolvation. The desolvated behavior in porous carbon could be availably simulated through the bilayer graphene with the interlayer spacings of 4-10 Å as the flat pore model by a first-principles calculation. The desolvated behavior of hydrated potassium ion ([K(H2O)]+) is calculated in AA- and AB-stacking hydroxyl-, epoxy-, carboxyl-flat pores. The results show that the fully desolvated sizes of [K(H2O)]+in hydroxyl-, epoxy-, carboxyl-pores are 4.6 Å, 4.7 Å, and 4.2 Å, respectively. The fully desolvated pore size increases under the modification of hydroxyl- and epoxy-groups in pores and the size slightly reduces in carboxyl-pores compared with the fully desolvated size of (4.4 Å) [K(H2O)]+in flat pores without oxygen-containing functional group. Electron density difference and Hirshfeld charge analysis show that K+primarily interacts with the oxygen-containing functional groups of pores. Our present results are helpful to improve the capacity of supercapacitors by adjusting the types of oxygen-containing functional groups on the pore walls of porous carbon materials.

3D-Printed Nanocellulose-Based Cushioning-Antibacterial Dual-Function Food Packaging Aerogel.

Cushioning and antibacterial packaging are the requirements of the storage and transportation of fruits and vegetables, which are essential for reducing the irreversible quality loss during the process. Herein, the composite of carboxymethyl nanocellulose, glycerin, and acrylamide derivatives acted as the shell and chitosan/AgNPs were immobilized in the core by using coaxial 3D-printing technology. Thus, the 3D-printed cushioning-antibacterial dual-function packaging aerogel with a shell-core structure (CNGA/C-AgNPs) was obtained. The CNGA/C-AgNPs packaging aerogel had good cushioning and resilience performance, and the average compression resilience rate was more than 90%. Although AgNPs was slowly released, CNGA/C-AgNPs packaging aerogel had an obvious antibacterial effect on E. coli and S. aureus. Moreover, the CNGA/C-AgNPs packaging aerogel was biodegradable. Due to the customization capabilities of 3D-printing technology, the prepared packaging aerogel can be adapted to more application scenarios by accurately designing and regulating the microstructure of aerogels, which provides a new idea for the development of food intelligent packaging.

Antibacterial chitosan composite films with food-inspired carbon spheres immobilized AgNPs.

The cumulative toxicity of AgNPs has limited their application in food packaging. As such, the quest for AgNPs should focus on controlling their release to reduce the cumulative toxicity. Here, two kinds of green hydrothermal carbonized methods were used to treat sulfhydryl-modified chitosan to obtain two kinds of carbon spheres/AgNPs (Glutinous rice sesameballs-like AgNPs-SMCS and dragon fruit-like SMCS-Ag), which exhibited good stability and high immobilization efficiency for AgNPs, and the release of total Ag from AgNPs-SMCS and SMCS-Ag were only about 5.63% and 3.59% after 14 days, respectively. Subsequently, they were added into chitosan separately to prepare chitosan-based films. Two carbon spheres/AgNPs regulated the microstructure of chitosan-based films because of the electrostatic interaction and the micro-nanometer filling behavior, thus further immobilized the AgNPs. Importantly, the films presented good antibacterial activity and excellent safety. These results will provide a theoretical basis for the green and safe design of AgNPs antibacterial agent.