Identifying potential uses for green roof discharge based on its physical-chemical-microbiological quality.

Green roofs are promising tools in sustainable urban planning, offering benefits such as stormwater management, energy savings, aesthetic appeal, and recreational spaces. They play a crucial role in creating sustainable and resilient cities, providing both environmental and economic advantages. Despite these benefits, concerns persist about their impact on water quality, especially for non-potable use, as conflicting results are found in the literature. This study presents a comparative analysis of the quantity and quality of water drained from an extensive green roof against an adjacent conventional rooftop made of fiber-cement tiles in subtropical Brazil. Over a 14-month period, the water drained from both roofs was evaluated based on physical (turbidity, apparent color, true color, electrical conductivity, total solids, total dissolved solids, suspended solids), chemical (pH, phosphate, total nitrogen, nitrate, nitrite, chlorides, sulfates, and BOD), microbiological (total coliforms and E. coli), and metal (copper, iron, zinc, lead, and chrome) concentration parameters. The discharge from the green roof was 40% lower than its counterpart measured at the control roof, while the water quality from both roofs was quite similar. However, the green roof acted as source of chlorides, electrical conductivity, color, BOD, total hardness, E. coli, phosphate, sulfate, and turbidity. On the other side, the green roof neutralized the slightly acidic character of rainwater, showcasing its potential to mitigate the effects of acid rain. The study's results underscored that the water discharged from the green roof generally aligned with non-potable standards mandated by both Brazilian and international regulations. However, the findings emphasized the imperative need for pre-treatment of the green roof discharge before its utilization, specifically adjusting parameters like turbidity, BOD, total coliforms, and E. coli, which were identified as crucial to ensure water safety and compliance with non-potable use standards.

Evaluating bioretention scale effect on stormwater retention and pollutant removal.

Bioretention column studies are commonly used in laboratory to assess the performance of such structures in removal of pollutants and to investigate different conceptions aiming to increase their efficiency. However, no studies were found recommending suitable diameters or sizes, or about the uncertainties related to the transfer of results among the different scales (i.e., among different experiments or from the laboratory to field scale). This study assessed the effect of the varying diameters in experimental bioretention columns on the retention and removal of pollutants from stormwater runoff. Three sets of columns with diameters of 400 mm, 300 mm, and 200 mm were assessed. The results showed that runoff retention (R) was affected by the time interval between stormwater events, but not by the bioretention diameter, although the diameter influenced the variability of R results. The removal of TSS (95%), nitrite (98%), and phosphate (96%) did present variability among the different bioretention diameters. However, the nitrate removal was statistically different among the bioretention columns, with removal efficiency above 50% in the 300-mm and 200-mm columns, while the 400-mm columns acted as a source of nitrate by increasing its concentration in the outflow stormwater by up to 285%, suggesting that the removal of this pollutant can be influenced by the scale effect of the bioretention columns and the experiments with small bioretention diameters may not provide reliable results.

Improved Adsorption of the Toxic Herbicide Diuron Using Activated Carbon Obtained from Residual Cassava Biomass (Manihot esculenta).

The production and consumption of cassava (Manihot esculenta) occur in several places worldwide, producing large volumes of waste, mostly in the form of bark. This study sought to bring a new purpose to this biomass through producing activated carbon to use as an adsorbent to remove the herbicide Diuron from water. It was observed that the carbon contains the functional groups of methyl, carbonyl, and hydroxyl in a strongly amorphous structure. The activated carbon had a surface area of 613.7 m2 g-1, a pore volume of 0.337 cm3 g-1, and a pore diameter of 1.18 nm. The Freundlich model was found to best describe the experimental data. It was observed that an increase in temperature favored adsorption, reaching a maximum experimental capacity of 222 mg g-1 at 328 K. The thermodynamic parameters showed that the adsorption was spontaneous, favorable, and endothermic. The enthalpy of adsorption magnitude was consistent with physical adsorption. Equilibrium was attained within 120 min. The linear driving force (LDF) model provided a strong statistical match to the kinetic curves. Diffusivity (Ds) and the model coefficient (KLDF) both increased with a rise in herbicide concentration. The adsorbent removed up to 68% of pollutants in a simulated effluent containing different herbicides. Activated carbon with zinc chloride (ZnCl2), produced from leftover cassava husks, was shown to be a viable alternative as an adsorbent for the treatment of effluents containing not only the herbicide Diuron but also a mixture of other herbicides.

Monitoring sediment yield for soil and water conservation planning in rural catchments.

Sediment yield in river catchments can cause siltation of reservoirs and channels, carries contaminants adhered to sediment particles, and represents water erosion at the catchment scale, leading to decreased agricultural productivity. Hydrological monitoring enables the understanding of overland flow and soil erosion dynamics. In this study, we analyzed whether the relationship between precipitation (P), water flow (Q), and suspended sediment concentration (SSC) during rainfall events shows the usefulness of hydrological and sedimentological monitoring in soil and water conservation projects to river catchments. We conducted a study in the Lajeado Ferreira catchment in southern Brazil. This catchment is characterized by high soil fragility and erosion rates because of relief and intense tobacco cultivation. The small size of the catchment (120 ha) allowed a better understanding of the processes that occurred between hillslope and watercourses. We analyzed 43 rainfall-runoff events (P-Q), and we selected characteristic variables of each event and related them to independent variables (climate, land use, and soil management) and their seasonality using regression techniques. We also conducted a hysteresis analysis to understand the behavior of SSC in relation to runoff. The results showed a high relation of sediment yield (SY) with maximum water flow of the event (Qmax), and linear regression models showed the best performance between characteristic variables. In addition, the seasonal variability of the land coverage presented greater influence on the SY than the precipitation itself.

Eco-hidrologia integrada ao manejo dos recursos hídricos em áreas úmidas: caso do Banhado do Taim, RS / Ecohydrology integrated to the water resources management in wetlands: the Taim Wetland case, RS, Brazil

RESUMO A eco-hidrologia busca integrar os conhecimentos da hidrologia aos da ecologia, criando uma abordagem mais ampla para a compreensão da dinâmica dos recursos hídricos, facilitando o planejamento e as ações de programas de gestão. Uma das formas de integrar hidrologia à ecologia é por meio da elaboração de índices de adequabilidade de hábitat (IAHs), processo que tem se destacado por fornecer informações relevantes sobre áreas úmidas. O IAH é obtido pela relação entre as informações sobre espécies bioindicadoras e as condições eco-hidrológicas necessárias à sua sobrevivência, permitindo a avaliação de impactos sobre as espécies. O desenvolvimento de IAHs, integrados a processos de modelagem hidrodinâmica e sistemas de informação geográfica (SIGs), proporciona a obtenção de imagens de adequabilidade de hábitat, que permitem obter informações espacializadas sobre a qualidade do hábitat de determinada espécie, ou grupo de espécies, colaborando para o aperfeiçoamento das estratégias de gerenciamento dos recursos hídricos e a conservação da biodiversidade de áreas úmidas. A fim de melhor elucidar o processo de desenvolvimento de IAHs e sua aplicação, é apresentada a metodologia utilizada para avaliar a adequabilidade do Banhado do Taim, inserido na Estação Ecológica do Taim, importante área úmida localizada no sul da planície costeira do Rio Grande do Sul.

ABSTRACT The ecohydrology aims at integrating the concepts of hydrology and ecology, creating a broader approach to understand the water resources' dynamics, facilitating the plan and management of resources. One way to integrate hydrology with ecology is by developing Habitat Suitability Index (HSI), a process that stands out by providing relevant information on wetlands. HSI is obtained by relating the information about the bioindicators and ecohydrological conditions necessary to ensure these species' survival, enabling to evaluate the impacts on them. The development of HSIs integrated with hydrodynamic modeling and Geographic Information Systems (GIS) allows us to obtain spatialized habitat suitability information, that provide information about the quality of a species' (or group of species') habitat, contributing to the improvement of water resources management strategies combined with the biodiversity conservation in wetlands. Regarding this, the present article presents the HSI's development process and its application to evaluate the suitability of the Taim Basin, inserted in Taim Ecological Station, an important Southern Coastal wetland located in the State of Rio Grande do Sul.