1.
Langmuir
; 21(4): 1412-5, 2005 Feb 15.
Artigo
em Inglês
| MEDLINE
| ID: mdl-15697288
RESUMO
A substrate-independent method has been devised for ring formation at solid surfaces. This entails the aminolysis reaction of allylamine with maleic anhydride pulsed plasma polymer films to yield terminal alkene groups at the surface. Subsequent exposure to 1,3-cyclohexadiene leads to a Diels-Alder type (4 + 2) cycloaddition reaction to give a mixture of endo- and exo-bicyclo[2.2.2]oct-2-ene rings.