Investigation of TiO2 Deposit on SiO2 Films: Synthesis, Characterization, and Efficiency for the Photocatalytic Discoloration of Methylene Blue in Aqueous Solution.

TiO2-SiO2 thin films were created on Corning glass substrates using a simple method. Nine layers of SiO2 were deposited; later, several layers of TiO2 were deposited, and their influence was studied. Raman spectroscopy, high resolution transmission electron spectroscopy (HRTEM), an X-ray diffractometer (XRD), ultraviolet-visible spectroscopy (UV-Vis), a scanning electron microscope (SEM), and atomic force microscopy (AFM) were used to describe the sample's shape, size, composition, and optical characteristics. Photocatalysis was realized through an experiment involving the deterioration of methylene blue (MB) solution exposed to UV-Vis radiation. With the increase of TiO2 layers, the photocatalytic activity (PA) of the thin films showed an increasing trend, and the maximum degradation efficiency of MB by TiO2-SiO2 was 98%, which was significantly higher than that obtained by SiO2 thin films. It was found that an anatase structure was formed at a calcination temperature of 550 °C; phases of brookite or rutile were not observed. Each nanoparticle's size was 13-18 nm. Due to photo-excitation occurring in both the SiO2 and the TiO2, deep UV light (λ = 232 nm) had to be used as a light source to increase photocatalytic activity.

Performance Evaluation of Different Object Detection Models for the Segmentation of Optical Cups and Discs.

Glaucoma is an eye disease that gradually deteriorates vision. Much research focuses on extracting information from the optic disc and optic cup, the structure used for measuring the cup-to-disc ratio. These structures are commonly segmented with deeplearning techniques, primarily using Encoder-Decoder models, which are hard to train and time-consuming. Object detection models using convolutional neural networks can extract features from fundus retinal images with good precision. However, the superiority of one model over another for a specific task is still being determined. The main goal of our approach is to compare object detection model performance to automate segment cups and discs on fundus images. This study brings the novelty of seeing the behavior of different object detection models in the detection and segmentation of the disc and the optical cup (Mask R-CNN, MS R-CNN, CARAFE, Cascade Mask R-CNN, GCNet, SOLO, Point_Rend), evaluated on Retinal Fundus Images for Glaucoma Analysis (REFUGE), and G1020 datasets. Reported metrics were Average Precision (AP), F1-score, IoU, and AUCPR. Several models achieved the highest AP with a perfect 1.000 when the threshold for IoU was set up at 0.50 on REFUGE, and the lowest was Cascade Mask R-CNN with an AP of 0.997. On the G1020 dataset, the best model was Point_Rend with an AP of 0.956, and the worst was SOLO with 0.906. It was concluded that the methods reviewed achieved excellent performance with high precision and recall values, showing efficiency and effectiveness. The problem of how many images are needed was addressed with an initial value of 100, with excellent results. Data augmentation, multi-scale handling, and anchor box size brought improvements. The capability to translate knowledge from one database to another shows promising results too.

Segmentation of OCT and OCT-A Images using Convolutional Neural Networks / Segmentación de imágenes de OCT y OCT-A por medio de Redes Neuronales Convolucionales

ABSTRACT Segmentation is vital in Optical Coherence Tomography Angiography (OCT-A) images. The separation and distinction of the different parts that build the macula simplify the subsequent detection of observable patterns/illnesses in the retina. In this work, we carried out multi-class image segmentation where the best characteristics are highlighted in the appropriate plexuses by comparing different neural network architectures, including U-Net, ResU-Net, and FCN. We focus on two critical zones: retinal vasculature (RV) and foveal avascular zone (FAZ). The precision obtained from the RV and FAZ segmentation over 316 OCT-A images from the OCT-A 500 database at 93.21% and 92.59%, where the FAZ was segmented with an accuracy of 99.83% for binary classification.

RESUMEN La segmentación juega un papel vital en las imágenes de angiografía por tomografía de coherencia óptica (OCT-A), ya que la separación y distinción de las diferentes partes que forman la mácula simplifican la detección posterior de patrones/enfermedades observables en la retina. En este trabajo, llevamos a cabo una segmentación de imágenes multiclase donde se destacan las mejores características en los plexos apropiados al comparar diferentes arquitecturas de redes neuronales, incluidas U-Net, ResU-Net y FCN. Nos centramos en dos zonas críticas: la segmentación de la vasculatura retiniana (RV) y la zona avascular foveal (FAZ). La precisión para RV y FAZ en 316 imágenes OCT-A de la base de datos OCT-A 500 se obtuvo en 93.21 % y 92.59 %. Cuando se segmentó la FAZ en una clasificación binaria, con un 99.83% de precisión.

Diagnostic Strategies for Breast Cancer Detection: From Image Generation to Classification Strategies Using Artificial Intelligence Algorithms.

Breast cancer is one the main death causes for women worldwide, as 16% of the diagnosed malignant lesions worldwide are its consequence. In this sense, it is of paramount importance to diagnose these lesions in the earliest stage possible, in order to have the highest chances of survival. While there are several works that present selected topics in this area, none of them present a complete panorama, that is, from the image generation to its interpretation. This work presents a comprehensive state-of-the-art review of the image generation and processing techniques to detect Breast Cancer, where potential candidates for the image generation and processing are presented and discussed. Novel methodologies should consider the adroit integration of artificial intelligence-concepts and the categorical data to generate modern alternatives that can have the accuracy, precision and reliability expected to mitigate the misclassifications.

Logit models, the area under receiver characteristic curves, sensitivity, and specificity for Co-enrollment density in college networks dataset.

This article describes the data related to co-enrollment density (CD), a new network clustering index, that can predict persistence and graduation. The data hold the raw results and charts obtained with the algorithm for CD introduced in ``Co-Enrollment Density Predicts Engineering Students' Persistence and Graduation: College Networks and Logistic Regression Analysis.'' There are data for eight institutions that show CD as a predictor for graduation at four years, graduation at six years, and ever graduated. The files were processed using R to estimate CD at one, two, three, and four years. Logistic regression models, receiver operating characteristic curves, specificity, sensitivity, and cut-off points were estimated for each model. The R code to reproduce the metanalysis for the summary data is included. The displays for the logistic regression models, receiver operating characteristic curves, density curves for classes, models, and parameters are included.

A PID-Type Fuzzy Logic Controller-Based Approach for Motion Control Applications.

Motion control is widely used in industrial applications since machinery, robots, conveyor bands use smooth movements in order to reach a desired position decreasing the steady error and energy consumption. In this paper, a new Proportional-Integral-Derivative (PID) -type fuzzy logic controller (FLC) tuning strategy that is based on direct fuzzy relations is proposed in order to compute the PID constants. The motion control algorithm is composed by PID-type FLC and S-curve velocity profile, which is developed in C/C++ programming language; therefore, a license is not required to reproduce the code among embedded systems. The self-tuning controller is carried out online, it depends on error and change in error to adapt according to the system variations. The experimental results were obtained in a linear platform integrated by a direct current (DC) motor connected to an encoder to measure the position. The shaft of the motor is connected to an endless screw; a cart is placed on the screw to control its position. The rise time, overshoot, and settling time values measured in the experimentation are 0.124 s, 8.985% and 0.248 s, respectively. These results presented in part 6 demonstrate the performance of the controller, since the rise time and settling time are improved according to the state of the art. Besides, these parameters are compared with different control architectures reported in the literature. This comparison is made after applying a step input signal to the DC motor.

Optical Methods Based on Ultraviolet, Visible, and Near-Infrared Spectra to Estimate Fat and Protein in Raw Milk: A Review.

The present manuscript focuses on reviewing the optical techniques proposed to monitor milk quality in dairy farms to increase productivity and reduce costs. As is well known, the quality is linked to the fat and protein concentration; in addition, this issue is crucial to maintaining a healthy herd and preventing illnesses such as mastitis and ketosis. Usually, the quality of the milk is carried out with invasive methods employing chemical reagents that increase the time analysis. As a solution, several spectroscopy optical methods have been proposed, here, the benefits such as non-invasive measurement, online implementation, rapid estimation, and cost-effective execution. The most attractive optical methods to estimate fat and protein in cow's milk are compared and discussed considering their performance. The analysis is divided considering the wavelength operation (ultraviolet, visible, and infrared). Moreover, the weaknesses and strengths of the methods are fully analyzed. Finally, we provide the trends and a recent technique based on spectroscopy in the visible wavelength.

Blockchain Mechanism and Symmetric Encryption in A Wireless Sensor Network.

The Internet of Things (IoT) paradigm allows the connection and exchange of information between millions of smart devices. This paradigm grows and develops exponentially as do the risks and attacks on IoT infrastructures. Security, privacy, reliability, and autonomy are the most important requirements in IoT Systems. If these issues are not guaranteed, the IoT system could be susceptible to malicious users and malicious use. In centralized IoT systems, attacks and risks are greater, especially when data is transmitted between devices and shared with other organizations. To avoid these types of situations, this work presents a decentralized system that guarantees the autonomy and security of an IoT system. The proposed methodology helps to protect data integrity and availability based on the security advantages provided by blockchain and the use of cryptographic tools. The accuracy of the proposed methodology was measured on a temperature and humidity sensing IoT-based Wireless Sensor Network (WSN). The obtained results prove that the proposal fulfils the main requirements of an IoT system. It is autonomous, secure to share and send information between devices and users, has privacy, it is reliable, and the information is available in the infrastructure. Furthermore, this research demonstrates that the proposal is less susceptible to the most frequent attacks against IoT systems, such as linking attack, man in the middle, and Distributed Denial of Service (DDoS) attack.

Applications of solar and wind renewable energy in agriculture: A review.

The growing demand for food and the unstable price of fossil fuels has led to the search for environmentally friendly sources of energy. Energy is one of the largest overhead costs in the production of greenhouse crops for favorable climate control. The use of wind-solar renewable energy system for the control of greenhouse environments reduces fuel consumption and so enhances the sustainability of greenhouse production. This review describes the impact of solar-wind renewable energy systems in agricultural greenhouses.

A New Methodology Based on EMD and Nonlinear Measurements for Sudden Cardiac Death Detection.

Heart diseases are among the most common death causes in the population. Particularly, sudden cardiac death (SCD) is the cause of 10% of the deaths around the world. For this reason, it is necessary to develop new methodologies that can predict this event in the earliest possible stage. This work presents a novel methodology to predict when a person can develop an SCD episode before it occurs. It is based on the adroit combination of the empirical mode decomposition, nonlinear measurements, such as the Higuchi fractal and permutation entropy, and a neural network. The obtained results show that the proposed methodology is capable of detecting an SCD episode 25 min before it appears with a 94% accuracy. The main benefits of the proposal are: (1) an improved detection time of 25% compared with previously published works, (2) moderate computational complexity since only two features are used, and (3) it uses the raw ECG without any preprocessing stage, unlike recent previous works.

Revisiting Gaussian Process Regression Modeling for Localization in Wireless Sensor Networks.

Signal strength-based positioning in wireless sensor networks is a key technology for seamless, ubiquitous localization, especially in areas where Global Navigation Satellite System (GNSS) signals propagate poorly. To enable wireless local area network (WLAN) location fingerprinting in larger areas while maintaining accuracy, methods to reduce the effort of radio map creation must be consolidated and automatized. Gaussian process regression has been applied to overcome this issue, also with auspicious results, but the fit of the model was never thoroughly assessed. Instead, most studies trained a readily available model, relying on the zero mean and squared exponential covariance function, without further scrutinization. This paper studies the Gaussian process regression model selection for WLAN fingerprinting in indoor and outdoor environments. We train several models for indoor/outdoor- and combined areas; we evaluate them quantitatively and compare them by means of adequate model measures, hence assessing the fit of these models directly. To illuminate the quality of the model fit, the residuals of the proposed model are investigated, as well. Comparative experiments on the positioning performance verify and conclude the model selection. In this way, we show that the standard model is not the most appropriate, discuss alternatives and present our best candidate.

Long-range wireless mesh network for weather monitoring in unfriendly geographic conditions.

In this paper a long-range wireless mesh network system is presented. It consists of three main parts: Remote Terminal Units (RTUs), Base Terminal Units (BTUs) and a Central Server (CS). The RTUs share a wireless network transmitting in the industrial, scientific and medical applications ISM band, which reaches up to 64 Km in a single point-to-point communication. A BTU controls the traffic within the network and has as its main task interconnecting it to a Ku-band satellite link using an embedded microcontroller-based gateway. Collected data is stored in a CS and presented to the final user in a numerical and a graphical form in a web portal.