1.
J Org Chem
; 87(10): 6541-6551, 2022 05 20.
Artigo
em Inglês
| MEDLINE
| ID: mdl-35486716
RESUMO
A modular approach has been adopted to synthesize a wide range of visible light-driven photoswitchable azoheteroarenes. In this regard, we considered ortho substitution of cyclic amines in the aryl ring and varied substitution patterns. Using detailed spectroscopic studies, we established a relationship between structure and photoswitching ability and also half-lives of the Z-isomers. Through this, we envision tunable and bidirectional longer wavelength photoswitches.