Heat-Induced Actuator Fibers: Starch-Containing Biopolyamide Composites for Functional Textiles.

This study introduces the development of a thermally responsive shape-morphing fabric using low-melting-point polyamide shape memory actuators. To facilitate the blending of biomaterials, we report the synthesis and characterization of a biopolyamide with a relatively low melting point. Additionally, we present a straightforward and solvent-free method for the compatibilization of starch particles with the synthesized biopolyamide, aiming to enhance the sustainability of polyamide and customize the actuation temperature. Subsequently, homogeneous dispersion of up to 70 wt % compatibilized starch particles into the matrix is achieved. The resulting composites exhibit excellent mechanical properties comparable to those reported for soft and tough materials, making them well suited for textile integration. Furthermore, cyclic thermomechanical tests were conducted to evaluate the shape memory and shape recovery of both plain polyamide and composites. The results confirmed their remarkable shape recovery properties. To demonstrate the potential application of biocomposites in textiles, a heat-responsive fabric was created using thermoresponsive shape memory polymer actuators composed of a biocomposite containing 50 wt % compatibilized starch. This fabric demonstrates the ability to repeatedly undergo significant heat-induced deformations by opening and closing pores, thereby exposing hidden functionalities through heat stimulation. This innovative approach provides a convenient pathway for designing heat-responsive textiles, adding value to state-of-the-art smart textiles.

Active Textile Fabrics from Weaving Liquid Crystalline Elastomer Filaments.

Active fabrics, responding autonomously to environmental changes, are the "Holy Grail" of the development of smart textiles. Liquid crystal elastomers (LCEs) promise to be the base materials for large-stroke reversible actuation. The mechanical behavior of LCEs matches almost exactly the human muscle. Yet, it has not been possible to produce filaments from LCEs that will be suitable for standard textile production methods, such as weaving. Based on the recent development of LCE fibers, here, the crafting of active fabrics incorporating LCE yarn, woven on a standard loom, giving control over the weave density and structure, is presented. Two types of LCE yarns (soft and stiff) and their incorporation into several weaving patterns are tested, and the "champions" identified: the twill pattern with stiffer LCE yarn that shows the greatest blocking force of 1-2 N cm-1 , and the weft rib pattern with over 10% reversible actuation strain on repeated heating cycles. Reversible 3D shape changes of active fabric utilize the circular weaving patterns that lead to cone shapes upon heating. The seamless combination of active LCE yarns into the rich portfolio of existing passive yarns can be transformative in creating new stimuli-responsive actuating textiles.