Porphyrin-Regulated Heterostructured Hydrogel Ionic Diode with a High Rectification Ratio and Output Voltage.

Nanochannel ionic diodes require extremely complex and expensive fabrication processes. Polyelectrolyte ionic diodes attracted widespread attention among ionic rectification systems due to their simplicity of development and the ability to break the size limits of the nanochannel. However, enhancement of their rectification ratio is still in the exploratory stage. In this study, chitosan (CS) hydrogels and sodium polyacrylate (PAAs) hydrogels were prepared as the substrates for the heterostructured ionic diodes. 5,10,15,20-Tetrakis(4-aminophenyl)-21H,23H-porphyrin (TAPP) was selected to regulate the rectification ratio of ionic diodes. By adding 0.05 wt % TAPP to the CS hydrogel, the rectification ratio of the ionic diode can be increased to 10, which is 4 times larger than that of the undoped ionic diode. In contrast, the rectification ratio of the ionic diodes with TAPP added in the PAAs hydrogel decreases to 2. In addition, the ionic diode composed of the TAPP-doped CS hydrogel and PAAs hydrogel has the characteristics of a high open-circuit voltage. The open-circuit voltage of the 10 mm × 10 mm × 4 mm heterojunction hydrogel reached 370 mV. The ionic diodes can be used as a self-powered power supply device.

Flexible Wood Enhanced Poly(acrylic acid-co-acrylamide)/Quaternized Gelatin Hydrogel Electrolytes for High-Energy-Density Supercapacitors.

Hydrogels with good flexibility and strong hydrophilicity can be candidates for excellent flexible electrolyte materials. However, the poor structural stability, uncontrollable swelling, and lower potential window of hydrogel electrolytes need to be improved. This work combined quaternized gelatin with cross-linked poly(acrylic acid-co-acrylamide) to form a semi-interpenetrating network and gelatinized in situ in a flexible porous wood skeleton. The flexible wood (FW) skeleton enhances the hydrogel and limits the swelling of the hydrogel. In addition, quaternary ammonium groups and FW act synergistically to provide the composite hydrogel electrolyte with a high ionic conductivity of 5.57 × 10-2 S cm-1. The composite hydrogel electrolyte can enable the flexible supercapacitor to operate safely in a potential window of 0-2 V. The optimized supercapacitor has a high specific capacitance of 286.74 F g-1 and provides an outstanding energy density of 39.09 W h kg-1. The flexible supercapacitor shows a capacitance retention of up to 94.6% after 10,000 charge-discharge cycles, indicating dramatic cycling stability. Simultaneously, a capacitance retention of nearly 90% can be maintained by the flexible supercapacitor after 180° bends for 1000 times. A viable idea for developing high-performance hydrogel electrolytes and flexible supercapacitors is provided in this research.

Evaluating the Highway Tunnel Construction in Western Sichuan Plateau Considering Vocational Health and Environment.

Oxygen deficiency and coldness are the main challenges for highway tunnel construction in high-altitude areas such as western Sichuan plateau. The artificial oxygen supply and anti-freezing structure in the tunnel construction process has a significant impact on vocational health and the environment. Thus, the conditions of tunnels need to be carefully evaluated before construction. However, the current design code for tunnel construction contains few instructions about these aspects. This paper attempts to establish a simple evaluation method to guide the construction design by analyzing the oxygen partial pressure of trachea, the mean temperature of the coldest month, and the maximum freezing depth for tunnel projects in western Sichuan plateau. Based on the on-site meteorological monitoring at different altitudes of three typical tunnels in the western Sichuan plateau and the comparative analysis of the existing meteorological data, the corresponding relationships between the three parameters and the altitude were investigated. The thresholds by altitude for grading the tunnels are identified as 2100 m and 4200 m, respectively. The highway tunnels in the western Sichuan plateau are graded in three categories, namely, general-altitude tunnels, high-altitude tunnels, and ultra-high-altitude tunnels. The corresponding measures of oxygen supply and freezing prevention for different graded tunnels are recommended. The results would provide a basis for the design and construction of new tunnels and enhance the service life and operations safety of the tunnels in western Sichuan plateau and other similar high-altitude areas.