Synergistic Cr(VI) reduction and adsorption of Cu(II), Co(II) and Ni(II) by zerovalent iron-loaded hydroxyapatite.

Multi-metal contaminated soil, such as Cr(VI), Cu(II), and Co(II), still challenge the environmental remediation. In this work, zerovalent iron-loaded hydroxyapatite (ZVI/HAP) was first applied to simultaneously adsorb multi-metal in contaminated soil. During the remediation, the co-existing Cu(II), Ni(II), and Co(II) were adsorbed and precipitated onto ZVI/HAP. This "spontaneous deposition" simultaneously achieved the adsorption of the cationic metals and improved the isoelectric point of ZVI/HAP to 4.83 from 1.59, thus significantly alleviating the electronegativity to enhance the capture and reduction efficiency of Cr(VI). The application of ZVI/HAP resulted in the reduction of more than 99% of total Cr(VI) in contaminated soil, and the almost complete adsorption of water-soluble and DTPA-extractable Cu, Ni and Co within 20 d. Based on the sequential extraction and risk reduction assessment, soil Cr, Cu, Ni, and Co speciation was transformed from an unstable state (exchangeable and carbonate-bound fractions) to a relatively stable state, reducing the risk of heavy metals in contaminated soil significantly. This study developed an efficient strategy for the remediation of multi-metal contaminated soil.

"In-situ synthesized" iron-based bimetal promotes efficient removal of Cr(VI) in by zero-valent iron-loaded hydroxyapatite.

Anionic Cr(VI) and cationic heavy metals generally co-exist in industrial effluents and threaten the public health. Zero-valent iron (ZVI) particles tent to passivate rapidly, which results in a gradual drop in its reactivity. In this work, a strategy of "in-situ synthesized" iron-based bimetal was first developed to stimulate the self-activation of passivated ZVI. During this process, ZVI-loaded hydroxyapatite (ZVI/HAP) was prepared to enhance the affinity for co-existing Cu2+, which promoted the in-situ Cu0 deposition on ZVI/HAP to form a Fe-Cu bimetal. The deposited Cu0 significantly decreased the activation energy (Ea) of Cr(VI) reduction by 24.9%, and its corresponding Cr(VI) removal (96.53%) was much higher that of single Cr(VI) system (68.67%) within 9 h. More importantly, the removal of Cr(VI) and Cu2+ were synchronously achieved. Systematical electrochemical characterizations were first introduced to explore the galvanic behaviors of iron-based bimetal. The charge transfer resistance and the negative open circuit potential of ZVI/HAP significantly decreased with the Cu0 deposition, thereby accelerating the electron transfer from Fe0 to Cu2+. The enhanced electron transfer further facilitated the Fe(II) release to promote Cr(VI) reduction. This "in-situ synthesized" iron-based bimetal strategy provides a novel pattern for ZVI activation and exhibits practical application in remediation of combined contaminant.

Synergistic chromium(VI) reduction and phenol oxidative degradation by FeS2/Fe0 and persulfate.

It is a challenge to simultaneously treat the combined pollutants of chromium(VI) (Cr(VI)) and organics (such as phenol) in wastewater. Here, a stable and efficient redox system based on FeS2 sulfidated zero valent iron (FeS2/Fe0) and persulfate (PS) was developed to synchronously remove Cr(VI) and phenol. 100% of phenol (10 mg/L) was oxidized in 10 min and Cr(VI) (20 mg/L) was completely reduced to Cr(III) in 90 min in the FeS2/Fe0+PS system with a pH range of 3.0-9.0, respectively. phenol was selectively oxidized without re-oxidizing Cr(III) in such system. The surface-bound Fe2+ was the major reactive species to synchronously reduce Cr(VI) and oxidize phenol. The mechanisms were elucidated that the phenol degradation was accelerated by the generated Cr(III) complexing with its products, and that SO42-, whose production speed was accelerated by the PS activation to oxidize phenol and FeS2, was conductive to corrode Fe0 to regenerate the surface-bound Fe2+ for reducing Cr(VI) and oxidizing phenol. It is potential to develop a high-performance and large-scaled FeS2/Fe0-based redox platform to remediate the complex pollution of Cr(VI) and organics.

Improved spatial-shifting two-wavelength algorithm for 3D shape measurement with a look-up table.

Conventional two-wavelength algorithms have been broadly used for three-dimensional shape measurement. However, the maximum unambiguous range of phase unwrapping depends on the least-common multiple of two wavelengths, and thus coprime wavelengths are commonly selected. The recently proposed spatial-shifting two-wavelength (SSTW) algorithm can achieve the maximum unambiguous range with two non-coprime wavelengths, but this algorithm tends to fail for some wavelength selections. To address this problem, this paper presents a general look-up-table-based SSTW (LUT-SSTW) algorithm with arbitrary wavelength selection. The paper also analyzes the phase unwrapping robustness in terms of phase errors and provides guidance for wavelength selection. In addition, an improved LUT-SSTW algorithm is developed to enhance the phase unwrapping robustness, and further relax wavelength selection. Some experiments have been conducted, and their results verify the efficiency of the proposed method.