RESUMO
With the intensification of human activities, the amount of phosphorus (P)-containing waste has increased. When such waste is not recycled, P is released into the environment, leading to environmental issues such as the eutrophication of water bodies. In this study, based on the material flow analysis method, a P Waste Flow analysis model (P-WFA) was developed to analyze the P flow in the waste system of Poyang Lake, the largest freshwater lake in China. To address the research gap in long-term P flow analysis at the watershed scale, this study quantified the P content in the waste system of the Poyang Lake Watershed from 1950 to 2020. The analysis revealed that from 1950 to 2020, the total P input into the waste system increased from 5.49 × 104 tons in 1950 to 2.28 × 105 tons in 2020. The breeding industry system was identified as the primary source, accounting for 25.19-41.59 % of the total waste system. Over the past 70 years, P loss to surface water from waste systems has been primarily facilitated by manure from the breeding industry, as well as drainage from crop farming systems (77.74 % in 2020). At the same time, the P recycling rate (PRR) of the waste system exhibited an initial increase followed by a decrease, increasing from 44.14 % to 47.75 % before dropping to 44.41 %. Population growth, urbanization, and changes in consumption levels in Jiangxi Province have led to changes in the dietary structure and fertilizer use, consequently affecting the P cycling pattern. This study presents a comprehensive P flow model for waste systems in the Poyang Lake Watershed. This model can be used as a reference to enhance P cycling and manage P loss in other large freshwater lakes.
RESUMO
A magnetic MnFe2O4/MWNT nanocomposite activated with sodium persulfate (PDS) was investigated for the removal of the widely used antibiotic tetracycline (TC). The best-performing 80 wt.% MnFe2O4/MWNT nanocomposite was screened for catalytic degradation of TC by comparing the catalytic and adsorption processes. The nanocomposite was evaluated using a series of physical characterizations. The effects of catalyst dosage, PDS dosage, temperature, initial pH, and initial concentration of TC on TC removal were investigated. After the reaction for 90 min, the addition of 4 mM PDS to the 80 wt.% MnFe2O4/CNT catalyst at 0.5 g/L degraded 78.85% of TC and 51.97% of TOC at an initial TC concentration of 40 mg/L. The reusability of MnFe2O4/MWNT nanocomposite was evaluated and the structural stability of the material was verified. It was demonstrated that multiple active species (SO4-, ·OH, ·O2-, 1O2) were produced in the MnFe2O4/MWNT/PDS system. The catalytic mechanism was analyzed based on the XPS results. Total organic carbon (TOC) measurement indicated partial TC had completely mineralized. The presumable degradation pathway of TC was proposed according to intermediate products by the LC-MS method.