RESUMO
Rechargeable magnesium batteries (RMBs) have received increased attention due to their high volumetric capacity and safety. Nevertheless, the sluggish diffusion kinetics of highly polarized Mg2+ in host lattices severely hinders the development of RMBs. Herein, we report an electron injection strategy for modulating the Mo 4d-orbital splitting manner and first fabricate a dual-phase MoO2.8F0.2/MoO2.4F0.6 heterostructure to accelerate Mg2+ diffusion. The electron injection strategy triggers weak Jahn-Teller distortion in MoO6 octahedra and reorganization of the Mo 4d-orbital, leading to a partial phase transition from orthorhombic phase MoO2.8F0.2 to cubic phase MoO2.4F0.6. As a result, the designed heterostructure generates a built-in electric field, simultaneously improving its electronic conductivity and ionic diffusivity by at least one order of magnitude compared to MoO2.8F0.2 and MoO2.4F0.6. Importantly, the assembled MoO2.8F0.2/MoO2.4F0.6//Mg full cell exhibits a remarkable reversible capacity of 172.5 mAh g-1 at 0.1 A g-1, pushing forward the orbital-scale manipulation for high-performance RMBs.
RESUMO
Recently, aqueous iron ion batteries (AIIBs) using iron metal anodes have gained traction in the battery community as low-cost and sustainable solutions for green energy storage. However, the development of AIIBs is significantly hindered by the limited capacity of existing cathode materials and the poor intercalation kinetic of Fe2+. Herein, we propose a H+ and Fe2+ co-intercalation electrochemistry in AIIBs to boost the capacity and rate capability of cathode materials such as iron hexacyanoferrate (FeHCF) and Na4Fe3(PO4)2(P2O7) (NFPP). This is achieved through an electrochemical activation step during which a FeOOH nanowire layer is formed in situ on the cathode. This layer facilitates H+ co-intercalation in AIIBs, resulting in a high specific capacity of 151 mAh g-1 and 93% capacity retention over 500 cycles for activated FeHCF cathodes. We found that this activation process can also be applied to other cathode chemistries, such as NFPP, where we found that the cathode capacity is doubled as a result of this process. Overall, the proposed H+/Fe2+ co-insertion electrochemistry expands the range of applications for AIBBs, in particular as a sustainable solution for storing renewable energy.
RESUMO
Calcium ion batteries (CIBs) are a promising energy storage device due to the low redox potential of the Ca metal and the abundant reserves of the Ca element. However, the large radius and divalent nature of Ca2+ lead to its slow ion diffusion kinetics and the lack of suitable electrode materials for Ca storage. Here, a layered structure of Na2Ti3O7 (NTO) is presented as an anode material for nonaqueous CIBs. This NTO anode demonstrates a high discharge capacity of 165 mA h g-1 at 100 mA g-1 and a remarkable capacity retention rate of 80%, even after 2000 cycles at 500 mA g-1, surpassing the performance of all reported intercalation-type anode materials for CIBs. The NTO transfers to layered CaVIINaIXTi3O7 (CNTO) with intercalation of Ca2+ and extraction of Na+ during the first discharge process. Then, the CNTO undergoes the reversible insertion/extraction of Ca2+ during subsequent cycling. Additionally, density functional theory calculations reveal that NTO possesses a rapid two-dimensional diffusion pathway for Ca2+. Moreover, the full CIBs based on NTO as the anode further underscore its potential for CIBs. This work presents promising anode materials for CIBs, offering opportunities to promote the development of high-performance CIBs.
RESUMO
In the search for next-generation green energy storage solutions, Cu-S electrochemistry has recently gained attraction from the battery community owing to its affordability and exceptionally high specific capacity of 3350 mAh gs -1. However, the inferior conductivity and substantial volume expansion of the S cathode hinder its cycling stability, while the low output voltage limits its energy density. Herein, a hollow carbon sphere (HCS) is synthesized as a 3D conductive host to achieve a stable S@HCS cathode, which enables an outstanding cycling performance of 2500 cycles (over 9 months). To address the latter, a Zn//S@HCS alkaline-acid decoupled cell is configured to increase the output voltage from 0.18 to 1.6 V. Moreover, an electrode and electrolyte co-energy storage mechanism is proposed to offset the reduction in energy density resulting from the extra electrolyte required in Zn//S decoupled cells. When combined, the Zn//S@HCS alkaline-acid decoupled cell delivers a record energy density of 334 Wh kg-1 based on the mass of the S cathode and CuSO4 electrolyte. This work tackles the key challenges of Cu-S electrochemistry and brings new insights into the rational design of decoupled batteries.
RESUMO
Zinc ion batteries (ZIBs) have emerged as promising candidates for renewable energy storage owing to their affordability, safety, and sustainability. However, issues with Zn metal anodes, such as dendrite growth, hydrogen evolution reaction (HER), and corrosion, significantly hinder the practical application of ZIBs. To address these issues, organic solid electrolyte interface (SEI) layers have gained traction in the ZIB community as they can, for instance, help achieve uniform Zn plating/stripping and suppress side reactions. This article summarizes recent advances in organic artificial SEI layers for ZIB anodes, including their fabrication methods, electrochemical performance, and degradation suppression mechanisms.
RESUMO
Simple magnesium (Mg) salt solutions are widely considered as promising electrolytes for next-generation rechargeable Mg metal batteries (RMBs) owing to the direct Mg2+ storage mechanism. However, the passivation layer formed on Mg metal anodes in these electrolytes is considered the key challenge that limits its applicability. Numerous complex halogenide additives have been introduced to etch away the passivation layer, nevertheless, at the expense of the electrolyte's anodic stability and cathodes' cyclability. To overcome this dilemma, here, we design an electrolyte with a weakly coordinated solvation structure which enables passivation-free Mg deposition while maintaining a high anodic stability and cathodic compatibility. In detail, we successfully introduce a hexa-fluoroisopropyloxy (HFIP-) anion into the solvation structure of Mg2+, the weakly [Mg-HFIP]+ contact ion pair facilitates Mg2+ transportation across interfaces. As a consequence, our electrolyte shows outstanding compatibility with the RMBs. The Mg||PDI-EDA and Mg||Mo6S8 full cells use this electrolyte demonstrating a decent capacity retention of â¼80% over 400 cycles and 500 cycles, respectively. This represents a leap in cyclability over simple electrolytes in RMBs while the rest can barely cycle. This work offers an electrolyte system compatible with RMBs and brings deeper understanding of modifying the solvation structure toward practical electrolytes.
RESUMO
Rechargeable magnesium batteries (RMBs) have garnered significant attention for their potential in large-scale energy storage applications. However, the commercial development of RMBs has been severely hampered by the rapid failure of large-sized Mg metal anodes, especially under fast and deep cycling conditions. Herein, a concept proof involving a large-scale ion-reinforced phytic acid (PA) layer (100 cm × 7.5 cm) with an excellent water-oxygen tolerance, high Mg2+ conductivity, and favorable electrochemical stability is proposed to enable rapid and uniform plating/stripping of Mg metal anode. Guided by even distributions of Mg2+ flux and electric field, the as-prepared large-sized PA-Al@Mg electrode (5.8 cm × 4.5 cm) exhibits no perforation and uniform Mg plating/stripping after cycling. Consequently, an ultralong lifespan (2400 h at 3 mA cm-2 with 1 mAh cm-2) and high current tolerance (300 h at 9 mA cm-2 with 1 mAh cm-2) of the symmetric cell using the PA-Al@Mg anode could be achieved. Notably, the PA-Al@Mg//Mo6S8 full cell demonstrates exceptional stability, operating for 8000 cycles at 5 C with a capacity retention of 99.8%, surpassing that of bare Mg (3000 cycles, 74.7%). Moreover, a large-sized PA-Al@Mg anode successfully contributes to the stable pouch cell (200 and 750 cycles at 0.1 and 1 C), further confirming its significant potential for practical utilization. This work provides valuable theoretical insights and technological support for the practical implementation of RMBs.
RESUMO
Enhancing the activation of peroxymonosulfate (PMS) is essential for generating more reactive oxygen species in advanced oxidation process (AOPs). Nevertheless, improving PMS adsorption and expediting interfacial electron transfer to enhance reaction kinetics pose significant challenges. Herein, we construct confined W18O49 nanowires with asymmetric active centers containing Co-Vo-W (Vo: oxygen vacancy). The design incorporates surface-rich Vo and single-atom Co, and the resulting material is employed for PMS activation in water purification. By coupling unsaturated coordinated electrons in Vo with low-valence Co single atoms to construct an the "electron fountainhead", the adsorption and activation of PMS are enhanced. This results in the generation of more active free radicals (SO4â¢-, â¢OH, â¢O2-) and non-free radicals (1O2) for the decomposition of micropollutants. Thereinto, the degradation rate of bisphenol A (BPA) by Co-W18O49 is 32.6 times faster that of W18O49 monomer, which is also much higher than those of other transition-metal-doped W18O49 composites. This work is expected to help to elucidate the rational design and efficient PMS activation of catalysts with asymmetric active centers.
RESUMO
For the problem of space dynamic target tracking with occlusion, this paper proposes an online tracking method based on the combination between the five-frame difference and Deepsort (Simple Online and Realtime Tracking with a Deep Association Metric), which is to achieve the identification first and then tracking of the dynamic target. First of all, according to three-frame difference, the five-frame difference is improved, and through the integration with ViBe (Visual Background Extraction), the accuracy and anti-interference ability are enhanced; Secondly, the YOLOv5s (You Look Only Once) is improved using preprocessing of DWT (Discrete Wavelet Transformation) and injecting GAM (Global Attention Module), which is considered as the detector for Deepsort to solve the missing in occlusion, and the real-time and accuracy can be strengthened; Lastly, simulation results show that the proposed space dynamic target tracking can keep stable to track all dynamic targets under the background interference and occlusion, the tracking precision is improved to 93.88%. Furthermore, there is a combination with the physical depth camera D435i, experiments on target dynamics show the effectiveness and superiority of the proposed recognition and tracking algorithm in the face of strong light and occlusion.
RESUMO
Emerging aqueous ammonium-ion batteries (AIBs) are considered inexpensive, highly safe, ecofriendly, and sustainable energy storage systems. Although some high-performance electrode materials have been reported for AIBs, a comprehensive understanding of the origin of the high ammonium-ion storage performance is still lacking. Herein, the percolating network of anionic vacancies is determined to be the origin of the superior ammonium-ion storage properties of the Prussian blue analogues based on ab initio molecular dynamics simulation and electrochemical kinetic analyses. Fe[Fe(CN)6] with a percolating anionic vacancy network delivers an outstanding rate of 64.7 mAh g-1 at 2000 mA g-1 in addition to a capacity retention of 94.5% after 10â¯000 cycles. The low-strain intercalation ammonium-ion storage mechanism of highly deficient Fe Prussian blue with Fe as the redox center is revealed by in situ X-ray diffraction and ex situ X-ray absorption fine structure analysis. The results provide insights into the mechanism of ammonium-ion storage in Prussian blue analogues and guidance in the development of aqueous AIBs.