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Petal-like heterojunction materials ZnCo2O4/CoMoO4 with abundant oxygen vacancies are prepared on nickel foam (NF) using modified ionic hybrid thermal calcination technology. Nanoscale ion intermixing between Zn and Mo ions induces oxygen vacancies in the annealing process, thus creating additional electrochemical active sites and enhancing the electrical conductivity. The ZnCo2O4/CoMoO4 conductive network skeleton forms the primary transport pathway for electrons, while the internal electric field of the heterojunction serves as the secondary pathway. ZnCo2O4/CoMoO4 exhibits excellent rate performance and high capacity attributable to its unique double electron transport mode and the effect of oxygen vacancies. The initial discharge capacity at a current of 0.1 A g-1 is approximately 1774 mAh g-1, and the reversible capacity remains at 1100 mAh g-1 after 200 cycles. After a high current of 1 A g-1, the reversible capacity is observed to remain at approximately 1240 mAh g-1. The electronic structure, crystal structure, and work function of the heterojunction interface model are then analyzed by density functional theory (DFT). The analysis results indicate that the charge at the ZnCo2O4/CoMoO4 interface is unevenly distributed, which leads to an enhanced degree of electrochemical reaction. The presence of an internal electric field improves the transport efficiency of the carriers. Experimental and theoretical calculations demonstrate that the ZnCo2O4/CoMoO4 anode material designed in this work provides a reference for fabricating transition metal oxide-based lithium-ion batteries.
RESUMO
The rotating component is an important part of the modern mechanical equipment, and its health status has a great impact on whether the equipment can safely operate. In recent years, convolutional neural network has been widely used to identify the health status of the rotor system. Previous studies are mostly based on the premise that training set and testing set have the same categories. However, because the actual operating conditions of mechanical equipment are complex and changeable, the real diagnostic tasks usually have greater diversity than the pre-acquired datasets. The inconsistency of the categories of training set and testing set makes it easy for convolutional neural network to identify the unknown fault data as normal data, which is very fatal to equipment health management. To overcome the above problem, this article proposes a new method, Huffman-convolutional neural network, to improve the generalization ability of the model in detection task with various operating conditions. First, a new Huffman pooling kernel is designed according to the Huffman coding principle and the Huffman pooling layer structure is introduced in the convolutional neural network to enhance the model's ability to extract common features of data under different conditions. Second, a new objective function is proposed based on softmax loss, intra-class loss, and inter-class loss to improve the Huffman-convolutional neural network's ability to distinguish different classes of data and aggregate the same class of data. Third, the proposed method is tested on three different datasets to verify the generalization ability of the Huffman-convolutional neural network in diagnosis tasks with multi-operating conditions. Compared with other traditional methods, the proposed method has better performance and greater potential in multi-condition fault diagnosis and anomaly detection tasks with inconsistent class spaces.
Assuntos
Generalização Psicológica , Redes Neurais de ComputaçãoRESUMO
Intelligent fault diagnosis of rolling element bearings gains increasing attention in recent years due to the promising development of artificial intelligent technology. Many intelligent diagnosis methods work well requiring massive historical data of the diagnosed object. However, it is hard to get sufficient fault data in advance in real diagnosis scenario and the diagnosis model constructed on such small dataset suffers from serious overfitting and losing the ability of generalization, which is described as small sample problem in this paper. Focus on the small sample problem, this paper proposes a new intelligent fault diagnosis framework based on dynamic model and transfer learning for rolling element bearings race faults. In the proposed framework, dynamic model of bearing is utilized to generate massive and various simulation data, then the diagnosis knowledge learned from simulation data is leveraged to real scenario based on convolutional neural network (CNN) and parameter transfer strategies. The effectiveness of the proposed method is verified and discussed based on three fault diagnosis cases in detail. The results show that based on the simulation data and parameter transfer strategies in CNN, the proposed method can learn more transferable features and reduce the feature distribution discrepancy, contributing to enhancing the fault identification performance significantly.
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The health status of the momentum wheel is vital for a satellite. Recently, research on anomaly detection for satellites has become more and more extensive. Previous research mostly required simulation models for key components. However, the physical models are difficult to construct, and the simulation data does not match the telemetry data in engineering applications. To overcome the above problem, this paper proposes a new anomaly detection framework based on real telemetry data. First, the time-domain and frequency-domain features of the preprocessed telemetry signal are calculated, and the effective features are selected through evaluation. Second, a new Huffman-multi-scale entropy (HMSE) system is proposed, which can effectively improve the discrimination between different data types. Third, this paper adopts a multi-class SVM model based on the directed acyclic graph (DAG) principle and proposes an improved adaptive particle swarm optimization (APSO) method to train the SVM model. The proposed method is applied to anomaly detection for satellite momentum wheel voltage telemetry data. The recognition accuracy and detection rate of the method proposed in this paper can reach 99.60% and 99.87%. Compared with other methods, the proposed method can effectively improve the recognition accuracy and detection rate, and it can also effectively reduce the false alarm rate and the missed alarm rate.
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This paper presents a novel signal processing scheme by combining refined composite hierarchical fuzzy entropy (RCHFE) and random forest (RF) for fault diagnosis of planetary gearboxes. In this scheme, we propose a refined composite hierarchical analysis based method to improve the feature extraction performance of existing MFE and HFE methods. First, RCHFE is applied to extract the fault-induced information from the vibration signals. Because a refined composite analysis is used in HFF, the feature extraction capability of HFF can be effectively enhanced. Then, the extracted features are fed into the RF for effective fault pattern identification. The superiority of the proposed RCHFE-RF method is validated using both simulated and experimental signals. Results show that the proposed method outperforms MFE-RF and HFE-RF in identifying fault types of planetary gearboxes.
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As an important machine component, the gearbox is widely used in industry for power transmission. Condition monitoring (CM) of a gearbox is critical to provide timely information for undertaking necessary maintenance actions. Massive research efforts have been made in the last two decades to develop vibration-based techniques. However, vibration-based methods usually include several inherent shortages including contact measurement, localized information, noise contamination, and high computation costs, making it difficult to be a cost-effective CM technique. In this paper, infrared thermal (IRT) images, which can contain information covering a large area and acquired remotely, are based on developing a cost-effective CM method. Moreover, a convolutional neural network (CNN) is employed to automatically process the raw IRT images for attaining more comprehensive feature parameters, which avoids the deficiency of incomplete information caused by various feature-extraction methods in vibration analysis. Thus, an IRT-CNN method is developed to achieve online remote monitoring of a gearbox. The performance evaluation based on a bevel gearbox shows that the proposed method can achieve nearly 100% correctness in identifying several common gear faults such as tooth pitting, cracks, and breakages and their compounds. It is also especially robust to ambient temperature changes. In addition, IRT also significantly outperforms its vibration-based counterparts.
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Fault diagnosis of rotating machinery is crucial to improve safety, enhance reliability and reduce maintenance cost. The manual feature extraction and selection of traditional fault diagnosis methods depend on signal processing skills and expert experience, which is labor-intensive and time-consuming. As a typical intelligent fault diagnosis method, the convolutional neural network automatically learns features from original data, but it is extremely difficult to design and train a deep network architecture. This paper proposes a fault diagnosis scheme combined of hierarchical symbolic analysis (HSA) and convolutional neural network (CNN), which achieves laborsaving and timesaving preliminary feature extraction and accomplishes automatically feature learning with simplified network architecture. Firstly, hierarchical symbolic analysis is employed to extract features from original signals. The extracted features are able to identify different health conditions under various operating conditions. Then, convolutional neural network instead of human labor is used to learn the complex non-linear relationship between features and health conditions automatically. The architecture of CNN diagnosis model is simple and convenient to implement. Finally, a centrifugal pump dataset and a motor bearing dataset are adopted to validate the effectiveness of the proposed method. The diagnosis results show that the proposed method exhibits superior performance compared with shallow methods and deep learning methods.
RESUMO
Rotating machinery is widely applied in various types of industrial applications. As a promising field for reliability of modern industrial systems, early fault diagnosis (EFD) techniques have attracted increasing attention from both academia and industry. EFD is critical to provide appropriate information for taking necessary maintenance actions and thereby prevent severe failures and reduce financial losses. A massive amounts of research work has been conducted in last two decades to develop EFD techniques. This paper reviews and summarizes the research works on EFD of gears, rotors, and bearings. The main purpose of this paper is to serve as a guidemap for researchers in the field of early fault diagnosis. After a brief introduction of early fault diagnosis techniques, the applications of EFD of rotating machine are reviewed in two aspects: fault frequency-based methods and artificial intelligence-based methods. Finally, a summary and some new research prospects are discussed.
RESUMO
Hydraulic pump is a driving device of the hydraulic system, always working under harsh operating conditions, its fault diagnosis work is necessary for the smooth running of a hydraulic system. However, it is difficult to collect sufficient status information in practical operating processes. In order to achieve fault diagnosis with poor information, a novel fault diagnosis method that is the based on Symbolic Perceptually Important Point (SPIP) and Hidden Markov Model (HMM) is proposed. Perceptually important point technology is firstly imported into rotating machine fault diagnosis; it is applied to compress the original time-series into PIP series, which can depict the overall movement shape of original time series. The PIP series is transformed into symbolic series that will serve as feature series for HMM, Genetic Algorithm is used to optimize the symbolic space partition scheme. The Hidden Markov Model is then employed for fault classification. An experiment involves four operating conditions is applied to validate the proposed method. The results show that the fault classification accuracy of the proposed method reaches 99.625% when each testing sample only containing 250 points and the signal duration is 0.025 s. The proposed method could achieve good performance under poor information conditions.