A novel membrane-free electrochemical separation-filtering crystallization coupling process for treating circulating cooling water.

The traditional electrochemical descaling process exhibits drawbacks, including low OH- utilization efficiency, constrained cathode deposition area, and protracted homogeneous precipitation time. Consequently, this study introduces a novel membrane-free electrochemical separation-filtering crystallization (MFES-FC) coupling process to treat circulating cooling water (CCW). In the membrane-free electrochemical separation (MFES) system, OH- is rapidly extracted by pump suction from the porous cathode boundary layer solution, preventing neutralization with H+, thereby enhancing the removal of Ca2+ and Mg2+. Experimental results indicate that the pH of the pump suction water can swiftly increase from 8.13 to 11.42 within 10 min. Owing to the high supersaturation of the pump suction water, this study couples the MFES with a filtration crystallization (FC) system that employs activated carbon as the medium. This approach captures scale particles to enhance water quality and expedites the homogeneous precipitation of hardness ions, shortening the treatment time while further augmenting the removal rate. After the MFES-FC treatment, the single-pass removal rates for total hardness, Ca2+ hardness, Mg2+ hardness, and alkalinity in the effluent reached 92 %, 97 %, 64 %, and 67 %, respectively, with turbidity of 3 NTU, current efficiency of 86.6 %, and energy consumption of 7.19 kWh·kg-1 CaCO3. This coupling process facilitates an effective removal of hardness and alkalinity at a comparatively low cost, offering a new reference and inspiration for advancements in electrochemical descaling technology.

Advances on electrochemical disinfection research: Mechanisms, influencing factors and applications.

Disinfection, a vital barrier against pathogenic microorganisms, is crucial in halting the spread of waterborne diseases. Electrochemical methods have been extensively researched and implemented for the inactivation of pathogenic microorganisms from water and wastewater, primarily owing to their simplicity, efficiency, and eco-friendliness. This review succinctly outlined the core mechanisms of electrochemical disinfection (ED) and systematically examined the factors influencing its efficacy, including anode materials, system conditions, and target species. Additionally, the practical application of ED in water and wastewater treatment was comprehensively reviewed. Case studies involving various scenarios such as drinking water, hospital wastewater, black water, rainwater, and ballast water provided concrete instances of the expansive utility of ED. Finally, coupling ED with other technologies and the resulting synergies were introduced as pivotal foundations for subsequent engineering advancements.

Suppressing the Shuttle Effect and Dendrite Growth in Lithium-Sulfur Batteries.

Practical applications of lithium-sulfur batteries are simultaneously hindered by two serious problems occurring separately in both electrodes, namely, the shuttle effects of lithium polysulfides and the uncontrollable growth of lithium dendrites. Herein, to explore a facile integrated approach to tackle both problems as well as guarantee the efficient charge transfer, we used two-dimension hexagonal VS2 flakes as the building blocks to assemble nanotowers on the separators, forming a symmetrical double-side-modified polypropylene separator without blocking the membrane pores. Benefiting from the "sulfiphilic" and "lithiophilic" properties, high interfacial electronic conductivity, and the unique hexagonal tower-form nanostructure, the D-HVS@PP separator not only guarantees the effective suppression of the lithium polysulfide shuttle and the rapid ion/electron transfer but also realizes uniform and stable lithium nucleation and growth during cycling. Hence, just at the expense of an 11% increase in the separator weight (0.14 mg cm-2), the D-HVS@PP separator delivers an over 16 times higher initial areal capacity (8.3 mAh cm-2) than a conventional PP separator (0.5 mAh cm-2) under high sulfur-loading conditions (9.24 mg cm-2). Even when used under a low electrolyte/sulfur ratio of 4 mL g-1 and a practically relevant N/P ratio of 1.7, the D-HVS@PP separator still enabled stable cycling with a high cell-level gravimetric energy density. The potentials in broader applications (Li-S pouch battery and Li-LiFePO4 battery) and the promising commercial prospect (large-scale production and recyclability) of the developed separator are also demonstrated.

Synthesis of 2-Amino-5-acylthiazoles by a Tertiary Amine-Promoted One-Pot Three-Component Cascade Cyclization Using Elemental Sulfur as a Sulfur Source.

A novel one-pot three-component cascade cyclization strategy for the synthesis of 2-amino-5-acylthiazoles using enaminones, cyanamide, and elemental sulfur has been developed. The reported methods have demonstrated good tolerance of various functional groups. Up to 28 2-amino-5-acylthiazole compounds bearing diverse structural differences were successfully synthesized from easily obtained starting materials with moderate to excellent yields. Our method provides an effective way for the access of valuable and potentially bioactive 2-amino-5-acylthiazole derivatives.