The mitigation potential of synergistic quorum quenching and antibacterial properties for biofilm proliferation and membrane biofouling.

Biofouling has been a persistent problem hindering the application of membranes in water treatment, and quorum quenching has been identified as an effective method for mitigating biofouling, but surface accumulation of live bacteria still induces biofilm secretion, which poses a significant challenge for sustained prevention of membrane biofouling. In this study, we utilized quercetin, a typical flavonoid with the dual functions of quorum quenching and bacterial inactivation, to evaluate its role in preventing biofilm proliferation and against biofouling. Quercetin exhibited excellent antibacterial activity against Escherichia coli (E. coli) and Staphylococcus aureus (S. aureus), and the decreased bioactivity was positively correlated with the quercetin concentration, with inhibition rates of 53.1 % and 57.4 %, respectively, at the experimental concentrations. The RT-qPCR results demonstrated that quercetin inhibited AI-2 of E. coli and AGR of S. aureus mediated quorum sensing system, and reduced the expression of genes such as adhesion, virulence, biofilm secretion, and key regulatory proteases. As a result, the bacterial growth cycle was retarded and the biomass and biofilm maturation cycles were alleviated with the synergistic effect of quorum quenching and antibacterial activity. In addition, membrane biofouling was significantly declined in the dynamic operation experiments, dead cells in the biofilm overwhelmingly dominated, and the final normalized water fluxes were increased by more than 49.9 % and 34.5 % for E. coli and S. aureus, respectively. This work demonstrates the potential for mitigating biofouling using protocols that quorum quenching and inactivate bacteria, also provides a unique and long-lasting strategy to alleviate membrane fouling.

Removal ibuprofen from aqueous solution by a noval Al-modified biochar.

With the increase of organic emissions in production and human life, the pollution control of organic is now an urgent problem in the environmental field. In this study, hydrothermal carbonization rice husk-loaded Al-modified biochar (Al-BC) was synthesized, and the results of scanning electron microscopy could be used to determine that Al oxide composite was loaded on the surface of the material. The specific surface area was 57.049 m2 g-1, pore volume was 0.254 cm3 g-1, and average pore diameter was 8.922 nm for BC and 109.617 m2 g-1, 0.215 cm3 g-1, and 3.969 nm for Al-BC, respectively. The control effects of these two adsorption materials on organic pollutant ibuprofen (IBU) under different pH conditions were also investigated. The research results show that the adsorption capacity of Al-BC (30.24-1.48 mg g-1) is better than BC (19.98-0.92 mg g-1) at pH from 2 to 11. Solution pH plays a crucial role in IBU adsorption from organic solution. The Langmuir fitting results show that at pH = 7, the saturated adsorption capacity of IBU on BC could reach up to 18.68 mg g-1; the adsorption capacity on Al-BC was 60.49 mg g-1. The thermodynamic parameters indicate that the adsorption is spontaneous, endothermic, and increased disorder. The adsorption material prepared in this study could provide a reference for organic pollution control in water.

Modified biochar/humic substance/fertiliser compound soil conditioner for highly efficient improvement of soil fertility and heavy metals remediation in acidic soils.

Fertile and uncontaminated soil with appropriate pH is crucial in terms of the agricultural sustainable development. Herein, a compound soil conditioner containing chitosan modified straw biochar (CBC), kitchen waste compost product-derived humic substance (HS), NPK compound fertiliser (NPK-CF) was prepared to simultaneously adjust acidic soil pH, improve fertility, and immobilize heavy metal. The results exhibited that the best Pb and NH4+ adsorption performance was obtained in CBC with chitosan:biochar of 1:5. Then, the acid soil pH was improved from 5.03 to 6.66 in the presence of CBC/HS (5:5) with 3% addition weight (the mass ratio of conditioner to soil). Meanwhile, compared with the control, the contents of organic matter, available nitrogen, and available phosphorus significantly increased by 52.4%, 92.6%, and 136.3%, respectively. Moreover, Pb was highly efficient immobilised by CBC, and the concentration of Pb in the soil was decreased by 55.2%. The optimal growth trend of ryegrass was obtained in the presence of 3% addition weight (the mass ratio of conditioner to soil) CBC/HS (CBC:HS = 5:5) combined with 60% of the recommended NPK-CF application weight, which was mainly contributed by the improvement of the soil microbial abundance and community structure diversity. The addition of CBC/HS could effectively reduce the addition of NPK-CF and contribute to simultaneous controlling nitrogen loss, releasing phosphorus, immobilising Pb, adjusting pH, improving soil quality and controlling nonpoint pollution.

Persulfate-enhanced continuous flow three-dimensional electrode dynamic reactor for treatment of landfill leachate.

Compared with sequencing batch reactor, continuous flow dynamic reactors are more conducive to promotion and application. In this study, the ability of a three-dimensional (3D) electrode dynamic reactor to remove pollutants in the landfill leachate was investigated, in which landfill leachate entered through continuous flow. Either increased of current density or the decreased of flow rate was conducive to the removal of pollutants. The optimal process parameters for current density and flow rate were 16 mA cm-2 and 0.75 L h-1, respectively. When the current density was constant at 16 mA cm-2 and the flow rate was kept at 0.75 L h-1, 60.02% of total organic carbon (TOC), 96.50% of chroma, 64.98% of chemical oxygen demand (COD) and 99.46% of ammonia nitrogen (NH3-N) were removed. The characteristic peaks of refractory organic pollutants were reduced by 97.95%. After the reaction, the biological oxygen demand (BOD)/COD was increased from 0.24 to 0.32. As one of the emerging trace organics in landfill leachate, 85.90% of ibuprofen (IBU) was removed. The results showed that the 3D electrode dynamic reactor constructed in this study could reduce the TOC, refractory trace organic pollutant, NH3-N and chroma in the landfill leachate. The 3D electrode dynamic reactor constructed in this research has application potential in the field of landfill leachate treatment.

Biochar raw material selection and application in the food chain: A review.

As one of the largest carbon emitters, China promises to achieve carbon emissions neutrality by 2060. Various industries are developing businesses to reduce carbon emissions. As an important greenhouse gas emissions scenario, the reduction of carbon emissions in the food chain can be achieved by preparing the wastes into biochar. The food chain, as one of the sources of biochar, consists of production, processing and consumption, in which many wastes can be transferred into biochar. However, few studies use the food chain as the system to sort out the raw materials of biochar. A systematic review of the food chain application in serving as raw materials for biochar is helpful for further application of such technique, providing supportive information for the development of biochar preparation and wastes treating. In addition, there are many pollution sources in the food production process, such as agricultural contaminated soil and wastewater from livestock and aquatic, that can be treated on-site to achieve the goal of treating wastes with wastes within the food chain. This study focuses on waste resource utilization and pollution remediation in the food chain, summarizing the sources of biochar in the food chain and analyzing the feasibility of using waste in food chain to treat contaminated sites in the food chain and discussing the impacts of the greenhouse gas emissions. This review provides a reference for the resource utilization of waste and pollution reduction in the food chain.

Application fields of kitchen waste biochar and its prospects as catalytic material: A review.

In China, a large amount of kitchen waste (KW) is generated each year, and the resource utilisation of the KW has become a problem. KW has a high carbon content and can be used as a raw material for biochar. Kitchen waste biochar (KWB) can be used to prepare adsorption materials, soil amendments, energy materials, carbon quantum dots, and electrode materials. However, few studies have used KWB as a raw material for catalytic materials. The application of sulfur (S) and nitrogen (N) doped biochar in the field of catalysis has proved effective and feasible. KWB contained a certain mass percentage of N and S elements, which has good application potential for use in the field of catalysis by KWB. In the process of preparing KWB by KW, keeping S and N as much as possible and converting them into pyridine N and thiophene S benefit the application of catalysis. This review provides a reference for the future application of KWB in China.

A review on the landfill leachate treatment technologies and application prospects of three-dimensional electrode technology.

With the expansion of urbanisation, the total amount of solid waste produced by urban residents has been increasing, and the problem of municipal solid waste disposal has also been aggravated. Landfill leachate treatment technologies could be divided into three categories: biological, physical and advanced oxidation treatment technology. Among them, advanced oxidation treatment technology has a good effect on the treatment of landfill leachate with little secondary pollution and has excellent application potential. Three-dimensional (3D) electrode technology, as a new type of advanced oxidation technology, could remove refractory pollutants in water and has attracted considerable attention. This article aims to (1) compare existing landfill leachate treatment technologies, (2) summarise 3D electrode technology application scenarios, (3) discuss the advantages of 3D electrode technology in landfill leachate treatment and (4) look ahead the future directions of 3D electrode technology in landfill leachate treatment. We hope that this article will be helpful to researchers who are interested in the field of landfill leachate treatment.

Recognition of Badminton Shot Action Based on the Improved Hidden Markov Model.

In recent years, with the rapid development of sports, the number of people playing various sports is increasing day by day. Among them, badminton has become one of the most popular sports because of the advantages of fewer restrictions on the field and ease of learning. This paper develops a wearable sports activity classification system for accurately recognizing badminton actions. A single acceleration sensor fixed on the end of the badminton racket handle is used to collect the data of the badminton action. The sliding window segmentation technique is used to extract the hitting signal. An improved hidden Markov model (HMM) is developed to identify standard 10 badminton strokes. These include services, forehand chop, backhand chop the goal, the forehand and backhand, forehand drive, backhand push the ball, forehand to pick, pick the ball backhand, and forehand. The experimental results show that the model designed can recognize ten standard strokes in real time. Compared with the traditional HMM, the average recognition rate of the improved HMM is improved by 7.3%. The comprehensive recognition rate of the final strokes can reach up to 95%. Therefore, this model can be used to improve the competitive level of badminton players.

Removal of ibuprofen by sodium alginate-coated iron-carbon granules combined with the ultrasound and Fenton technologies: influencing factors and degradation intermediates.

This study focuses on the preparation of sodium alginate-coated iron-carbon granules (FeCGs) and their capacity to remove ibuprofen (IBU) by combining Fenton and ultrasound technologies. The preferred preparation conditions are as follows: 2% (w/v) sodium alginate, 10% (w/v) iron fillings and biochar, and used CaCl2 as the cross-linking agent. 74.72% of IBU was removed by ultrasound/FeCG under 10 g/L FeCG and 250 W ultrasound power. Fenton/FeCG could remove 92.41% of IBU under 10 g/L FeCG and 2 mM H2O2. Under the above experimental conditions, ultrasound/FeCG has higher reaction speed (9.44 × 10-3 min-1) than Fenton/FeCG (4.95 × 10-3 min-1). However, Fenton/FeCG could remove more TOC than ultrasound/FeCG. During the reaction using the Fenton/FeCG system, 11 degradation intermediates were detected, but only 7 intermediates were produced by the ultrasound/FeCG system. A common single-chain product C5H10O3 formed by IBU degradation was detected in the reaction products during Fenton/FeCG reaction, which benzene ring structure was destroyed; however, the minimum molecular weight of the product detected using the ultrasound/FeCG system was that of C8H10O; the benzene ring structure of IBU is not destroyed. This study provides guidance in the preparation of sodium alginate-coated FeCGs, evaluating the applicability of Fenton/FeCG and ultrasound/FeCG, which was meaningful for organic pollution wastewater treatment.

Electrochemical treatment of organic pollutants in landfill leachate using a three-dimensional electrode system.

The use of three-dimensional electrode is a new electrochemical oxidation technology for landfill leachate treatment. In this study, a particle electrode was developed using Fe/C granules, which were suspended between the cathode and the anode to create a three-dimensional electrode. The three-dimensional electrode activated sodium persulfate to treat landfill leachate. Fe/C granules were prepared by incorporating iron filings and hydrothermally carbonized biochar into alginate beads. The optimal parameters of the three-dimensional electrode for chemical oxygen demand (COD) removal from landfill leachate were determined based on a series of single factor experiments as an operating voltage of 5 V, a sodium persulfate concentration of 28 mM, and 1 g of Fe/C granules. Treatment with the three-dimensional electrode at optimized conditions achieved 72.9% removal of COD and 99.9% removal of ammonia nitrogen, resulting in landfill leachate being clear and transparent. The changes in total organic carbon, nitrite, and nitrate concentrations indicated that most organic pollution and ammonia nitrogen were converted into CO2 and N2. This study provides an alternative technology for the treatment of refractory organic pollutants.