Zero Threshold for Water Adsorption on MAPbBr3.

Hybrid organic-inorganic perovskites (HOIPs) have shown great promise in a wide range of optoelectronic applications. However, this performance is inhibited by the sensitivity of HOIPs to various environmental factors, particularly high levels of relative humidity. This study uses X-ray photoelectron spectroscopy (XPS) to determine that there is essentially no threshold to water adsorption on the in situ cleaved MAPbBr3 (001) single crystal surface. Using scanning tunneling microscopy (STM), it shows that the initial surface restructuring upon exposure to water vapor occurs in isolated regions, which grow in area with increasing exposure, providing insight into the initial degradation mechanism of HOIPs. The electronic structure evolution of the surface was also monitored via ultraviolet photoemission spectroscopy (UPS), evidencing an increased bandgap state density following water vapor exposure, which is attributed to surface defect formation due to lattice swelling. This study will help to inform the surface engineering and designs of future perovskite-based optoelectronic devices.

Review on the oxidative catalysis methods of converting lignin into vanillin.

Vanillin plays an important role not only in food and flavouring, but also as a platform compound for the synthesis of other valuable products, mainly derived from the oxidative decarboxylation of petroleum-based guaiacol production. In order to alleviate the problem of collapsing oil resources, the preparation of vanillin from lignin has become a good option from the perspective of environmental sustainability, but it is still not optimistic in terms of vanillin production. Currently, catalytic oxidative depolymerization of lignin for the preparation of vanillin is the main development trend. This paper mainly reviews four ways of preparing vanillin from lignin base: alkaline (catalytic) oxidation, electrochemical (catalytic) oxidation, Fenton (catalytic) oxidation and photo (catalytic) oxidative degradation of lignin. In this work, the working principles, influencing factors, vanillin yields obtained, respective advantages and disadvantages and the development trends of the four methods are systematically summarized, and finally, several methods for the separation and purification of lignin-based vanillin are briefly reviewed.

Relationship between the Change in E/T Ratio and the Cooking Performance of Eucalyptus and Acacia Woods during Kraft Pulping Process.

Lignin structure is an important factor affecting the cooking part of the pulping process. In this study, the effect of lignin side chain spatial configuration on cooking performance was analyzed, and the structural characteristics of eucalyptus and acacia during cooking were compared and studied by combining ozonation, GC-MS, NBO, and 2D NMR (1H-13C HSQC). In addition, the changes in the lignin content of four different raw materials during the cooking process were studied via ball milling and UV spectrum analysis. The results showed that the content of lignin in the raw material decreased continuously during the cooking process. Only in the late cooking stage, when the lignin removal reached its limit, did the lignin content tend to be stable due to the polycondensation reaction of lignin. At the same time, the E/T ratio and S/G ratio of the reaction residual lignin also followed a similar rule. At the beginning of cooking, the values of E/T and S/G decreased rapidly and then gradually rose when they reached a low point. The different initial E/T and S/G values of different raw materials lead to the disunity of cooking efficiency and the different transformation rules of different raw materials in the cooking process. Therefore, the pulping efficiency of different raw materials can be improved using different technological means.

Preparation of Symmetrical Capacitors from Lignin-Derived Phenol and PANI Composites with Good Electrical Conductivity.

As a natural polymer, lignin is only less abundant in nature than cellulose. It has the form of an aromatic macromolecule, with benzene propane monomers connected by molecular bonds such as C-C and C-O-C. One method to accomplish high-value lignin conversion is degradation. The use of deep eutectic solvents (DESs) to degrade lignin is a simple, efficient and environmentally friendly degradation method. After degradation, the lignin is broken due to ß-O-4 to produce phenolic aromatic monomers. In this work, lignin degradation products were evaluated as additives for the preparation of polyaniline conductive polymers, which not only avoids solvent waste but also achieves a high-value use of lignin. The morphological and structural characteristics of the LDP/PANI composites were investigated using 1H NMR, Fourier-transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy, thermogravimetric analysis and elemental analysis. The LDP/PANI nanocomposite provides a specific capacitance of 416.6 F/g at 1 A/g and can be used as a lignin-based supercapacitor with good conductivity. Assembled as a symmetrical supercapacitor device, it provides an energy density of 57.86 Wh/kg, an excellent power density of 952.43 W/kg and, better still, a sustained cycling stability. Thus, the combination of polyaniline and lignin degradate, which is environmentally friendly, amplifies the capacitive function on the basis of polyaniline.

Dual Network Hydrogel with High Mechanical Properties, Electrical Conductivity, Water Retention and Frost Resistance, Suitable for Wearable Strain Sensors.

With the progress of science and technology, intelligent wearable devices have become more and more popular in our daily life. Hydrogels are widely used in flexible sensors due to their good tensile and electrical conductivity. However, traditional water-based hydrogels are limited by shortcomings of water retention and frost resistance if they are used as the application materials of flexible sensors. In this study, the composite hydrogels formed by polyacrylamide (PAM) and TEMPO-Oxidized Cellulose Nanofibers (TOCNs) are immersed in LiCl/CaCl2/GI solvent to form double network (DN) hydrogel with better mechanical properties. The method of solvent replacement give the hydrogel good water retention and frost resistance, and the weight retention rate of the hydrogel was 80.5% after 15 days. The organic hydrogels still have good electrical and mechanical properties after 10 months, and can work normally at -20 °C, and has excellent transparency. The organic hydrogel show satisfactory sensitivity to tensile deformation, which has great potential in the field of strain sensors.

Soil heavy metal pollution and food safety in China: Effects, sources and removing technology.

Soil plays a fundamental role in food safety and the adverse effects of contaminants like heavy metal (loid)s on crop quality have threatened human health. Therefore, it is important to focus on the food safety and agricultural soil pollution by heavy metals, especially for China where the demand for food production is increasing. This review comprehensively introduced the current status of agricultural soil pollution by heavy metals in China, analyzed the main sources of contaminants, including the applications of pesticides and fertilizers, atmospheric deposition related to vehicle emissions and coal combustion, sewage irrigation and mining. Food safety and agricultural soil pollution by heavy metals, the removal technologies for soil remediation such as soil amendments, phytoremediation and foliar sprays were also introduced. The review can provide significant insights for policymakers, environmental engineers, and agro-technicians regarding soil contamination control and management strategies and technologies.

Correlations between health-promoting lifestyle and health-related quality of life among elderly people with hypertension in Hengyang, Hunan, China.

Hypertension is considered as an important public health problem in developed and developing countries. The disease is closely associated with health-promoting lifestyle (HPL), and it seems that HPL plays an important role in improving health-related quality of life (HRQOL). This cross-sectional study is to investigate the effects of health-promoting lifestyle (HPL) on health-related quality of life in elderly people with hypertension from a community health service center in Hengyang, Hunan, PR China.Totally 530 elderly patients with hypertension from the community health service center were included in this study, who were asked to fill in a questionnaire (504 patients responded). HPL was assessed by the health-promoting lifestyle profile II (HPLP-II), and HRQOL was measured by the Short Form Health Survey Questionnaire (SF-36).HPL among these elderly people with hypertension was at moderate level (125.02 ±â€Š21), with the highest score for nutrition and the lowest score for health responsibility. Moreover, HRQOL among these elderly hypertensive people was at moderate level (54.36 ±â€Š21.18). Role-emotional domain score was far below average, vitality domain was a little below average, social functioning and general health domains were a little above average, and other domains were far above average. Furthermore, HPL and HRQOL were positively correlated (P < .01). According to the standardized regression coefficients, the influencing factors for HRQOL included (in a descending order) the health responsibility, physical activity, interpersonal relationships, stress management, spiritual growth, and nutrition.HPL and HRQOL were both relatively poor in the elderly people with hypertension from the community health service center. HPL represents an important factor affecting HRQOL of elderly people with hypertension. HRQOL could be improved through promoting HPL (such as health responsibility and physical activity).

Enhanced removal of Cr(VI) from aqueous solution by supported ZnO nanoparticles on biochar derived from waste water hyacinth.

Biochar derived from waste water hyacinth was prepared and modified by ZnO nanoparticles for Cr(VI) removal from aqueous solution with the aim of Cr(VI) removal and management of waste biomass. The effect of carbonization temperature (500-800 °C), ZnO content (10-50 wt%) loaded on biochar and contact time (0.17-14 h) on the Cr(VI) removal were investigated. It was found that higher than 95% removal efficiency of Cr(VI) can be achieved with the biochar loaded 30 wt% ZnO. The adsorption kinetics of the sorbent is consistent with the pseudo-second-order kinetic model and adsorption isotherm follows the Langmuir model with maximum adsorption capacity of 43.48 mg g-1 for Cr(VI). Multiple techniques such as XRD, XPS, SEM, EDX and FT-IR were performed to investigate the possible mechanisms involved in the Cr (VI) adsorption. The results show that there is precipitation between chromium ions and Zn oxide. Furthermore, the ZnO nanoparticles acts as photo-catalyst to generate photo-generated electrons to enhance the reduction of Cr(VI) to Cr(III). The as-prepared ZnO/BC possess good recyclability and the removal ratio remained at about 70% in the fifth cycle, which suggests that both contaminants removal and effective management of water hyacinth can be achieved by the approach.

Fe3+-Doped TiO2 Nanotube Arrays on Ti-Fe Alloys for Enhanced Photoelectrocatalytic Activity.

Highly ordered, vertically oriented Fe3+-doped TiO2 nanotube arrays (Fe-TNTs) were prepared on Ti-Fe alloy substrates with different Fe contents by the electrochemical anodization method. The as-prepared Fe-TNTs were characterized by scanning electron microscope (SEM), transmission electron microscopy (TEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and related electrochemical techniques. XPS results demonstrated that Fe3+ ions were successfully doped into TiO2 nanotubes. The photoelectrochemical activity of Fe-TNTs was compared with that of pure TiO2 nanotube arrays (TNTs). The results showed that Fe-TNTs grown on low concentration (0.5 wt %-1 wt % Fe) Ti-Fe alloys possessed higher photocurrent density than TNTs. The Fe-TNTs grown on Ti-Fe alloy containing 0.8 wt % Fe exhibited the highest photoelectrochemical activity and the photoelectrocatalytic degradation rate of methylene blue (MB) aqueous solution was significantly higher than that of TNTs.