The Defect Passivation of Tin Halide Perovskites Using a Cesium Iodide Modification.

Tin-based perovskites are promising for realizing lead-free perovskite solar cells; however, there remains a significant challenge to achieving high-performance tin-based perovskite solar cells. In particular, the device fill factor was much lower than that of other photovoltaic cells. Therefore, understanding how the fill factor was influenced by device physical mechanisms is meaningful. In this study, we reported a method to improve the device fill factor using a thin cesium iodide layer modification in tin-based perovskite cells. With the thin passivation layer, a high-quality perovskite film with larger crystals and lower charge carrier densities was obtained. As a result, the series resistance of devices was decreased; the shunt resistance of devices was increased; and the non-radiative recombination of devices was suppressed. Consequently, the fill factor, and the device efficiency and stability were greatly enhanced. The champion tin-based perovskite cells showed a fill factor of 63%, an efficiency of 6.1% and excellent stability. Our study reveals that, with a moderate thin layer modification strategy, the long-term stability of tin-based PSCs can be developed.

Hole Transport Materials for Tin-Based Perovskite Solar Cells: Properties, Progress, Prospects.

The power conversion efficiency of modern perovskite solar cells has surpassed that of commercial photovoltaic technology, showing great potential for commercial applications. However, the current high-performance perovskite solar cells all contain toxic lead elements, blocking their progress toward industrialization. Lead-free tin-based perovskite solar cells have attracted tremendous research interest, and more than 14% power conversion efficiency has been achieved. In tin-based perovskite, Sn2+ is easily oxidized to Sn4+ in air. During this process, two additional electrons are introduced to form a heavy p-type doping perovskite layer, necessitating the production of hole transport materials different from that of lead-based perovskite devices or organic solar cells. In this review, for the first time, we summarize the hole transport materials used in the development of tin-based perovskite solar cells, describe the impact of different hole transport materials on the performance of tin-based perovskite solar cell devices, and summarize the recent progress of hole transport materials. Lastly, the development direction of lead-free tin-based perovskite devices in terms of hole transport materials is discussed based on their current development status. This comprehensive review contributes to the development of efficient, stable, and environmentally friendly tin-based perovskite devices and provides guidance for the hole transport layer material design.

Research on the Frequency Response and Dynamic Range of the Quadrature Fiber Optic Fabry-Perot Cavity Microphone Based on the Differential Cross Multiplication Demodulation Algorithm.

A quadrature fiber optic Fabry-Perot cavity microphone based on a differential cross multiplication algorithm consists of a pair of fibers and a membrane. It has many advantages such as high sensitivity, a simple structure, and resistance to electromagnetic interference. However, there are no systematic studies on its key performance, for example, its frequency response and dynamic range. In this paper, a comprehensive study of these two key parameters is carried out using simulation analysis and experimental verification. The upper limit of the frequency response range and the upper limit of the dynamic range influence each other, and they are both affected by the data sampling rate. At a certain data sampling rate, the higher the upper limit of the frequency response range is the lower the upper limit of the dynamic range. The quantitative relationship between them is revealed. In addition, these two key parameters also are affected by the quadrature phase deviation. The quadrature phase deviation should not exceed 0.25π under the condition that the demodulated signal intensity is not attenuated by more than 3 dB. Subsequently, a short-step quadrature Fabry-Perot cavity method is proposed, which can suppress the quadrature phase deviation of the quadrature fiber optic Fabry-Perot cavity microphone based on the differential cross multiplication algorithm.

Analysis of phase response of fiber Fabry-Pérot cavity microphones.

In this paper, the phase response of fiber Fabry-Pérot cavity-based fiber optic microphones (FFPC-FOMs) is discussed through an analysis of the results of simulation and experiments. The phase difference of FFPC-FOMs mainly originates from two aspects: different phase lags of the mechanical-acoustic systems and different quadrature working points (Q*) on interference curves. The former is analyzed by an impedance-type analogous circuit, and the simulation results reveal that the change in cavity length and resonance frequency in a large range have an insignificant influence on the phase difference. The latter shows a unique effect on the phase difference and causes the phase of FFPC-FOMs to be either in or out of phase. The phase differences of four samples of FFPC-FOMs with different cavity lengths and resonance frequencies are measured in the frequency range 50 Hz-4 kHz. Experimental results of the phase difference are well consistent with simulation results. All samples of FFPC-FOMs can be divided into two groups: one is near 0° and the other is near 180°. In addition, the FFPC-FOMs in each group have good phase consistency for the array applications.

Femtosecond laser fabricated all-optical fiber sensors with ultrahigh refractive index sensitivity: modeling and experiment.

All-optical fiber sensors based on ultracompact fiber inline Mach-Zehnder interferometer (MZI) are fabricated by side-ablating a U-shape microcavity in a single-mode optical fiber with the fiber core partially removed using femtosecond (fs) laser pulses, in which the two light paths are accordingly formed in the remaining D-type fiber core and the U-shape microcavity. Beam propagation method (BPM) analysis is utilized to illustrate the dependences of good transmission spectra on parameters including the ablation depth, ablation length and the refractive index of U-shape micocavity, which gives some guidelines to optimize parameters for fs laser micromachining and predicts RI (refractive index) sensitivities within given RI ranges. The modeling results of ultrahigh RI sensitivities for gases and solutions are -3243.75 ± 0.65nm/RIU (refractive index unit) and -10789.29 ± 18.91nm/RIU, respectively. In RI testing experiments, the sensor exhibits ultrahigh RI sensitivities of -3754.79 ± 44.24nm/RIU with refractive indices ranging from 1.0001143 to 1.0002187 by testing different mixture ratios of N2 and He gases, and -12162.01 ± 173.92nm/RIU with refractive indices ranging from 1.3330 to 1.33801 by testing different concentrations of sucrose solutions, which is essentially in agreement with the modeling results.

A high-quality Mach-Zehnder interferometer fiber sensor by femtosecond laser one-step processing.

During new fiber sensor development experiments, an easy-to-fabricate simple sensing structure with a trench and partially ablated fiber core is fabricated by using an 800 nm 35 fs 1 kHz laser. It is demonstrated that the structure forms a Mach-Zehnder interferometer (MZI) with the interference between the laser light passing through the air in the trench cavity and that in the remained fiber core. The fringe visibilities are all more than 25 dB. The transmission spectra vary with the femtosecond (fs) laser ablation scanning cycle. The free spectral range (FSR) decreases as the trench length increases. The MZI structure is of very high fabrication and sensing repeatability. The sensing mechanism is theoretically discussed, which is in agreement with experiments. The test sensitivity for acetone vapor is about 10(4) nm/RIU, and the temperature sensitivity is 51.5 pm/°C at 200 ∼ 875 °C with a step of 25 °C.