100 km wear-free sliding achieved by microscale superlubric graphite/DLC heterojunctions under ambient conditions.

Wear-free sliding between two contacted solid surfaces is the ultimate goal in the effort to extend the lifetime of mechanical devices, especially when it comes to inventing new types of micro-electromechanical systems where wear is often a major obstacle. Here we report experimental observations of wear-free sliding for a micrometer-sized graphite flake on a diamond-like-carbon (DLC) surface under ambient conditions with speeds up to 2.5 m/s, and over a distance of 100 km. The coefficient of friction (COF) between the microscale graphite flake, a van der Waals (vdW) layered material and DLC, a non-vdW-layered material, is measured to be of the order of [Formula: see text], which belongs to the superlubric regime. Such ultra-low COFs are also demonstrated for a microscale graphite flake sliding on six other kinds of non-vdW-layered materials with sub-nanometer roughness. With a synergistic analysis approach, we reveal the underlying mechanism to be the combination of interfacial vdW interaction, atomic-smooth interfaces and the low normal stiffness of the graphite flake. These features guarantee a persistent full contact of the interface with weak interaction, which contributes to the ultra-low COFs. Together with the extremely high in-plane strength of graphene, wear-free sliding is achieved. Our results broaden the scope of superlubricity and promote its wider application in the future.

Negative friction coefficient in microscale graphite/mica layered heterojunctions.

The friction of a solid contact typically shows a positive dependence on normal load according to classic friction laws. A few exceptions were recently observed for nanoscale single-asperity contacts. Here, we report the experimental observation of negative friction coefficient in microscale monocrystalline heterojunctions at different temperatures. The results for the interface between graphite and muscovite mica heterojunction demonstrate a robust negative friction coefficient both in loading and unloading processes. Molecular dynamics simulations reveal that the underlying mechanism is a synergetic and nontrivial redistribution of water molecules at the interface, leading to larger density and more ordered structure of the confined subnanometer-thick water film. Our results are expected to be applicable to other hydrophilic van der Waals heterojunctions.