Michael Addition Inducing Self-Assembly to Construct Mechanochromic BP Film.

Liquid crystalline blue phase (BP) with 3D cubic nanostructure has attracted much interest in the fields of photonic crystals due to their unique optical properties and the ability to control the flow of light. However, there remains a challenge for simultaneously achieving self-assembly and mechanochromic response of soft 3D cubic nanostructures. Herein, a scalable strategy for the preparation of soft 3D cubic nanostructured films using oligomerization of the Michael addition reaction, which can induce the assembly of double-twisted cylinders for collective replication, remodeling, recombination, and growth, with a phase transition from BPII to BPI, and to chiral nematic phase, is presented. The prepared BP patterns can be obtained by Michael addition oligomerization reaction and composite mask photopolymerization, which present distinct mechanochromic sensitive due to patterns derived from different BP state, and the pattern can be reversibly erased and recurred by mechanical force and temperature. The average domain size of BPII prepared using this strategy can achieve 96 µm, which is 2.5 times larger than that obtained using the conventional cooling approach. This work provides new insights into the self-assembly and selective chemochromism of functional materials and devices.

Super-Wide Temperature Lasers Spanning from -180 to 240 °C Based on Fully-Polymerized Blue Phase Superstructures.

Blue phase liquid crystal (BPLC) lasers have potential applications in displays, sensors, and anti-counterfeiting fields owing to their outstanding optical properties. However, there remain challenges on lasing below 0 °C, which significantly limits the potential application of BPLC lasers in low-temperature environments. In this work, BPLC lasing below 0 °C is realized for the first time in a super-wide temperature range of -180-240 °C using a well-designed fully-polymerized BPLC system with a narrow line width of 0.0881 nm and a low lasing threshold of 37 nJ pulse-1. This fully-polymerized BPLC both effectively avoids low-temperature random crystallization and has excellent compatibility with dye molecules that significantly widen the lasing temperature range below 0 °C. Besides, the variations of laser peak and threshold are also revealed below 0 °C, that is, redshifted laser wavelength and increased threshold value with decreasing temperature, which contribute to a blue-shifted laser signal and a U-shaped lasing threshold in -180-240 °C. These unique laser behaviors can be ascribed to the temperature-dependent anisotropically microstructural deformation of the BP lattice. This work not only opens a door to the development of low-temperature BPLC lasers but also sets out important insights in the design of novel organic optical devices.

Over 200 °C Broad-Temperature Lasers Reconstructed from a Blue-Phase Polymer Scaffold.

Blue-phase liquid crystal (BPLC) lasers have received extensive attention and have potential applications in sensors, displays, and anti-counterfeiting, owing to their unique 3D photonic bandgap. However, the working temperature range of such BPLC lasers is insufficient, and investigations are required to elucidate the underlying mechanism. Herein, a broad-temperature reconstructed laser is successfully achieved in dye-doped polymer-stabilized blue-phase liquid crystals (DD-PSBPLCs) with an unprecedented working temperature range of 25-230 °C based on a robust polymer scaffold, which combines the thermal stability and the tunability from the system. The broad-temperature lasing stems from the high thermal stability of the robust polymerized system used, which affords enough reflected and matched fluorescence signals. The temperature-tunable lasing behavior of the DD-PSBPLCs is associated with the phase transition of the unpolymerized content (≈60 wt%) in the system, which endows with a reconstructed characteristic of BP lasers including a U-shaped lasing threshold, a reversible lasing wavelength, and an obvious lasing enhancement at about 70 °C. This work not only provides a new idea for the design of broad-temperature BPLC lasers, but also sets out important insight in innovative microstructure changes for novel multifunctional organic optic devices.

How Does Organizational Unlearning Influence Product Innovation Performance? Moderating Effect of Environmental Dynamism.

Product innovation integrates technology, knowledge, management practices, and market innovation, making it essential to gain a competitive advantage. Effective management of dynamic knowledge, which is the foundation of and driving force for product innovation, is a powerful tool that allows a firm to successfully innovate, adapt to environmental changes, and improve its competitiveness. In the "nanosecond age," unlearning and learning in an organization is crucial to a firm's ability to promptly update its organizational knowledge and maintain innovation vitality. Based on the dynamic knowledge management perspective, this study integrates and constructs a theoretical model with environmental dynamism as the moderating variable, discusses the impact of organizational unlearning on product innovation performance, and empirically analyzes 208 valid questionnaires in the Yangtze River Delta using the multiple regression method. The results show that organizational unlearning shares a positive relationship with dynamic capabilities and product innovation performance. Dynamic capability is positively related to product innovation performance and has a partial mediating effect on the relationship between organizational unlearning and product innovation performance. Environmental dynamism shares a positive moderating effect on the relationship between organizational unlearning and product innovation performance. This study deepens the existing research on the factors that influence product innovation performance, which may help firms improve their dynamic knowledge management and product innovation performance.