1.
Inorg Chem
; 61(28): 10624-10628, 2022 Jul 18.
Artigo
em Inglês
| MEDLINE
| ID: mdl-35776662
RESUMO
Polymeric {Cu6[(µ3-η2:η2:η2)2-C60](FPz)6Cl·3C6H5Cl}∞ [FPz = 4-(trifluoromethyl)pyrazolate], synthesized solvothermally with chlorobenzene as the solvent, is a doubly-connecting trans bis-adduct hexanuclear cuprofullerene that has copper in mixed valence. The compound is an example of a metallofullerene having semiconductivity character.
2.
Chem Commun (Camb)
; 58(36): 5470-5473, 2022 May 03.
Artigo
em Inglês
| MEDLINE
| ID: mdl-35416208
RESUMO
The controlled synthesis of high-nuclear regioisomeric core-shell exohedral metallofullerenes (ExMFs) is challenging. Herein, we demonstrated the synthesis of regioisomeric core-shell cuprofullerene C60@CuI24 and its 3-D coordination polymer using heteroleptic ligands, realizing high-nuclear regioisomeric ExMFs and a polymeric ExMF structure.