Robust PbO2 modified by co-deposition of ZrO2 nanoparticles for efficient degradation of ceftriaxone sodium.

In recent years, PbO2 electrodes have received widespread attention due to their high oxygen evolution reaction (OER) activity. However, due to the brittle nature of the plating layer, it is easy to cause the active layer to fall off. Pb2+ will leach out with the electrochemical process causing secondary pollution. The starting point of this study is established to improve the stability and adhesion of the electrode coating. Electrochemical oxidation technology has the characteristics of high treatment efficiency, wide range of applications, and non-polluting environment. In this study, conventional PbO2 electrodes were modified by using co-deposition of ZrO2 nanoparticles. In addition, α-PbO2 was added to increase the stability of the electrodes. At a high current density of 1 A/cm2, the accelerated life of the pure PbO2 electrode is 648 h, the accelerated life of the PbO2-ZrO2 electrode is 1.37 times that of the pure PbO2, and the electrode with an added α-PbO2 layer is 1.69 times that of the pure PbO2 electrode. The amount of dissolved Pb2+ was only 29% of that of pure PbO2. The electrochemical performance of the electrode is evaluated by studying the degradation effect of ceftriaxone sodium (CXM). The addition of ZrO2 nanoparticles alters the particle size and deposition content of PbO2, leading to a unique crystal structure distinct from pure PbO2. Compared to conventional PbO2 electrodes, the PbO2-ZrO2 can remove chemical oxygen demand (COD) and pollutants more efficiently, removing for 59% increased by 38.47%. Therefore, PbO2-ZrO2 is of great value in the field of electrochemical degradation of industrial pollutants.

A magnetic chitosan for efficient adsorption of vanadium (V) from aqueous solution.

The all-vanadium redox flow battery (VRFB) is becoming a promising technology for large-scale energy storage due to its advantages such as scalability and flexibility. In recent years, the VRFB has been successfully developed and put into use in many countries. It is expected that the abandoned VRFB will generate a large amount of vanadium waste. To our knowledge, there are few reports on the disposal of spent VRFBs. Herein, chitosan-coated nano-zero-valent iron (CS-Fe0) is proposed for the first time as adsorbents for the treatment of spent VRFBs. It can provide a new approach to deal with the upcoming large number of spent VRFBs. The calculated maximum adsorption capacity for V(V) of chitosan and CS-Fe0 reached 209.5 and 511.3 mg/g at 288 K, respectively. CS-Fe0 showed better adsorption performance than chitosan under different pH conditions and is easy to be separated from the liquid phase. The Freundlich isotherm was suitable for the adsorption process of chitosan, and CS-Fe0 was more consistent with the Langmuir isotherm. Ionic strength (0.05-0.5 M) had a positive effect on the adsorption capacity of CS-Fe0, and the influence of coexisting anions on CS-Fe0 could be negligible. FTIR and XPS analyses revealed that the primary mechanisms were the electrostatic attraction of chitosan and redox of Fe0. The present study confirmed that CS-Fe0 could be a potential material to efficiently trap V(V) from the VRFB electrolyte.