Enhancing piezoelectric coefficient and thermal stability in lead-free piezoceramics: insights at the atomic-scale.

Given the highly temperature-sensitive nature of the polymorphic phase boundaries, attaining excellent piezoelectric coefficient with superior temperature stability in lead-free piezoceramics via direct compositional design remains a formidable challenge. We demonstrate the synergistic improvement of piezoelectric coefficient and thermal stability in lead-free piezoceramics via atomic-scale local ferroelectric structure design. Via modulation of the local Landau energy barrier at doping sites, we effectively mitigate fluctuations in piezoelectric d33. Our approach achieves an impressive d33 of ~430 pC/N with a minimal temperature fluctuation range (△d33 ~ 7%) across the room temperature to 100 °C in potassium sodium niobate ceramics. Further optimization through annealing extends this temperature up to 150 °C (△d33 ~ 8%) while maintaining a high d33 of ~380 pC/N, rivaling the performance of classic temperature stable lead zirconate titanate. This work establishes a framework for addressing the dilemma between high piezoelectric coefficient and inadequate temperature stability in lead-free piezoceramics.

Effect of Cooling Rate on α Variant Selection and Microstructure Evolution in TB17 Titanium Alloy.

The α variant selection and microstructure evolution in a new metastable ß titanium alloy TB17 were studied in depth by DTA, microhardness, XRD, SEM, and EBSD characterization methods. Under the rapid cooling rate conditions (150 °C/min-400 °C/min), only a very small amount of granular αWM (α Widmanstatten precipitates within the grains) precipitated within the grains. The secondary α phase precipitated in the alloy changed from granular to fine needle-like at moderate cooling rates (15 °C/min-20 °C/min). When continuing to slow down the cooling rates (10 °C/min and 1 °C/min), the αGB (α precipitates along the ß grain boundaries), αWGB (α Widmanstatten precipitates that developed from ß grain boundaries or αGB) and αWM grew rapidly. Moreover, the continuous cooling transformation (CCT) diagram illustrated the effect of cooling rate on the ß/α phase transition. EBSD analysis revealed that the variants selection of α near the original ß grain boundary is mainly divided into three categories. (i) The double-BOR (Burgers orientation relationship) αWGB colonies within neighboring ß grains grow in different directions but have the same crystallographic orientation. (ii) The double-BOR αWGB colonies within neighboring ß grains have different growth directions and different crystallographic orientations. (iii) The double-BOR αWGB colonies within the same grain have the same growth direction, but different crystallographic directions. And these double-BOR αWGB colonies correspond to two variants of the given {0001}α//{110}ß.

In situ atomic observations of aggregation growth and evolution of penta-twinned gold nanocrystals.

The twin boundaries and inherent lattice strain of five-fold twin (5-FT) structures offer a promising and innovative approach to tune nanocrystal configurations and properties, enriching nanomaterial performance. However, a comprehensive understanding of the nonclassical growth models governing 5-FT nanocrystals remains elusive, largely due to the constraints of their small thermodynamically stable size and complex twin configurations. Here, we conducted in situ investigations to elucidate the atomic-scale mechanisms driving size-dependent and twin configuration-related aggregation phenomena between 5-FT and other nanoparticles at the atomic scale. Our results reveal that surface diffusion significantly shapes the morphology of aggregated nanoparticles, promoting the symmetrical formation of 5-FT, especially in smaller nanoparticles. Moreover, the inherent structural characteristics of 5-FT mitigate the dominance of surface diffusion in its morphological evolution, retarding the aggregation evolution process and fostering intricate twin structures. These findings contribute to advancing our capacity to manipulate the configuration of twinned particles, enabling more predictable synthesis of functional nanomaterials for advanced engineering applications.

Revealing the Effect of α' Decomposition on Microstructure Evolution and Mechanical Properties in Ti80 Alloy.

Three types of solution treatment and aging were designed to reveal the α' decomposition and its effect on the mechanical properties of near-α Ti-80 alloy, as follows: solution at 970 °C then quenching (ST), ST + aging at 600 °C for 5 h (STA-1), and ST + aging 600 °C for 24 h (STA-2). The results show that the microstructures of the ST samples were mainly composed of equiaxed αp and acicular α', with a large number of dislocations confirmed by the KAM results. After subsequent aging for 5 h, α' decomposed into acicular fine αs and nano-ß (intergranular ß, intragranular ß) in the STA-1 specimen, which obstructed dislocation motion during deformation, resulting in the STA-1 specimen exhibiting the most excellent yield strength (1012 MPa) and maintaining sufficient elongation (8.1%) compared with the ST (898 MPa) and STA-2 (871 MPa) samples. By further extending the aging time to 24 h, the size of acicular αs and nano-ß gradually increased while the density of dislocations decreased, which resulted in a decrease in strength and an increase in plasticity. Based on this, a microstructures-properties correlation model was proposed. This study provides a new method for strength-plasticity matching of near-α titanium alloys through α' decomposition to acicular αs+nano-ß.

Constructing a Hydrophilic Microsensor for High-Antifouling Neurotransmitter Dopamine Sensing.

Real-time sensing of dopamine is essential for understanding its physiological function and clarifying the pathophysiological mechanism of diseases caused by impaired dopamine systems. However, severe fouling from nonspecific protein adsorption, for a long time, limited conventional neural recording electrodes concerning recording stability. This study reported a high-antifouling nanocrystalline boron-doped diamond microsensor grown on a carbon fiber substrate. The antifouling properties of this diamond sensor were strongly related to the grain size (i.e., nanocrystalline and microcrystalline) and surface terminations (i.e., oxygen and hydrogen terminals). Experimental observations and molecular dynamics calculations demonstrated that the oxygen-terminated nanocrystalline boron-doped diamond microsensor exhibited enhanced antifouling characteristics against protein adsorption, which was attributed to the formation of a strong hydration layer as a physical and energetic barrier that prevents protein adsorption on the surface. This finally allowed for in vivo monitoring of dopamine in rat brains upon potassium chloride stimulation, thus presenting a potential solution for the design of next-generation antifouling neural recording sensors. Experimental observations and molecular dynamics calculations demonstrated that the oxygen-terminated nanocrystalline boron-doped diamond (O-NCBDD) microsensor exhibited ultrahydrophilic properties with a contact angle of 4.9°, which was prone to forming a strong hydration layer as a physical and energetic barrier to withstand the adsorption of proteins. The proposed O-NCBDD microsensor exhibited a high detection sensitivity of 5.14 µA µM-1 cm-2 and a low detection limit of 25.7 nM. This finally allowed for in vivo monitoring of dopamine with an average concentration of 1.3 µM in rat brains upon 2 µL of potassium chloride stimulation, thus presenting a potential solution for the design of next-generation antifouling neural recording sensors.

Highly Flexible, High-Performance, and Stretchable Piezoelectric Sensor Based on a Hierarchical Droplet-Shaped Ceramics with Enhanced Damage Tolerance.

Stretchable self-powered sensors are of significant interest in next-generation wearable electronics. However, current strategies for creating stretchable piezoelectric sensors based on piezoelectric polymers or 0-3 piezoelectric composites face several challenges such as low piezoelectric activity, low sensitivity, and poor durability. In this paper, a biomimetic soft-rigid hybrid strategy is used to construct a new form of highly flexible, high-performance, and stretchable piezoelectric sensor. Inspired by the hinged bivalve Cristaria plicata, hierarchical droplet-shaped ceramics are manufactured and used as rigid components, where computational models indicate that the unique arched curved surface and rounded corners of this bionic structure can alleviate stress concentrations. To ensure electrical connectivity of the piezoelectric phase during stretching, a patterned liquid metal acts as a soft circuit and a silicone polymer with optimized wettability and stretchability serves as a soft component that forms a strong mechanical interlock with the hierarchical ceramics. The novel sensor design exhibits excellent sensitivity and durability, where the open circuit voltage remains stable after 5000 stretching cycles at 60% strain and 5000 twisting cycles at 180°. To demonstrate its potential in heathcare applications, this new stretchable sensor is successfully used for wireless gesture recognition and assessing the progression of knee osteoarthritis.

Octylammonium Iodide Induced In-situ Healing at "perovskite/Carbon" Interface to Achieve 85% RH-moisture Stable, Hole-Conductor-Free Perovskite Solar Cells with Power Conversion Efficiency >19.

"Perovskite/carbon" interface is a bottle-neck for hole-conductor-free, carbon-electrode basing perovskite solar cells due to the energy mismatch and concentrated defects. In this article, in-situ healing strategy is proposed by doping octylammonium iodide into carbon paste that used to prepare carbon-electrode on perovskite layer. This strategy is found to strengthen interfacial contact and reduce interfacial defects on one hand, and slightly elevate the work function of the carbon-electrode on other hand. Due to this effect, charge extraction is accelerated, while recombination is obviously reduced. Accordingly, power conversion efficiency of the hole-conductor-free, planar perovskite solar cells is upgraded by ≈50%, or from 11.65 (± 1.59) % to 17.97 (± 0.32) % (AM1.5G, 100 mW cm-2 ). The optimized device shows efficiency of 19.42% and open-circuit voltage of 1.11 V. Meanwhile, moisture-stability is tested by keeping the unsealed devices in closed chamber with relative humidity of 85%. The "in-situ healing" strategy helps to obtain T80 time of >450 h for the carbon-electrode basing devices, which is four times of the reference ones. Thus, a kind of "internal encapsulation effect" has also been reached. The "in situ healing" strategy facilitates the fabrication of efficient and stable hole-conductor-free devices basing on carbon-electrode.

Dynamic Spheroidization Mechanism and Its Orientation Dependence of Ti-6Al-2Mo-2V-1Fe Alloy during Subtransus Hot Deformation.

The dynamic spheroidization mechanism and its orientation dependence in Ti-6Al-2Mo-2V-1Fe alloys during subtransus hot deformation were studied in this work. For this purpose, hot compression tests were carried out at temperatures of 780-880 °C, with strain rates of 0.001-0.1 s-1. Based on SEM, EBSD and TEM characterization, the results showed that the aspect ratio of the α phase decreased with increasing deformation temperatures and decreasing strain rates. At 880 °C/0.001 s-1, the aspect ratio of the α phase was the smallest at 2.05. The proportion of HAGBs decreased with increasing temperatures and strain rates, which was different from the trend of the spheroidization; this indicated that the formation of HAGBs was not necessary for the spheroidization process. Furthermore, the formation of the α/α interface was related to the evolution of dislocations and twin boundaries at high (880 °C) and low temperatures (780 °C), respectively. Moreover, the dependence of lamellar spheroidization on the crystallographic orientation tilt from the compression direction (θ) was clarified: when θ was between 45° and 60°, both the prism slip and basal slip systems were activated together, which was more favorable for spheroidization. This study could provide guidance for titanium alloy process designs and microstructure regulation.

Co-generation of hydroxyl and sulfate radicals via homogeneous and heterogeneous bi-catalysis with the EO-PS-EF tri-coupling system for efficient removal of refractory organic pollutants.

Advanced oxidation processes are commonly considered one of the most effective techniques to degrade refractory organic pollutants, but the limitation of a single process usually makes it insufficient to achieve the desired treatment. This work introduces, for the first time, a highly-efficient coupled advanced oxidation process, namely Electro-Oxidation-Persulfate-Electro-Fenton (EO-PS-EF). Leveraging the EO-PS-EF tri-coupling system, diverse contaminants can be highly efficiently removed with the help of reactive hydroxyl and sulfate radicals generated via homogeneous and heterogeneous bi-catalysis, as certified by radical quenching and electron spin resonance. Concerning degradation of tetracycline (TC), the EO-PS-EF system witnessed a fast pseudo-first-order reaction kinetic constant of 2.54 × 10-3 s-1, ten times that of a single EO system and three-to-four times that of a binary system (EO-PS or EO-EF). In addition, critical parameters (e.g., electrolyte, pH and temperature) are systematically investigated. Surprisingly, after 100 repetitive trials TC removal can still reach 100% within 30 min and no apparent morphological changes to electrode materials were observed, demonstrating its long-term stability. Finally, its universality was demonstrated with effective degradation of diverse refractory contaminants (i.e., antibiotics, dyes and pesticides).

Improved Thermal Stability and Film Uniformity of Halide Perovskite by Confinement Effect brought by Polymer Chains of Polyvinyl Pyrrolidone.

Polyvinyl pyrrolidone (PVP) is doped to PbI2 and organic salt during two-step growth of halideperovskite. It is observed that PVP molecules can interact with both PbI2 and organic salt, reduce the aggregation and crystallization of the two, and then slow down the coarsening rate of perovskite. As doping concentration increases from 0 to 1 mM in organic salt, average crystallite size of perovskite decreases monotonously from 90 to 34 nm; Surface fluctuation reduces from 259.9 to 179.8 nm at first, and then increases; Similarly, surface roughness decreases from 45.55 to 26.64 nm at first, and then rises. Accordingly, a kind of "confinement effect" is resolved to crystallite growth and surface fluctuation/roughness, which helps to build compact and uniform perovskite film. Density of trap states (t-DOS) is cut down by ≈60% at moderate doping  (0.2 mM). Due to the "confinement effect", power conversion efficiency of perovskite solar cells is improved from 19.46 (±2.80) % to 21.50 (±0.99) %, and further improved to 24.11% after surface modification. Meanwhile, "confinement effect" strengthens crystallite/grain boundaries and improves thermal stability of both film and device. T80 of device increases to 120 h, compared to 50 h for reference ones.

Static Globularization Behavior and Artificial Neural Network Modeling during Post-Annealing of Wedge-Shaped Hot-Rolled Ti-55511 Alloy.

The globularization of the lamellar α phase by thermomechanical processing and subsequent annealing contributes to achieving the well-balanced strength and plasticity of titanium alloys. A high-throughput experimental method, wedge-shaped hot-rolling, was designed to obtain samples with gradient true strain distribution of 0~1.10. The samples with gradient strain distribution were annealed to obtain the gradient distribution of globularized α phase, which could rapidly assess the globularization fraction of α phase under different conditions. The static globularization behavior under various parameters was systematically studied. The applied prestrain provided the necessary driving force for static globularization during annealing. The substructure evolution and the boundary splitting occurred mainly at the early stage of annealing. The termination migration and the Ostwald ripening were dominant in the prolonged annealing. A backpropagation artificial neural network (BP-ANN) model for static globularization was developed, which coupled the factors of prestrain, annealing temperature, and annealing time. The average absolute relative errors (AARE) for the training and validation set are 3.17% and 3.22%, respectively. Further sensitivity analysis of the factors shows that the order of relative importance for static globularization is annealing temperature, prestrain and annealing time. The developed BP-ANN can precisely predict the static globularization kinetic curves without overfitting.

Improved Crystallization of Lead Halide Perovskite in Two-Step Growth Method by Polymer-Assisted "Slow-Release Effect".

Fast reaction between organic salt and lead iodide always leads to small perovskite crystallites and concentrated defects. Here, polyacrylic acid is blended with organic salt, so as to regulate the crystallization in a two-step growth method. It is observed that addition of polyacrylic acid retards aggregation and crystallization behavior of the organic salt, and slows down the reaction rate between organic salt and PbI2 , by which "slow-release effect" is defined. Such effect improves crystallization of perovskite. X-ray diffraction study shows that, after addition of 2 mm polyacrylic acid, average crystallite size of perovskite increases from ≈40 to ≈90 nm, meanwhile, grain size increases. Thermal admittance spectroscopy study shows that trap density is reduced by nearly one order (especially for deep energy levels). Due to the improved crystallization and reduced trap density, charge recombination is obviously reduced, while lifetime of charge carriers in perovskite film and devices are prolonged, according to time-resolved photoluminescence and transient photo-voltage decay curve tests, respectively. Accordingly, power conversion efficiency of the device is promoted from 19.96 (±0.41)% to 21.84 (±0.25)% (with a champion efficiency of 22.31%), and further elevated to 24.19% after surface modification by octylammonium iodide.

Flexible PVDF-TrFE Nanocomposites with Ag-decorated BCZT Heterostructures for Piezoelectric Nanogenerator Applications.

Flexible piezoelectric nanogenerators are playing an important role in delivering power to next-generation wearable electronic devices due to their high-power density and potential to create self-powered sensors for the Internet of Things. Among the range of available piezoelectric materials, poly(vinylidene fluoride-trifluoroethylene) (PVDF-TrFE)-based piezoelectric composites exhibit significant potential for flexible piezoelectric nanogenerator applications. However, the high electric fields that are required for poling cannot be readily applied to polymer composites containing piezoelectric fillers due to the high permittivity contrast between the filler and matrix, which reduces the dielectric strength. In this paper, novel Ag-decorated BCZT heterostructures were synthesized via a photoreduction method, which were introduced at a low level (3 wt %) into the matrix of PVDF-TrFE to fabricate piezoelectric composite films. The effect of Ag nanoparticle loading content on the dielectric, ferroelectric, and piezoelectric properties was investigated in detail, where a maximum piezoelectric energy-harvesting figure of merit of 5.68 × 10-12 m2/N was obtained in a 0.04Ag-BCZT NWs/PVDF-TrFE composite film, where 0.04 represents the concentration of the AgNO3 solution. Modeling showed that an optimum performance was achieved by tailoring the fraction and distribution of the conductive silver nanoparticles to achieve a careful balance between generating electric field concentrations to increase the level of polarization, while not degrading the dielectric strength. This work therefore provides a strategy for the design and manufacture of highly polarized piezoelectric composite films for piezoelectric nanogenerator applications.

Anisotropy in the Tensile Properties of a Selective Laser Melted Ti-5Al-5Mo-5V-1Cr-1Fe Alloy during Aging Treatment.

In this work, the anisotropic microstructure and mechanical properties of selective laser melted (SLMed) Ti-5Al-5Mo-5V-1Cr-1Fe (Ti-55511) alloy before and after aging treatment are investigated. Owing to the unique thermal gradient, the prior columnar ß grains with {001} texture component grow in the building direction, and the mechanical properties of the as-fabricated Ti-55511 alloy exhibit slight anisotropy. Aging treatment creates uniform precipitation of the α phase at the boundaries as well as the interior of ß grains. Due to the microstructure of the aged samples with a weak texture, the mechanical properties exhibit almost isotropic characteristics with an ultimate tensile strength of 1133 to 1166 MPa, yield strength of 1093 to 1123 MPa, and elongation from 13 to 16%, which meet the aerospace allowable specification very well. By XRD and EBSD analyses, the total dislocation density of the aged samples (~134.8 × 1013 m-2) is significantly lower than that of the as-fabricated samples (~259.4 × 1013 m-2); however, the aged samples exhibit a higher geometrically necessary dislocation (GND) density (~28.5 × 1013 m-2) compared with the as-fabricated samples GND density (~2.9 × 1013 m-2). Thus, a new approach to strengthening theory for estimating the anisotropic mechanical properties of AM alloys is proposed.

Reconfigurable Quasi-Nonvolatile Memory/Subthermionic FET Functions in Ferroelectric-2D Semiconductor vdW Architectures.

The functional reconfiguration of transistors and memory in homogenous ferroelectric devices offers significant opportunities for implementing the concepts of in-memory computing and logic-memory monolithic integration. Thus far, reconfiguration is realized through programmable doping profiles in the semiconductor channel using multiple-gate operation. This complex device architecture limits further scaling to match the overall chip requirements. Here, reconfigurable memory/transistor functionalities in a ferroelectric-gated van der Waals transistor by controlling the behavior of ferroelectric oxygen vacancies at the interface are demonstrated. Short- and long-term memory functions are demonstrated by modulating the border oxygen vacancy distribution and the associated charge dynamics. The quasi-nonvolatile long-term memory exhibits data retention of over 105 s and endurance of up to 5 × 105 cycles, verifying its applicability as a potential device platform for neuromorphic networks. More importantly, by modulating the ferroelectricity of the interfacial domains with the interactions of oxygen vacancies, a hysteresis-free logic transistor is realized with a subthermionic subthreshold swing down to 46 mV dec-1 , which resembles a negative-capacitance field-effect transistor. The new concept of achieving functional reconfiguration with prior device performance in a single-gate ferroelectric field-effect transistor is of great advantage in future integrated circuit applications.

Porous tantalum structure integrated on Ti6Al4V base by Laser Powder Bed Fusion for enhanced bony-ingrowth implants: In vitro and in vivo validation.

Despite the widespread application of Ti6Al4V and tantalum (Ta) in orthopedics, bioinertia and high cost limit their further applicability, respectively, and tremendous efforts have been made on the Ti6Al4V-Ta alloy and Ta coating to address these drawbacks. However, the scaffolds obtained are unsatisfactory. In this study, novel high-interface-strength Ti6Al4V-based porous Ta scaffolds were successfully manufactured using Laser Powder Bed Fusion for the first time, in which porous Ta was directly manufactured on a solid Ti6Al4V substrate. Mechanical testing revealed that the novel scaffolds were biomechanically compatible, and the interfacial bonding strength was as high as 447.5 MPa. In vitro biocompatibility assay, using rat bone marrow mesenchymal stem cells (r-BMSCs), indicated that the novel scaffolds were biocompatible. Alkaline phosphatase and mineralized nodule determination demonstrated that the scaffolds favored the osteogenic differentiation of r-BMSCs. Moreover, scaffolds were implanted into rabbits with femur bone defects, and imaging and histological evaluation identified considerable new bone formation and bone ingrowth, suggesting that the scaffolds were well integrated with the host bone. Overall, these results demonstrated good mechanical compatibility, biocompatibility, and osteointegration performance of the novel Ti6Al4V-based porous Ta scaffold, which possesses great potential for orthopedic clinical applications.

Structural Evolution in BiNbO4.

The sequence of transitions between different phases of BiNbO4 has been thoroughly investigated and clarified using thermal analysis, high-resolution neutron diffraction, and Raman spectroscopy. The theoretical optical phonon modes of the α-phase have been calculated. Based on thermoanalytical data supported by density functional theory (DFT) calculations, the ß-phase is proposed to be metastable, while the α- and γ-phases are stable below and above 1040 °C, respectively. Accurate positional parameters for oxygen positions in the three main polymorphs (α, ß, and γ) are presented and the structural relationships between these polymorphs are discussed. Even though no significant changes, only relaxation phenomena, are observed in the dielectric behavior of α-BiNbO4 below 1000 °C, evidence of two further subtle transitions at ∼350 and 600 °C is presented through careful analysis of structural parameters from variable temperature neutron diffraction measurements. Such phase variations are also evident in the phonon modes in Raman spectra and supported by changes in the thermoanalytical data. These subtle transitions may correspond to the previously proposed antiferroelectric to ferroelectric and ferroelectric to paraelectric phase transitions, respectively.

Construction of Bio-Piezoelectric Platforms: From Structures and Synthesis to Applications.

Piezoelectric materials, with their unique ability for mechanical-electrical energy conversion, have been widely applied in important fields such as sensing, energy harvesting, wastewater treatment, and catalysis. In recent years, advances in material synthesis and engineering have provided new opportunities for the development of bio-piezoelectric materials with excellent biocompatibility and piezoelectric performance. Bio-piezoelectric materials have attracted interdisciplinary research interest due to recent insights on the impact of piezoelectricity on biological systems and their versatile biomedical applications. This review therefore introduces the development of bio-piezoelectric platforms from a broad perspective and highlights their design and engineering strategies. State-of-the-art biomedical applications in both biosensing and disease treatment will be systematically outlined. The relationships between the properties, structure, and biomedical performance of the bio-piezoelectric materials are examined to provide a deep understanding of the working mechanisms in a physiological environment. Finally, the development trends and challenges are discussed, with the aim to provide new insights for the design and construction of future bio-piezoelectric materials.

Polarisation tuneable piezo-catalytic activity of Nb-doped PZT with low Curie temperature for efficient CO2 reduction and H2 generation.

The reduction of CO2 into useful hydrocarbon chemicals has attracted significant attention in light of the depletion in fossil resources and the global demand for sustainable sources of energy. In this paper, we demonstrate piezo-catalytic electrochemical reduction of CO2 by exploiting low Curie temperature, T c ∼ 38 °C, Nb-doped lead zirconate titanate (PZTN) piezoelectric particulates. The large change in spontaneous polarisation of PZTN due to the acoustic pressures from to the application of ultrasound in the vicinity of the T c creates free charges for CO2 reduction. The effect of applied acoustic power, particulate agglomeration and the impact of T c on piezo-catalytic performance are explored. By optimization of the piezo-catalytic effect a promising piezo-catalytic CO2 reduction rate of 789 µmol g-1 h-1 is achieved, which is much larger than the those obtained from pyro-catalytic effects. This efficient and polarisation tunable piezo-catalytic route has potential to promote the development of CO2 reduction via the utilization of vibrational energy for environmental improvement.

A novel gradient current density output mode for effective electrochemical oxidative degradation of dye wastewater by boron-doped diamond (BDD) anode.

In order to solve the problems of high energy consumption and low current efficiency in electrochemical oxidation (EO) degradation under the traditional constant output process (COP), a gradient output process (GOP) of current density is proposed in this paper. That is, the current density is gradually reduced in a fixed degradation time, and the Reactive Blue 19 simulated dye wastewater was used as the degradation target. The general applicability of the process was further confirmed by studying the optimal gradient current density output parameters, the dye concentration, electrolyte concentration and other dye compounds with different molecular structures. The corresponding results show that the chemical oxygen demand (COD) removal (78%) and the color removal (100%) under the GOP are similar to those in the COP, and the overall energy consumption is reduced by about 50% compared with that in the traditional constant current mode. Moreover, the current efficiency in the middle and late stages of EO process has increased by 8.6 times compared with COP.