RESUMO
Metallophthalocyanine (MPc) and carbon nano-onion (CNO) derivatives were synthesized and characterized by using ultraviolet-visible spectroscopy, infrared and Raman spectroscopy, scanning electron microscopy with energy-dispersive X-ray spectroscopy and X-ray powder diffraction. The unmodified CNOs and MPc-CNO derivatives were used as photocatalysts for rhodamine B (RhB) degradation under visible-light irradiation. The photocatalytic studies revealed that the MPc-CNO nanostructural materials simultaneously exhibited a high absorption capacity and an excellent visible-light-driven photocatalytic activity towards RhB. These nanostructures possess great potential for use as active photocatalysts for organic pollutant degradation.
RESUMO
Many macromolecular systems, including carbon nanostructures (CNs), have been synthesized and investigated as acceptors in photovoltaic devices. Some CNs have shown interesting electrochemical, photophysical and electrocatalytic properties and have been used in energy and sustainability applications. This study focuses on the covalent functionalization of carbon nanoonion (CNO) surfaces with ferrocene moieties to obtain donor-acceptor systems involving CNOs as acceptors. The systems were synthesized and characterized by infrared, Raman, UV-vis and fluorescence spectroscopies, thermogravimetric analysis, scanning electron microscopy, nitrogen adsorption and electrochemical measurements. The HOMO-LUMO levels were calculated to evaluate the possibility of using these systems in photoactive devices. In this study, for the first time, the CNO-based derivatives were applied as acceptors in the active layer of photovoltaic devices. This study is the first to use large CNO-based derivatives as acceptors in organic photovoltaic devices, and a power conversion efficiency as high as 1.89% was achieved.