Persistent Organic Pollutants (POPs), Current Use Pesticides (CUPs) and Polycyclic Aromatic Hydrocarbons (PAHs) in edible marine invertebrates from a Patagonian harbor.

Despite their global ban in 2001, persistent organic pollutants (POPs) remain detectable in marine species, posing ongoing environmental and health risks. Current use pesticides (CUPs) like chlorpyrifos and chlorothalonil, along with polycyclic aromatic hydrocarbons (PAHs), also contaminate coastal areas, affecting human health. This study assessed POPs, CUPs and PAHs in bivalves, gastropods, polychaetes, crustaceans, and echinoderms from an Atlantic Patagonian harbor. Concentrations of organochlorine pesticides (OCPs), polychlorinated biphenyls (PCBs), and polybrominated diphenyl ethers (PBDEs) ranged from

Noise pollution assessment and management in rare earth mining areas: a case study of Kollam, Kerala, India.

Noise pollution is an unintentional consequence of mining activities, needing rigorous assessment, monitoring, and mitigation techniques to reduce its impact on local residents and ecosystems. The study specifically examines the noise pollution from rare earth mining activities in the Neendakara-Kayamkulam (NK) coastal belt, Kollam, Kerala, India, a region rich in ilmenite, rutile, sillimanite, zircon, and monazite. Despite the known environmental and health impacts of noise pollution, there is limited specific data on its magnitude and sources in this region, as well as a lack of effective mitigation strategies tailored to rare earth mining operations. Studies have indicated that mining operations, such as the movement of heavy mineral sands, considerably elevate noise levels, which have an effect on the environment's quality and public health. This study seeks to fill the gap by geospatial mapping and assessing the noise levels and recommend measures to effectively mitigate noise pollution. Systematic noise measurements were conducted at 48 suitable locations within the NK coastal belt, including residential, commercial, industrial, coastal, and silence zones. The noise levels vary from 49.1 dB(A) near a religious place to 82.4 dB(A) near the local industry. The study employs geospatial noise mapping and land cover superimposition to implement class-specific mitigation measures for noise pollution in a coastal vicinity mixed land use area, including natural and vegetative barriers, operational scheduling, zoning, and land use planning.

CORAL-Catamaran for Underwater Exploration: Development of a Multipurpose Unmanned Surface Vessel for Environmental Studies.

CORAL (Catamaran fOr UndeRwAter expLoration) is a compact, unmanned catamaran-type vehicle designed and developed to assist the scientific community in exploring marine areas such as inshore regions that are not easily accessible by traditional vessels. This vehicle can operate in different modalities: completely autonomous, semi-autonomous, or remotely assisted by the operator, thus accommodating various investigative scenarios. CORAL is characterized by compact dimensions, a very low draft and a total electric propulsion system. The vehicle is equipped with a single echo-sounder, a 450 kHz Side Scan Sonar, an Inertial Navigation System assisted by a GPS receiver and a pair of high-definition cameras for recording both above and below the water surface. Here, we present results from two investigations: the first conducted in the tourist harbour in Pozzuoli Gulf and the second in the Riomaggiore-Manarola marine area within the Cinque Terre territory (Italy). Both surveys yielded promising results regarding the potentiality of CORAL to collect fine-scale submarine elements such as anthropic objects, sedimentary features, and seagrass meadow spots. These capabilities characterize the CORAL system as a highly efficient investigation tool for depicting shallow bedforms, reconstructing coastal dynamics and erosion processes and monitoring the evolution of biological habitats.

Dual-isotope ratios of carbonaceous aerosols for seasonal observation and their assessment as source indicators.

Carbonaceous aerosols exhibit seasonal variations due to a complex interplay of emission sources, meteorological conditions, and chemical processes. This study presents the first year-round dual­carbon isotopic analysis of carbonaceous aerosols in Northeastern Europe (Lithuania). The emphasis was placed on the processes affecting carbonaceous submicron particle (PM1) concentrations and their isotopic composition (δ13CTC, fc) during different seasons. Aerosol particles were collected in the two distinct sites: at an urban background site (Vilnius) and a coastal site (Preila). The concentrations of total carbon (TC) and black carbon (BC) varied both spatially and temporally. The annual average concentrations were 4 µg/m3 for TC and 2.3 µg/m3 for BC at the urban background site. They were considerably lower at the coastal site with 2.9 µg/m3 for TC and 0.74 µg/m3 for BC. The peak concentrations of TC and BC that occur during the cold season indicate a significant impact from residential heating. The δ13C in aerosols exhibited a distinct seasonal cycle with depleted δ13CTC values during the warm season (April-October). Through the integration of isotopic composition, contemporary carbon (fc), and BC source apportionment, we achieved precise predictions of isotopic parameter changes, encompassing pollution sources and the influence of meteorological parameters. To better understand the respective contributions of local and regional sources, air mass trajectories, wind patterns (speed and direction), and the polar conditional probability function (CPF) were studied in parallel. The study indicates that the isotopic composition of PM1 at both sites is primarily controlled by emission sources (local and regional), while meteorological conditions (temperature and mixing layer height) have less influence. These variations have important implications for regional air quality, climate dynamics, and public health, which are persistently subject to continuous research and monitoring.

Leaching potentials of microplastic fibers and UV stabilizers from coastal-littered face masks.

Synthetic fibrous textiles are ubiquitous plastic commodities in everyday existence. Nevertheless, there exists a dearth of understanding regarding their environmental occurrence and the releasing capacities of associated additives. In this study, ten additives were determined in twenty-eight kinds of daily used plastic products including face masks, synthetic clothing, and food containers. Our results revealed that a typical kind of fibrous plastic, face masks, contained a greater variety of additives with UV stabilizers in particular, when compared to other plastic commodities. The above phenomena triggered our field investigation for the occurrence and release potentials of face mask fibers and the co-existing UV stabilizers into the environment. We further collected 114 disposed masks from coastal areas and analyzed their UV stabilizer concentrations. Results showed that the abundance of littered face masks ranged from 40-1846 items/km2 along the Yangtze Estuary, China; and UV stabilizers were of 0.3 ± 0.7 ng/g and 0.7 ± 1.7 ng/g in main bodies and ear ropes, respectively. The UV stabilizer concentrations in the field collected masks were only ∼7 % of their new counterparts, implying their potential leaching after disposal. By simulating the weathering scenario, we predict that a substantial amount of microplastics, with 1.1 × 1010 polypropylene fibers and 3.7 × 1010 polyester fibers, are probably be released daily into the coastal environment after face masks disposal; whereas the accompanied leaching amount of UV stabilizers was relatively modest under the current scenario.

First record of plastiglomerates, pyroplastics and plasticrusts along the beaches of Tamilnadu, Southeast coast of India.

Plastic litter affects coastal and marine ecosystems globally. This study represents the first record of pyroplastics and plasticrust in the beaches of Tamil Nadu, India. All samples were FTIR spectroscopically examined to confirm the polymer composition of the suspected plastics. The 16 plastic formations were found in TamilNadu, including six plastiglomerates nine pyroplastics and one plasticrust. Five types of polymers (PET, PP, PVC, PA, and PE) were found on the plastic matrices. The study also revealed that pyroplastics and plasticrust formed by degradation of plastics through weathering in the coastal environment. The present study also found that four types of marine fouling organisms such as oyster larvae, bryozoan, barnacle and polychaete worm were encrusted on the two pyroplastics. The emergence of these new forms of plastic raises concerns about their interactions with the environment and biota.

Spatial distribution, compositional pattern, and source apportionment of colloidal trace metals in the coastal water of Shandong Peninsula, northeastern China.

The Shandong Peninsula (SP) is the largest peninsula in China hosting rich economic and agricultural activities. In this study, we investigated the behavior of dissolved Mn, Fe, Cu, Zn, Cd, and Pb and their colloidal phases in the coastal and estuarine areas of SP. Pb and Zn had the highest contamination factors of 0.22-10.15 and 0.90-4.41, respectively. The <1 kDa accounted for 23-57 % of the total dissolved phase. Mn, Fe, Cu, Zn, Cd, and Pb were more likely to bind to 100 kDa-0.45 µm colloids (21-57 %). For colloidal Fe and Cu, the adsorption-release behavior had more significant effects on their dynamics. In contrast, the changes in colloidal Mn, Cd, and Pb were mainly controlled by the combined influence of temperature, dissolved oxygen, and microbial activity. However, the 1-3 kDa Zn exhibited a greater pH-dependent dispersion and was significantly positively correlated with it.

Spatial distribution and seasonal variation of trace hazardous elements contamination in the coastal environment.

Groundwater is the second largest water source for daily consumption, only next to surface water resources. Groundwater has been extensively investigated for its pollution level in urban areas. The groundwater quality assessments in industrial areas associated with every urban landscape are still lacking. In order to examine the spatial distribution characteristics, pollution levels, and sources of trace metals in the densely populated Chennai coastal region of Tamilnadu, India, physicochemical parameters and trace element concentrations have been determined in groundwater. 55 groundwater samples from Tamil Nadu's coastal region were collected and analyzed for physicochemical parameters such as pH, (EC), (TDS), and (TH) during the pre-monsoon (June 2015) and post-monsoon (January 2016) seasons. We used trace elements and analyzed them in this study (Mg, Zn, Pb, Ni, Co, Cu, Cr, and Fe). Furthermore, anthropogenic input from industries and power plants exacerbates the pollution of Ni, Mg, Fe, and Mn. Due to evaporites and anthropogenic input, samples with excessive salinity, total hardness, and water quality are considered unsuitable for irrigation or drinking. The results demonstrated that seasonal, geogenic, and anthropogenic influences all have a significant impact on the heterogeneous chemistry of groundwater.

Atmospheric Nitrogen Pollution Control Benefits the Coastal Environment.

Nitrogen is an essential nutrient and a major limiting element for the ocean ecosystem. Since the preindustrial era, substantial amounts of nitrogen from terrestrial sources have entered the ocean via rivers, groundwater, and atmospheric deposition. China serves as a key hub in the global nitrogen cycle, but the pathways, sources, and potential mitigation strategies for land-ocean nitrogen transport are unclear. By combining the CHANS, WRF-Chem, and WNF models, we estimated that 8 million tonnes (Tg) of nitrogen was transferred into the ocean in 2017 in China, with atmospheric deposition contributing 1/3. About half variation of the offshore chlorophyll concentration was explained by atmospheric deposition. The Bohai Sea was the hot spot of nitrogen input, estimated at 214 kg N ha-1, while other areas were around 25-51 kg N ha-1. The largest contributors are agricultural systems (4 Tg, 55%), followed by domestic sewage (2 Tg, 21%). Abatement measures could reduce nitrogen export to the ocean by 43%, and mitigating ammonia and nitrogen oxide emissions accounts for 33% of this reduction, highlighting the importance of addressing air pollution in resolving ocean pollution. The cost-benefit analysis suggests the priority of nitrogen reduction in cropland and transport systems for the ocean environment.

In vitro screening of imidazolium and pyrrolidinium based ionic liquids toxicity on subcellular fractions of the Mediterranean mussel Mytilus galloprovincialis.

Ionic liquids (ILs) have been considered eco-friendly alternatives to conventional organic solvents. However, several studies have reported that ILs exert toxicity towards aquatic invertebrates. Applying in vitro methodology, the aim of the present study was to evaluate the potential effect of three ILs on the biochemical performance of exposed Mytilus galloprovincialis digestive gland and gills cellular fractions. Carboxylesterase might be involved in the derived toxicity mechanism of ILs as activity levels increased significantly in digestive gland exposed fractions. This group of ILs did not seem to induce genotoxicity, except in gills cellular fractions exposed to 1-butyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide. In the literature, in vitro methodology has been suggested as an important complement to animal testing and in silico studies. The present research underlines its efficacy as a quick pre-screening before in vivo testing, particularly with heterogenic groups of substances with high variability in composition, such as ILs and deep eutectic solvents.

The molecular level degradation state of drift plastics in the Sea of Japan coastline.

Polyethylene (PE) and polyethylene terephthalate (PET) are among the most abundant plastics polluting the oceans. However, their environmental fate depends on how they have been weathered. Due to its unique geography, the Sea of Japan is a pollution hotspot where plastics accumulate. In this study, the structures of plastics, having drifted into the Sea of Japan coastline environment, were analyzed with a particular focus on examining polymer crystallization and carbonyl formation; two factors which influence microplastic formation and the adsorption of contaminants onto plastic surfaces. PE in the coastal environment did not show evidence of crystallization, although carbonyl formation did increase. By contrast, PET bottles were shown to not be uniform in structure, with unaged bottles being less crystalline in the neck component compared to the body. Because of this difference, in environmental PET bottles, it was the bottle neck that showed increases in crystallization and carbonyl group formation.

Intra-annual variation in microplastics in mussels (Mytilus galloprovincialis) inhabiting an urbanized bay of South Korea.

This study investigated the presence of microplastics (MPs) in mussels from an urbanized bay in Korea, focusing on intra-annual variation. The average MP concentration was 0.36 ± 0.14 n/g w.w. (1.24 ± 0.56 n/individual). MPs were detected throughout the year with minor monthly variation and no significant monthly changes. Although there was no correlation between MP concentration in mussel and seawater, a positive relationship was observed when normalizing MPs to mussel's condition index (except for July). Polypropylene, polyethylene and acrylate polymer were dominant MPs, with high-density polymers comprising 59 % of the total. Most MPs were fragments and particles <200 µm. This study indicates that strict time restrictions for mussel sampling may not be necessary to assess MP levels in this bay. Additionally, considering MPs in seawater, biological conditions of mussel may be essential for understanding variations in MP levels in mussels. Including small MPs (<200 µm) and high-density polymers in MP assessment is recommended.

Effects of TiO2 ultraviolet filter and sunscreens on coastal dune plant performance and competitive interactions.

Ultraviolet filters (UVFs) added to sunscreens (SS) are emerging contaminants in marine environments due to their adverse effects on organisms and ecosystems. UVFs have also been detected in beach-dune systems, but their influence on resident organisms has not been explored yet. Native plants are fundamental components of coastal dunes, and these ecologically/economically important systems are currently among the most threatened globally. Thus, understanding whether UVFs may act as threats to dune plants is crucial. This field study evaluated and compared the effects of titanium dioxide nanoparticles (nTiO2), one of the inorganic UVFs most commonly added to sunscreens, and those of a commercial sunscreen product containing it (SS-nTiO2) on the performance of adult dune plants of a native (Thinopyrum junceum) and a non-native invasive species (Carpobrotus sp. pl.) and their competitive interactions at environmentally realistic concentrations. The effects of nTiO2, SS-nTiO2 and of a sunscreen product containing just organic UVFs (SS-OF) on early life stages of T. junceum were also examined. Ti bulk content in sand and plants at the study site ranged from 970 to 1069 mg kg-1 and from 2 to 7.9 mg kg-1, respectively. Thinopyrum junceum adult plants periodically exposed during the summer season to seawater contaminated by SS-nTiO2 produced less biomass than un-exposed plants and nTiO2 exposed plants. nTiO2 and SS-nTiO2 reduced the capacity of T. junceum to control the spread of Carpobrotus. Both SS-nTiO2 and SS-OF reduced seedling emergence in T. junceum whereas nTiO2 did not. These results demonstrated that the periodical exposures of native dune plants to sunscreens could reduce their establishment success and growth and favor invasive plant spread potentially resulting in community structure changes. They also emphasize the need to assess the phytotoxicity not only of single UVFs but especially that of complete sunscreen products to design more eco-friendly formulations in the future.

Assessment of environmental parameters effect on potentially toxic elements mobility in foreshore sediments to support marine-coastal contamination prediction.

Potentially toxic elements (PTEs) presence in marine sediments can significantly affect the environmental quality and negatively influence economy and recreational activities in related areas. Accordingly, contamination monitoring and control in the marine environment is a fundamental task. In this work, four PTEs behavior (i.e. As, Hg, Pb, and Zn) in sandy foreshore sediments (SFSs) was thoroughly investigated at different pH, redox potential and temperature conditions of the marine water. For all the tests, the released As was 2.7-6 times higher than its initial concentration in water. Nonetheless, final mass balances showed that preferential release in the liquid phase occurred for Pb and Hg (up to 10 % and 9.1 %, respectively). Moreover, final Zn and Hg content increase in SFSs labile fractions indicated their higher bioavailability after the tests. The obtained results outline an approach useful to predict the contaminants behavior in marine matrices and support environmental monitoring and preservation strategies.

Seafloor warm water temperature anomalies impact benthic macrofauna communities of a high-Arctic cold-water fjord.

Amid the alarming atmospheric and oceanic warming rates taking place in the Arctic, western fjords around the Svalbard archipelago are experiencing an increased frequency of warm water intrusions in recent decades, causing ecological shifts in their ecosystems. However, hardly anything is known about their potential impacts on the until recently considered stable and colder northern fjords. We analyzed macrobenthic fauna from four locations in Rijpfjorden (a high-Arctic fjord in the north of Svalbard) along its axis, sampled intermittently in the years 2003, 2007, 2010, 2013 and 2017. After a strong seafloor warm water temperature anomaly (SfWWTA) in 2006, the abundance of individuals and species richness dropped significantly across the entire fjord in 2007, together with diversity declines at the outer parts (reflected in Shannon index drops) and increases in beta diversity between inner and outer parts of the fjord. After a period of three years with stable water temperatures and higher sea-ice cover, communities recovered through recolonization processes by 2010, leading to homogenization in community composition across the fjord and less beta diversity. For the last two periods (2010-2013 and 2013-2017), beta diversity between the inner and outer parts gradually increased again, and both the inner and outer sites started to re-assemble in different directions. A few taxa began to dominate the fjord from 2010 onwards at the outer parts, translating into evenness and diversity drops. The inner basin, however, although experiencing strong shifts in abundances, was partially protected by a fjordic sill from impacts of these temperature anomalies and remained comparatively more stable regarding community diversity after the disturbance event. Our results indicate that although shifts in abundances were behind important spatio-temporal community fluctuations, beta diversity variations were also driven by the occurrence-based macrofauna data, suggesting an important role of rare taxa. This is the first multidecadal time series of soft-bottom macrobenthic communities for a high-Arctic fjord, indicating that potential periodic marine heatwaves might drive shifts in community structure, either through direct effects from thermal stress on the communities or through changes in environmental regimes led by temperature fluctuations (i.e. sea ice cover and glacial runoff, which could lead to shifts in primary production and food supply to the benthos). Although high-Arctic macrobenthic communities might be resilient to some extent, sustained warm water anomalies could lead to permanent changes in cold-water fjordic benthic systems.

Investigation and comparative analysis of ecological risk for heavy metals in sediment and surface water in east coast estuaries of India.

The sediments and surface water from 8 stations each from Dhamara and Paradeep estuarine areas were sampled for investigation of heavy metals, Cd, Cu, Pb, Mn, Ni, Zn, Fe, and Cr contamination. The objective of the sediment and surface water characterization is to find the existing spatial and temporal intercorrelation. The sediment accumulation index (Ised), enrichment index (IEn), ecological risk index (IEcR) and probability heavy metals (p-HMI) reveal the contamination status with Mn, Ni, Zn, Cr, and Cu showing permissible (0 ≤ Ised ≤ 1, IEn Ë‚ 2, IEcR ≤ 150) to moderate (1 ≤ Ised ≤ 2, 40 ≤ Rf ≤ 80) contamination. The p-HMI reflects the range from excellent (p-HMI = 14.89-14.54) to fair (p-HMI = 22.31-26.56) in off shore stations of the estuary. The spatial patterns of the heavy metals load index (IHMc) along the coast lines indicate that the pollution hotspots are progressively divulged to trace metals pollution over time. Heavy metal source analysis coupled with correlation analysis and principal component analysis (PCA) was used as a data reduction technique, which reveals that the heavy metal pollution in marine coastline might originate from redox reactions (FeMn coupling) and anthropogenic sources.

Plastic litter changes the rhizosphere bacterial community of coastal dune plants.

The presence of plastic litter in coastal environments like beach-dune systems has been well documented, and recent studies have shown that this pollutant can influence sand properties as well as dune vegetation. However, the effects of plastics on rhizosphere bacterial communities of dune plants have largely been neglected. This is an ecologically relevant issue since these communities may play an important role in improving plant growth and resilience of dune systems. Here, we explored the impact of plastic litter made of either non-biodegradable polymers (NBP) or biodegradable/compostable polymers (BP) on the structure and composition of rhizosphere bacterial communities associated with two widespread species along coastal European dunes, Thinopyrum junceum and Sporobolus pumilus, by using a one-year field experiment combined with metabarcoding techniques. Both plastics did not affect neither the survival nor the biomass of T. junceum plants, but they significantly increased alpha-diversity of rhizosphere bacterial communities. They also changed rhizosphere composition by increasing the abundance of the phyla Acidobacteria, Chlamydiae, and Nitrospirae, and of the family Pirellulaceae, and reducing the abundance of the family Rhizobiaceae. NBP reduced drastically the survival of S. pumilus while BP increased its root biomass compared to controls. BP also increased the abundance of the phylum Patescibacteria of the rhizosphere bacterial communities. Our findings provide the first evidence that NBP and BP can change rhizosphere bacterial communities associated with dune plants and highlight the importance of investigating how these changes can affect the resilience of coastal dunes to climate change.

The joint effects of atmospheric dry and wet deposition on organic carbon cycling in a mariculture area in North China.

In this research, the atmospheric dry and wet deposition fluxes of particulate organic carbon (POC) over the coastal waters around the Yangma Island in North Yellow Sea were investigated. Combining the results of this research and previous reports about the wet deposition fluxes of dissolved organic carbon (DOC) in precipitation (FDOC-wet) and dry deposition fluxes of water-dissolvable organic carbon in atmospheric total suspended particles (FDOC-dry) in this area, a synthetic assessment of the influence of atmospheric deposition on the eco-environment was conducted. It was found that the annual dry deposition flux of POC was 1097.9 mg C m-2 a-1, which was approximately 4.1 times that of FDOC-dry (266.2 mg C m-2 a-1). For wet deposition, the annual flux of POC was 445.4 mg C m-2 a-1, accounting for 46.7 % that of FDOC-wet (954.3 mg C m-2 a-1). Therefore, atmospheric POC was mainly deposited through dry process with the contribution of 71.1 %, which was contrary to the deposition of DOC. Considering the indirect input of organic carbon (OC) from atmospheric deposition, that is, the new productivity supported by nutrient input from dry and wet deposition, the total OC input from atmospheric deposition to the study area could be up to 12.0 g C m-2 a-1, highlighting the important role of atmospheric deposition in the carbon cycling of coastal ecosystems. The contribution of direct and indirect input of OC through atmospheric deposition to the dissolved oxygen consumption in total seawater column was assessed to be lower than 5.2 % in summer, suggesting a relatively smaller contribution to the deoxygenation in summer in this region.

Abundance and characterization of microplastics in amphipods from the Japanese coastal environment.

Microplastics can be ingested by tiny detritivores such as amphipods, with potential consequences on the food chain. The present study characterizes the abundance, chemical composition, and size of microplastics in amphipods found in the Japan Sea coastal environment, which is a hotspot for microplastic accumulation. High amounts of microplastic ingestion and a large discrepancy by amphipod species, Talorchestia nipponensis, Ampithoe valida, and Trinorchestia trinitatis, were observed (between 0.2 and 76.3 particles/individual) which may be due to differences in habitat preference and background contamination. This result indicates that coastal amphipods in particular may ingest large amounts of microplastics. The average microplastic particle size in amphipods was 59 ± 8.6 µm, with 83% of particles smaller than 90 µm, and polyethylene was dominant. This study provides insights into microplastic abundance in coastal amphipods and the context for further studies on coastal amphipod microplastic ingestion.

Pollution and ecological risk assessments for heavy metals in coastal, river, and road-deposited sediments from Apia City in Upolu Island, Samoa.

This study was the first to investigate the pollution and ecological risks of heavy metals in coastal, river/stream and road-deposited sediments (RDS) from Apia in Samoa. Cr and Ni concentrations in sediment samples were higher than those of other metals. River sediments and RDS had relatively high EF values around the intensive commercial areas, with a moderate to significant enrichment of Cu, Zn, Cd, and Pb. The results indicate that Cr and Ni have a natural origin from volcanic parent materials, while Cu, Zn, Cd, and Pb originated from anthropogenic activities, such as traffic emissions and the discharge of municipal wastewater. The assessments of pollution and ecological risk revealed that coastal sediments adjacent to the river are anthropogenically contaminated and present a moderate ecological risk. This study demonstrates that metals that have accumulated in the urban impermeable layer and river/stream bed have flowed into the coastal environment through runoff.