Cassava starch-based hot melt adhesive for textile industries.

The textile industry uses a lot of adhesives to join materials together, and many of these adhesives use petroleum-based ingredients that are harmful to the environment. To replace petroleum-based adhesives with a more environmentally friendly option for the textile industry, this study set out to create and evaluate a hot-melt adhesive derived from cassava starch. By adding kaolin clay as a filler and tannin as a tackifier in different ratios of starch, the created adhesive was enhanced. Tannic acid to starch ratios of 2:1, 6:1, and 10:1 w/w and kaolin to starch ratios of 3:1, 5:1, and 7:1 w/w were used to investigate the effects of clay and tackifier, respectively. The adhesives's viscosity, moisture content, tensile strength, and shear strength were then measured. The presence of kaolin and tannic acid in starch-based adhesives favored a good interaction between the adhesive's ingredients. The adhesive's maximum shear strength was measured at 4.93 ± 0.11 Mpa when dry and 0.263 ± 0.21 Mpa when wet. The current data indicate that the optimal tensile strength was determined to be 3.45 ± 0.22 MPa. This result showed that hot melt adhesives based on cassava starch would be a good environmentally friendly substitute for petroleum-based adhesives, and more study in this field is necessary.

Superhydrophobic and environmentally friendly bovine bone biomass based cellulose membrane for oil-water separation.

With the development of superhydrophobic materials for oil-water separation, there is an urgent need to develop environmentally friendly, low-cost, and novel hydrophobic materials. In this paper, based on bovine bone biomass raw materials, bone ash particles are obtained by calcination and grinding, and then bovine bone ash/cotton fabric cellulose membranes are prepared by vacuum filtration and impregnation methods. The pore size of the membrane is regulated and the hydrophobicity of the material is enhanced by constructing the surface microstructures. Results indicate that the membranes possess good hydrophobicity with a contact angle of 161° and the flux can reach 53,635.2 L/m2h for light oil. The separation efficiencies for petroleum ether, cyclohexane, kerosene, and dichloromethane all reach >99 %. In addition, the separation efficiency of the cellulose membrane is still >99 % in the 40-day separation test and always exceeds 90 % for 30 cycling test, indicating that it has good stability and recoverability. Interestingly, the cellulose membrane is prepared from biodegradable and renewable raw materials, which reduces environmental pollution and effectively utilize natural resources.

Facile fabrication of ultradurable flame-retardant and hydrophobic cotton fabric with P/N-rich maltodextrin derivative and octadecyltrimethoxysilane.

Flame-retardant and hydrophobic cotton fabric provides protections from fire, stain and bacteria in daily life. However, it is still a great challenge to achieve ultrahigh durability via a green and facile technology. Herein, we synthesized a reactive P/N-rich maltodextrin derivative (PM), and reported a facile dipping-baking strategy to fabricate ultradurable flame-retardant and hydrophobic cotton fabric with PM and octadecyltrimethoxysilane (OTMS). The acids released from PM not only reacted with cellulose during baking, but also catalyzed the hydrolysis-polycondensation of OTMS and silylation reaction of cellulose. Thanks to the P/N/Si synergy and the existence of polyalkylsiloxane coating, treated fabric exhibited outstanding flame retardancy and hydrophobicity with a limiting oxygen index (LOI) of 34.7% and a water contact angle (WCA) of 143.3°. The chemical crosslinkings in PM-cellulose and OTMS-cellulose imparted ultrahigh durability to treated fabric. The LOI and WCA of treated fabric still reached 27.2% and 127.9° after 50 harsh washing cycles, respectively. Moreover, the WCA still maintained above 125° after 3000 intense friction cycles or soaked in strongly acidic/alkaline solution for 3 days. This work not only provides a new idea to synthesize biobased reactive flame retardant, but also a feasible and sustainable strategy for fabricating ultradurable hydrophobic and flame-retardant cotton fabric.

A multi-functional coating on cotton fabric to incorporate electro-conductive, anti-bacterial, and flame-retardant properties.

Multi-functional textiles have become a growing trend among smart customers who dream of having multiple functionalities in a single product. Thus, this study aimed to develop a multi-functional textile from a common textile substrate like cotton equipped with electrically conductive, anti-bacterial, and flame-retardant properties. Herein, a bunch of compounds from various sources like petro-based poly-aniline (PANI), phosphoric acid (H3PO4), inorganic silver nanoparticles (Ag-NPs), and biomass-sourced fish scale protein (FSP) were used. The coating was prepared via in-situ polymerization of PANI with the cotton substrate, followed by the dipping in AGNPs solution, layer-by-layer deposition of FSP and sodium alginate, and finally, a dip-dry-cure technique after immersing the modified cotton substrate into the H3PO4 and citric acid solution. The key results indicated that the fabric treated with PANI/Ag-NPs/FSP/P-compound exhibited a balanced improvement in all three desired properties as the electrical resistance was reduced by 44.44 % while showing superior bacterial inhibition against gram-positive bacteria (S. aureus) and gram-negative bacteria (E. coli), and produced dense-black carbonaceous char residues, indicating its flame retardant properties as well. Thus, such amicable developments made the cotton textile substrate a multi-functional textile, which showed potential to be used in medical textiles, wearable electronics, fire-fighter suits, etc.

Novel Synthesis of Zinc Oxide on Cotton Fabric by Cathodic Cage Plasma Deposition for Photocatalytic and Antibacterial Performance.

Cotton fabrics with zinc oxide (ZnO) coating are of significant interest due to their excellent antibacterial performance. Thus, they are widely in demand in the textile industry due to their medical and hygienic properties. However, conventional techniques used to deposit ZnO on fabric require long processing times in deposition, complex and expensive equipment, and multiple steps for deposition, such as a separate process for nanoparticle synthesis and subsequent deposition on fabric. In this study, we proposed a new method for the deposition of ZnO on fabric, using cathodic cage plasma deposition (CCPD), which is commonly used for coating deposition on conductor materials and is not widely used for fabric due to the temperature sensitivity of the fabric. The effect of gas composition, including argon and a hydrogen-argon mixture, on the properties of ZnO deposition is investigated. The deposited samples are characterized by XRD, SEM, EDS, photocatalytic, and antibacterial performance against Staphylococcus aureus and Pseudomonas aeruginosa bacteria. It is observed that ZnO-deposited cotton fabric exhibits excellent photocatalytic degradation of methylene blue and antibacterial performance, specifically when a hydrogen-argon mixture is used in CCPD. The results demonstrate that CCPD can be used effectively for ZnO deposition on cotton fabric; this system is already used in industrial-scale applications and is thus expected to be of significant interest to garment manufacturers and hospitals.

Single overall 'H-shaped' multifunctional compound achieves fire safety, durability, enhanced strength, and smoke suppression of cotton fabrics.

Challenges currently faced by phosphorus-based flame retardants for cotton fabrics include reduced fabric strength after treatment, high smoke release during combustion, formaldehyde release from commercial phosphorus-based flame retardants and poor flame retardant durability after treatment. In the present work, a P/N/B synergistic flame retardant TBST is synthesized using phosphoric acid, cyanuric acid, boric acid, pentaerythritol, etc. The phosphorus­nitrogen­boron atomic ratio is 2:3:1, and it is successfully prepared on cotton fabric to prepare TBST/Cotton. When the weight gain rate is 29.8 %, the LOI value is 41.6 ± 0.3 %, indicating that TBST/Cotton has excellent flame retardant performance. At the same time, in the vertical flame test, the length of residual carbon is 5.6 cm. In addition, the THR and HRR are reduced by 58.4 % and 91.9 % respectively compared to Cotton, indicating that TBST/Cotton has excellent combustion performance. In addition, compared to the residual carbon content of Cotton at 710 °C, the residual carbon content of TBST/Cotton in nitrogen increased by 27.79 %. For a 30 % increase in weight, the increase in longitudinal mechanical strength is 23.1 %. Inferred the decomposition mechanism and flame retardant mechanism of TBST/Cotton. TBST/Cotton has the advantages of good flame retardant durability and enhanced mechanical properties, and the reinforcement mechanism of TBST has been speculated.

Utilization of titanium dioxide (TiO2) nanoparticles to improve functionality and mechanical performances of cotton fabric.

This study aims to produce high-quality functional cotton fabric through the deposition of nano TiO2. Here nanoparticles are deposited by the pad-dry-cure method with different recipes formulated using an acrylic binder and wax emulsifier together with TiO2 nanoparticles to observe the optimal effect on the final quality. The treated fabric is characterized by SEM, EDS, XRD, and FTIR. To analyze the results, the antimicrobial properties, UV protection, and crease resistance are measured as functional properties. Furthermore, tensile and tearing strength, frictional resistance, bending length, abrasion resistance, and pilling are determined as mechanical properties. The results confirm that the binder significantly affects on nano deposition and improves the mentioned functional characteristics. However, the deposition of nano TiO2 has deteriorated cotton's mechanical properties, and that degradation is intensified by the use of binder. This degradation problem is overcome by using the emulsifier as an auxiliary since the recipe having an emulsifier improves all the mechanical qualities of nano-treated cotton fabric. Particularly, the sample containing a binder and an emulsifier (Nano TiO2-3) ensures up to 97 % UV-ray blockage, 93 % antibacterial activity, and 9 % increase in tensile strength.

Anti-flammable, anti-fouling, anti-bacterial treatment of cotton fabrics with MOF-based hybrid coatings for highly efficient oil-water separation.

A flame-retardant and hydrophobic coating was deposited on the surface of the cotton fabric via a two-step spray deposition technique. Specifically, the coating was composed of flame-retardant component (guanidine phosphate) and hydrophobic components (Ti-MOF and bis(3-aminopropyl)-terminated poly(dimethylsiloxane) (PDMS)) and crosslinked with glutaraldehyde. The limiting oxygen index (LOI) of the coated cotton fabrics increased from 18.0 % to 32.0 % (15#) and 26.5 % (15#-Ti-PDMS) relative to that of the original cotton fabric, and the coated cotton fabrics also self-extinguished in the UL-94 flammability test. Compared with that of the original cotton fabric, the PHRR of the coated fabrics was significantly lower, reaching 80 %. The coated cotton fabrics (15# and 15#-Ti-PDMS) had good antibacterial properties against Staphylococcus aureus (S. aureus). In addition, 15#-Ti-PDMS had high hydrophobicity, good washing and abrasion resistance and good water-oil separation performance. Its water contact angle was 146°. The water contact angle remained above 130° after 10 laundering cycles and 50 scratch cycles. Even under strongly acidic and strongly basic conditions, the water-oil separation efficiency of 15#-Ti-PDMS was greater than 99 %, and it was still greater than 90 % after 10 cycles. Therefore, a simple and effective method for preparing flame-retardant, hydrophobic and antibacterial cotton fabric was developed.

Smart Cellulose-Based Janus Fabrics with Switchable Liquid Transportation for Personal Moisture and Thermal Management.

The Janus fabrics designed for personal moisture/thermal regulation have garnered significant attention for their potential to enhance human comfort. However, the development of smart and dynamic fabrics capable of managing personal moisture/thermal comfort in response to changing external environments remains a challenge. Herein, a smart cellulose-based Janus fabric was designed to dynamically manage personal moisture/heat. The cotton fabric was grafted with N-isopropylacrylamide to construct a temperature-stimulated transport channel. Subsequently, hydrophobic ethyl cellulose and hydrophilic cellulose nanofiber were sprayed on the bottom and top sides of the fabric to obtain wettability gradient. The fabric exhibits anti-gravity directional liquid transportation from hydrophobic side to hydrophilic side, and can dynamically and continuously control the transportation time in a wide range of 3-66 s as the temperature increases from 10 to 40 °C. This smart fabric can quickly dissipate heat at high temperatures, while at low temperatures, it can slow down the heat dissipation rate and prevent the human from becoming too cold. In addition, the fabric has UV shielding and photodynamic antibacterial properties through depositing graphitic carbon nitride nanosheets on the hydrophilic side. This smart fabric offers an innovative approach to maximizing personal comfort in environments with significant temperature variations.

Enhancing flame retardancy and multi-functionalization of environmentally friendly cotton fabrics with a polydimethylsiloxane-based polyurethane.

Phosphorus-containing flame retardants are prone to result in the buildup of biotoxins, while halogen flame retardants easily lead to hazardous gases. Therefore, it is crucial to develop a multifunctional flame-retardant cotton fabric without phosphorus and halogen. Herein, single-ended hydroxy-terminated polydimethylsiloxane (PDMS-ID) was synthesized through single-ended hydrosilicone oil and 1,4-butanediol, followed by the preparation of a waterborne polyurethane (RWPU) containing side chain polydimethylsiloxane through the reaction of PDMS-ID with isocyanate prepolymer. Characterization data shows that its particle size distribution is relatively dispersed while maintaining good emulsification performance. Based on this, a halogen-free and phosphorus-free multifunctional flame retardant cotton fabric (COF-BBN@RWPU) was successfully prepared through treatment with boric acid/borax/3-aminopropyltriethoxysilane solution and subsequent RWPU encapsulation. In vertical flammability test (VFT), COF-BBN@RWPU has a char length of 57 mm and a limiting oxygen index (LOI) of 42.3 % with a 11 % weight gain while pure cotton was burned through with a LOI of 18.0 %. In addition, the total heat release and total smoke release of COF-BBN@RWPU decreased by 80.0 % and 47.2 %, compared with pure cotton. Additionally, COF-BBN@RWPU can achieve a maximum contact angle of 140.1° with an oil-water separation rate of 98.4 %. This study presents an eco-friendly approach to achieving the multifunctionality of cellulose fabrics.

Construction of "ant-like tentacle" structure for ultra-sensitive detection of low-concentration ammonia through colorimetric fluorescent dual-signal gas-sensitive cotton fabric.

Detection and monitoring of ammonia (NH3) are crucial in various industries, including plant safety management, food freshness testing, and water pollution control. Nevertheless, creating portable, low-cost, highly sensitive, and easily regenerated ppm-level NH3 sensors poses a significant challenge. In this investigation, an innovative "ant-like tentacle" fabrication strategy was proposed, and a colorimetric fluorescent dual-signal gas-sensitive cotton fabric (PAH-fabric) for NH3 detection was successfully prepared by conventional dyeing using suitable molecular-level photoacid (PAH) sensitive units. The visual recognition lower detection limit of the ultra-low is 1.09 ppm-level. PAH-fabric is not only straightforward, convenient, and cost-effective to prepare, but it can also be efficiently regenerated and recycled multiple times (maintaining excellent gas-sensitive performance even after 100 cycles) by strategically leveraging volatile acid fumigation. Detailed molecular reaction mechanisms involved in the NH3 response and PAH-fabric regeneration are elucidated. PAH-fabric, available either as a portable kit or an alarm system, offers a promising approach for ultra-low NH3 detection. The demonstrated "ant-like tentacle" fabrication strategy introduces numerous possibilities for designing and developing sensors with adjustable response thresholds, particularly those requiring high sensitivity.

Sugar beet (Beta vulgaris L.) leaves as natural colorant for cotton dyeing using an ecofriendly approach toward industrial progress.

In the industrial sector, vegetable residual materials have received attention in the production of bio-colorant for textile dyeing. The current research endeavor is centered on investigating the possibility of using sugar beet leaves as a natural source of dye for the purpose of dyeing cotton fabrics. Different extraction methods were utilized to isolate the bio-colorant present in sugar beet residual material, and the most favorable colorant yield was obtained using a 5% methanolic KOH solution. For optimal dyeing results, the cotton fabric performed dyeing for a duration of 45 min at a temperature of 60 °C, using a salt solution concentration of 6 g/100 mL and 50 mL of the extracted dye solution. Characterization of dye using Fourier transform infrared spectroscopy analysis confirmed the presence of quercetin in the leaf extract. For the creation of a range of color variations, mordants that were chemical in nature, such as tannic acid, iron sulfate, potassium dichromate, and copper sulfate, as well as mordants that were bio-based, such as onion peel, pomegranate peel, henna, golden shower bark, and turmeric, were employed in harmony. In comparison, the utilization of bio-mordants resulted in darker shades that exhibited enhanced color intensity and superior color fastness properties with the value of 4-5 for wash, 4 for wet rubbing, 4-5 for dry rubbing, and 4-5 for light. The findings of this study hold significant value in terms of ecofriendly waste management and contribute to advancements in the industrial sector by utilizing waste residual materials as a natural source of colorants.

Construction of a durable, halogen-free, and phosphorus-free flame retardant cotton fabric system with hydrophobic properties by phase separation and interface polymerization.

Inspired by the synthesis of polyurethane, a multifunctional fabric with hydrophobic and long-lasting flame retardancy was prepared through the phase separation and interfacial reaction process between PEI (polyethyleneimine)/BX (borax) aqueous solution and isocyanate terminated polydimethylsiloxane (PDMS-NCO) in tetrahydrofuran solution. The limit oxygen index of the treated fabric increased from 18.0 % to 33.7 %, and the total heat release decreased by 34.2 %. The enhancement of flame retardant performance and thermal stability is attributed to the enhanced char-forming capacity. After 50 cycles of water washing, the cotton fabric can still pass the vertical flammability test because of the curing effect of PDMS-NCO on functional additives. Furthermore, SEM analysis revealed that the formation of nano-rough structures on the fibers was promoted by phase separation, thus leading an increased water contact angle of sample to 139°. The materials utilized in this modified process do not contain elements such as F, Cl, Br, and P, indicating its potential as an environmentally friendly methodology for fabric functionalization.

Low temperature carbonization and synergistic flame retardancy of cotton fabric coated by phosphorus­nitrogen flame retardants.

To solve the problems of flammability and smoldering of cotton fabric, its flame-retardant finishing was executed with biomass wool keratin (WK) and cyclic phosphate ester (CPE) through the soaking and baking process. The synergistic mechanism of WK low-temperature melting and CPE catalytic dehydration prompted the formation of protective carbonization layer on cotton fabric surface, and this protective layer reduced its pyrolysis rate, inhibited the production of combustible materials and improved its flame retardancy. The results of synchronous thermal analysis indicate that the initial decomposition temperature of WK and CPE is lower than that of cotton fabric, and they precede the endothermic degradation before fabric main body. This effectively promotes the low-temperature carbonization of cotton fabric and inhibits its pyrolysis. The initial decomposition temperature of WK/CPE treated fabrics advances by 47.9 °C-97.8 °C, presenting significant low-temperature carbonization trend. Moreover, they form 3.0 %-20.0 % aromatic structural char before the pyrolysis of cotton cellulose due to the low-temperature dehydration and carbonization reactions. The damage length after vertical burning is only 4.0 cm for treated fabric with five layers, its after-flame and smoldering disappear, and its limiting oxygen index value increases to 28.7 %. This research provides an effective idea for the flammability and smoldering problems of cotton fabric.

Flexible, breathable, and durable superhydrophobic cotton fabric modified by behenic acid, tung oil, and ZIF-8 with anti-icing and self-cleaning properties.

Textiles with self-cleaning and anti-icing capabilities in cold climates are essential for outdoor workers and enthusiasts. Superhydrophobic modification of textile surfaces is effective in imparting these characteristics. Although there are numerous methods available for manufacturing superhydrophobic textiles, careful consideration is warranted for environmental concerns over fluorochemicals, stability of superhydrophobic coatings, and fabric breathability. In this work, we utilized biomass resources such as tung oil and behenic acid, along with zeolitic imidazolate framework (ZIF-8), to modify cotton fabrics, thereby creating an innovative behenic acid/tung oil/ZIF-8 modified cotton (BTZC) fabric with anti-icing and self-cleaning features. This material manifests a unique nanoflower-shaped surface morphology, demonstrating exceptional superhydrophobicity with a static water contact angle (CA) of 162° and a sliding angle (SA) of 2°. Moreover, BTZC excels in its thermal stability, breathability, and resistance to icing. Equally impressive is its robust stability, as evidenced through rigorous testing under continuous washing and abrasion, sustained high and low temperatures, extreme pH environments, and immersion in various chemical solvents. BTZC presents as a fluorine-free, durable, economically viable alternative for outdoor textile applications, marking substantial progress in the utilization of biomass and metal-organic framework materials in the textile industry and promising implications for value enhancement.

Multifunctional Wearable Electronic Based on Fabric Modified by PPy/NiCoAl-LDH for Energy Storage, Electromagnetic Interference Shielding, and Photothermal Conversion.

With the rapid advancement of electronic technology, traditional textiles are challenged to keep up with the demands of wearable electronics. It is anticipated that multifunctional textile-based electronics incorporating energy storage, electromagnetic interference (EMI) shielding, and photothermal conversion are expected to alleviate this problem. Herein, a multifunctional cotton fabric with hierarchical array structure (PPy/NiCoAl-LDH/Cotton) is fabricated by the introduction of NiCoAl-layered double hydroxide (NiCoAl-LDH) nanosheet arrays on cotton fibers, followed by polymerization and growth of continuous dense polypyrrole (PPy) conductive layers. The multifunctional cotton fabric shows a high specific areal capacitance of 754.72 mF cm-2 at 5 mA cm-2 and maintains a long cycling life (80.95% retention after 1000 cycles). The symmetrical supercapacitor assembled with this fabric achieves an energy density of 20.83 Wh cm-2 and a power density of 0.23 mWcm-2. Moreover, the excellent electromagnetic interference shielding (38.83 dB), photothermal conversion (70.2 °C at 1000 mW cm-2), flexibility and durability are also possess by the multifunctional cotton fabric. Such a multifunctional cotton fabric has great potential for using in new energy, smart electronics, and thermal management applications.

Lightweight, breathable and self-cleaning polypyrrole-modified multifunctional cotton fabric for flexible electromagnetic interference shielding.

The thriving of wearable electronics and the emerging new requirements for electromagnetic interference (EMI) shielding have driven the innovation of EMI shielding materials towards lightweight, wearability and multifunctionality. Herein, the hierarchical polypyrrole nanotubes (PNTs)/PDMS structures are rationally constructed on the textile for obtaining multifunctional and flexible EMI shielding textiles by in-situ polymerization and surface coating. The modified cotton fabric possesses a conductivity of about 2715.8 S/m and an SET of 28.2 dB in the X band when the thickness is only 0.5 mm. After ultrasonic treatment, cyclic bending and washing, the conductivity and EMI shielding performance remain stable and exhibit long-term durability. Importantly, the textile's inherent lightweight, breathable and soft properties have been completely retained after modification. This work shows application potentiality in the field of EMI pollution protection and affords a novel path for the construction of multifunctionally wearable and durable EMI shielding materials.

Construction of composite self-assembly coating based on chitosan for enhancing the flame-retardant and antibacterial performances of cotton fabric.

In this work, the step-by-step dip-coating (SBS) method was used to effectively improve the drawback of LBL by reducing the construction of a multilayer polyelectrolyte. Bio-based flame retardants, phytic acid (PA), and chitosan (CS) were further self-assembly on the surface of cotton fabric treated by epichlorohydrin-modified aramid nanofibers (AEP), ionic liquid (IL), and Cu ion. The pure cotton fabric was immersed in each dipping liquid only once, improving fire safety and antibacterial performance. The treated cotton self-extinguished with a 59 mm char length in the vertical flammability test, and the limiting oxygen index (LOI) value increased from 18.5 % to 38.5 %. The result of the cone calorimeter test (CCT) revealed that the fire hazard of flame-retardant cotton noteworthy declined (e.g., ~44.1 % and 55.4 % decline in peak heat release rate (pHRR) and total heat release rate (THR)). Conspicuously, the treated cotton exhibited a remarkably inhibiting effect on E. coli and S. aureus activity. The cotton fabric after flame-retardant finishing exhibited excellent fire safety and antibacterial performance.

Synergistically active Fe3O4 magnetic and EDTA modified cellulose cotton fabric using chemical method and their effective pollutants removal ability from wastewater.

A unique combination of cotton fabric (CF) with a mixture of EDTA and APTES Fe3O4 magnetic particles was developed and utilized for the first time as an adsorbent for removing pollutants from wastewater. Initially, Fe3O4 was synthesized using the co-precipitation method. Further, the surface of Fe3O4 was modified by introducing amino functional groups through a reaction with APTES, resulting in Fe3O4-NH2. Following this, the surface of carbon fiber (CF) was altered using ethylenediaminetetraacetic acid (EDTA) to create CF@EDTA. Through the use of EDC-HCl and NHS, Fe3O4-NH2 was attached to the surface of CF@EDTA, resulting in the final product CF@EDTA/Fe3O4. Subsequently, the prepared CF@EDTA/Fe3O4 was utilized to adsorb metal pollutants from wastewater, with a thorough analysis conducted using various characterization techniques including FTIR, SEM, EDX, XRD, VSM, and XPS to study the materials. The study specifically aimed to assess the adsorption performance of our cotton-based material towards As(III) and Cr3+ metal ions. The pH study was also performed. Results indicated that the material exhibited an adsorption capacity of approximately 714 mg/g for As(III) ions and 708 mg/g for Cr3+ ions. The Langmuir and Freundlich models, as well as pseudo-first and second-order models were also analyzed. The Langmuir and pseudo-second-order models were found to best fit the data. In terms of regeneration and reusability, the materials showed straightforward regeneration and recyclability for up to 15 cycles. The remarkable adsorption capacity, combined with the unique blend of cotton and Fe3O4 magnet, along with its recyclability, positions our material CF@EDTA/Fe3O4 as a promising contender for wastewater treatment and other significant areas in water research.

A bio-based durable reactive flame retardant for cotton fabric based on lentinan.

Cotton fabric has extensive application due to its comfort and breathability. However, the inherent flammability limits its wide application. Durable polysaccharide-based flame retardants with a low impact on the softness of fabrics are rarely reported. In this work, a novel flame retardant ammonium phosphate of lentinan (APLNT) was synthesized and grafted on the surface of cotton fabric. The treated cotton fabric had a high limiting oxygen index (LOI) value of 43.3 % and passed the vertical burning test (VBT) with a 21.1 % weight gain of APLNT. Compared with control cotton, the peak heat release rate and total heat release values of Cotton-APLNT2 decreased by 92.8 % and 50.9 %, respectively. In addition, the cotton fabric still passed the VBT and kept an LOI value of 27.0 % even after 50 laundering cycles, indicating that the fabric can be used for daily needs. More importantly, the treated fabric remains soft. This research provided a new strategy for preparing bio-based durable flame retardant cotton fabrics.