Comparing the effect of two polishing systems on surface roughness of feldspathic, lithium disilicate, and translucent zirconia ceramics after orthodontic bracket debonding: An in vitro study.

INTRODUCTION: Debonding of orthodontic brackets on ceramic restorations leave a rough surface which should be efficiently polished. In this study the effect of two diamond polishing systems (DPS), namely Optra Fine® (OF) and Diapol Twist® (DT) on surface roughness (SR) of feldspathic (F), lithium disilicate (LD), and translucent zirconia (TZ) ceramics assessed after bracket debonding. MATERIALS AND METHODS: Ninety disc-shaped specimens fabricated from F, LD, and TZ ceramics and glazed (Gl). Ten glazed specimens of 3 ceramic types served as control (C) groups (n=30). Other 60 specimens were deglazed, and after specific surface preparation according to ceramic type, upper central incisor brackets were bonded. After debonding, the remaining adhesive composite removed with tungsten carbide bur and specimens randomly assigned into 6 groups. The nine experimental groups defined as: Glazed F specimens (C), Deglazed F specimens polished with DT, Deglazed F specimens polished with OF, Glazed LD specimens (C), Deglazed LD specimens polished with DT, Deglazed LD specimens polished with OF, Glazed TZ specimens (C), Deglazed TZ specimens polished with DT, Deglazed TZ specimens polished with OF. The SR assessed quantitatively by profilometry (Ra and Rz parameter) and qualitatively by scanning electron microscopy (SEM). Quantitative data were statistically analysed using Kolmogorov-Smirnov test, two-way ANOVA and Tukey post-hoc test (α=0.05). RESULTS: No significant difference found in SR of three glazed ceramic types (P=0.293 for Ra and P=0.473 for Rz). There was no significant difference of Ra between polished and glazed groups (P>0.05). However, difference in Rz was significant (P<0.05), and only TZ specimens could reach to the level of smoothness caused by glazing. CONCLUSIONS: Both diamond polishing systems can efficiently reduce the surface roughness, despite of ceramic type. Optra Fine® system showed a superior performance than Diapol Twist® without significant difference. LIMITATIONS: In this study only one brand of each ceramic type was investigated. This study was approved by Ethical Review Committee (IR.IAU.KHUISF.REC.1401.156).

Detection of Debonding Defects in Carbon Fiber-Reinforced Polymer (CFRP)-Rubber Bonded Structures Based on Active Lamb Wave Energy Analysis.

Carbon fiber-reinforced polymers (CFRPs) are widely used in the fabrication of solid rocket motor casings due to their exceptional performance. However, the bonding interface between CFRP and viscoelastic materials (rubber) is prone to debonding damage during service and storage under complex environmental conditions, which poses a significant threat to the structural integrity and reliability of the engine. Existing nondestructive testing (NDT) methods, such as X-ray imaging, infrared thermography, and ultrasonic testing, although somewhat effective, exhibit significant limitations in detecting interfacial defects in deep or multilayered composite materials, particularly under the challenging conditions of service and storage. This study proposes an innovative method based on active Lamb wave energy analysis and introduces the Damage Evolution Factor (DEF), specifically designed to detect and evaluate interfacial debonding defects in CFRP-rubber bonded structures within solid rocket motors during service and storage. Through numerical simulations and experimental validation, we selected the A0 mode Lamb wave, which is more sensitive to interfacial damage, as the incident wave and excited it on the surface of the structure. Displacement time-history response signals at observation points under different damage models were extracted and analyzed, and DEF values were calculated. The results show that DEF values increase with the size of the interfacial debonding damage. Similar trends were observed in experimental studies, further validating the effectiveness of this method and demonstrating that DEF can be used for the quantitative evaluation of interfacial debonding defects in CFRP-rubber bilayer bonded structures.

Innovative Fiber-Reinforced Polymer Rope-Based Closed-Form Retrofitting Methods Applied in Reinforced Concrete T-Shaped Beams under Torsion.

The fiber-reinforced polymer (FRP) strengthening of reinforced concrete (RC) elements with torsional deficiencies has not yet been extensively studied. Existing studies have primarily focused on rectangular RC beams. The few studies on L or T-shaped beams have used open-form retrofitting methods. However, premature debonding of the retrofitting from concrete surfaces often leads to detachment before achieving enhanced torsional capacity. This study introduces an innovative application of closed-form FRP retrofitting for RC T-beams against torsion. Two novel closed-form torsional upgrading methods were proposed and investigated through a comprehensive experimental program involving eight large-scale T-beams. One method employs FRP ropes embedded in transverse grooves near the surface, while the other combines U-shaped EB-FRP strips with FRP ropes. Additionally, two configurations were examined replicating scenarios where the upper part of the slab is accessible or inaccessible. The results demonstrate that the closed-form methods improve torsional strength by 9% to 25% and twist at failure by 92% to 536% compared to unstrengthened beams, with beams retrofitting through the slab exhibiting superior performance. Step-by-step technical guidelines of the proposed methods are presented to minimize construction defects and ensure effective implementation in real RC structures.

Does staining orthodontic adhesive provide an advantage in adhesive resin removal and enamel roughness? An in vitro study.

BACKGROUND: The removal of adhesive remnants after bracket debonding has been shown to cause damaging effects on the enamel surface. This study aimed to investigate the efficacy of stained adhesive remnant removal (ARR) on enamel roughness compared to translucent composite. MATERIAL AND METHODS: Thirty extracted premolar teeth were divided equally into three groups; conventional composite control group (CC), stained composite group (SC) and stained bonding solution group (SB). The buccal surface of each tooth was cleaned, dried and the surface roughness (Ra) was evaluated using a contact prophylometer (T0). After bracket debonding, a high-speed carbide bur under a water-cooling system was used for ARR in one direction and the time consumed for ARR was recorded. After ARR, the second mean Ra values were recorded (T1). The samples were then polished using polishing paste with low-speed rubber cup and the third mean Ra values were recorded (T2). RESULTS: Repeated one-way ANOVA revealed a significant difference in the mean Ra values at T0, T1 and T2 within each group P˂0.05. A statistically significant difference in the changes of the mean Ra values after ARR (T1-T0) and after polishing (T1-T2) was found between the CC group and both SC and SB groups. A significant difference in the time consumed for ARR was found between the three groups with CC group being the most time-consuming group. CONCLUSION: Stained composite material followed by the stained bonding solution provided better visibility during ARR with lower mean Ra values and less time for ARR compared totranslucent composite material.

Effects of Thermocycling with Two Different Curing Techniques on Enamel Micro-Cracks Formation, Debonding, and Failure Modes of Ceramic Brackets: An In Vitro Study.

Despite the rise in popularity of ceramic braces for adults, the risk of enamel microcracks (EMCs) upon removal remains a significant drawback for both dental professionals and patients. Our study aimed to assess the effects of thermocycling, pre-curing, and co-curing techniques with different bonding agents on the enamel surface of teeth after the removal of ceramic brackets. We also examined the incidence, quantity, length, and direction of EMCs on tooth surfaces. Additionally, the adhesive remnant index (ARI) scores and orthodontic bracket bond failure modes were evaluated and compared. The study divided 40 extracted upper canine teeth into ten groups for further analysis. Two groups had intact enamel as the negative control, while the remaining groups had orthodontic ceramic brackets bonded using different bonding agents and curing techniques. Thermocycling was performed in five groups, and ARI was assessed after debonding. The study findings were statistically significant (p < 0.05) in demonstrating the impact of curing techniques on EMCs and debonding outcomes. Seventh-generation bonding agents resulted in complete adhesive removal (ARI = 0). The microcracks' incidence, number, and length showed insignificant results. Differences in ARI between thermocycler and non-thermocycler samples were insignificant. Both co-curing and pre-curing techniques yielded comparable ARI results. This study highlights the importance of using advanced bonding agents to minimize enamel damage during ceramic bracket debonding.

In vitro assessment of cementation of CAD/CAM fabricated prostheses over titanium bases. A systematic review.

OBJECTIVES: The objective of this study is to investigate the outcomes of clinically relevant laboratory studies regarding the cementation of implant-supported restorations over ti-bases. MATERIALS AND METHODS: The present study has been conducted according to PRISMA statement. An electronic search was performed, including publications up to March 2024, to identify studies investigating the parameters affecting the cementation between ti-bases and CAD/CAM prostheses. An assessment of the internal validity was performed, using a custom-made risk of bias tool (QUIN). RESULTS: From the included studies, 40.1% were reported on luting systems, 25% on ti-base surface treatment, 25% on restoration surface, 21.8% on restoration material, and 18.7% on ti-base height. The majority of the included studies were associated with a medium risk of bias. In the absence of micro-retentive features, air-abrasion of ti-bases with a minimum height of 3.5 mm can be beneficial for restoration's retention. The bonding performance can vary not only between different bonding systems but also for different applications within the same system, based on a restoration's material and surface treatment as well as on ti-base height and surface treatment. CONCLUSIONS: The height of the ti-base seems to be the prevailing factor as it constitutes the prerequisite for other modifications of the bonding surfaces to have an advantageous effect. Since the parameters that can affect bonding performance between ti-base and restoration can interact with each other, it is important for the clinician to focus on verified bonding protocols.

Evaluation of Fatigue Damage Monitoring of Single-Lap Composite Adhesive Joint Using Conductivity.

The widely used adhesive joining technique suffers from the drawback of being unable to be dismantled to examine for degradation. To counteract this weakness, several structural health monitoring (SHM) methods have been proposed to reveal the joint integrity status. Among these, doping the adhesive with carbon nanotubes to make the joint conductive and monitoring its electrical resistance change is a promising candidate as it is of relatively low cost and easy to implement. In this work, resistance change to monitor fatigue debonding of composite single-lap adhesive joints has been attempted. The debonded area, recorded with a liquid penetrant technique, related linearly to the fatigue life expended. However, it correlates with the resistance change in two different trends. Scanning electron microscopy on the fracture surface reveals that the two trends are associated with distinct failure micromechanisms. Implications of these observations on the practical use of the resistance change for SHM are discussed.

Performance Evaluation of Structural Health Monitoring System Applied to Full-Size Composite Wing Spar via Probability of Detection Techniques.

Probability of detection (POD) is an acknowledged mean of evaluation for many investigations aiming at detecting some specific property of a subject of interest. For instance, it has had many applications for Non-Destructive Evaluation (NDE), aimed at identifying defects within structural architectures, and can easily be used for structural health monitoring (SHM) systems, meant as a compact and more integrated evolution of the former technology. In this paper, a probability of detection analysis is performed to estimate the reliability of an SHM system, applied to a wing box composite spar for bonding line quality assessment. Such a system is based on distributed fiber optics deployed on the reference component at specific locations for detecting strains; the attained data are then processed by a proprietary algorithm whose capability was already tested and reported in previous works, even at full-scale level. A finite element (FE) model, previously validated by experimental results, is used to simulate the presence of damage areas, whose effect is to modify strain transfer between adjacent parts. Numerical data are used to verify the capability of the SHM system in revealing the presence of the modeled physical discontinuities with respect to a specific set of loads, running along the beam up to cover its complete extension. The POD is then estimated through the analysis of the collected data sets, wide enough to assess the global SHM system performance. The results of this study eventually aim at improving the current strategies adopted for SHM for bonding analysis by identifying the intimate behavior of the system assessed at the date. The activities herein reported have been carried out within the RESUME project.

Experimental Study on the Detection of the Existence and Location of Mimicked and Unexpected Interface Debonding Defects in an Existing Rectangular CFST Column with PZT Materials.

Interface bonding conditions between concrete and steel materials play key roles in ensuring the composite effect and load-carrying capacity of concrete-steel composite structures such as concrete-filled steel tube (CFST) members in practice. A method using both surface wave and electromechanical impedance (EMI) measurement for detecting the existence and the location of inaccessible interface debonding defects between the concrete core and steel tube in CFST members using piezoelectric lead zirconate titanate (PZT) patches as actuators and sensors is proposed. A rectangular CFST specimen with two artificially mimicked interface debonding defects was experimentally verified using PZT patches as the actuator and sensor. By comparing the surface wave measurement of PZT sensors at different surface wave travelling paths under both a continuous sinusoidal signal and a 10-period sinusoidal windowed signal, three potential interface debonding defects are quickly identified. Furthermore, the accurate locations of the three detected potential interface debonding defects are determined with the help of EMI measurements from a number of additional PZT sensors around the three potential interface debonding defects. Finally, the accuracy of the proposed interface debonding detection method is verified with a destructive observation by removing the local steel tube at the three detected interface debonding locations. The observation results show that the three detected interface debonding defects are two mimicked interface debonding defects, and an unexpected debonding defect occurred spontaneously due to concrete shrinkage in the past one and a half years before conducting the test. Results in this study indicate that the proposed method can be an efficient and accurate approach for the detection of unknown interface debonding defects in existing CFST members.

Enhancing Flexural Behavior of Reinforced Concrete Beams Strengthened with Basalt Fiber-Reinforced Polymer Sheets Using Carbon Nanotube-Modified Epoxy.

The external bonding (EB) of fiber-reinforced polymer (FRP) is a usual flexural reinforcement method. When using the technique, premature debonding failure still remains a factor of concern. The effect of incorporating multi-wall carbon nanotubes (MWCNTs) in epoxy resin on the flexural behavior of reinforced concrete (RC) beams strengthened with basalt fiber-reinforced polymer (BFRP) sheets was investigated through four-point bending beam tests. Experimental results indicated that the flexural behavior was significantly improved by the MWCNT-modified epoxy. The BFRP sheets bonded by the MWCNT-modified epoxy more effectively mitigated the debonding failure of BFRP sheets and constrained crack development as well as enhanced the ductility and flexural stiffness of strengthened beams. When the beam was reinforced with two-layer BFRP sheets, the yielding load, ultimate load, ultimate deflection, post-yielded flexural stiffness, energy absorption capacity and deflection ductility of beams strengthened using MWCNT-modified epoxy increased by 7.4%, 8.3%, 18.2%, 22.6%, 29.1% and 14.3%, respectively, in comparison to the beam strengthened using pure epoxy. It could be seen in scanning electron microscopy (SEM) images that the MWCNTs could penetrate into concrete and their pull-out and crack bridging consumed more energy, which remarkably enhanced the flexural behavior of the strengthened beams. Finally, an analytical model was proposed for calculating characteristic loads and characteristic deflections of RC beams strengthened with FRP sheets, which indicated a reasonably good correlation with the experimental results.

Bond Shear Tests to Evaluate Different CFRP Shear Strengthening Strategies for I-Shaped Concrete Cross-Sections.

I-shaped concrete girders are widely used in precast bridge and roof construction, making them a common structural component in existing infrastructure. Despite well-established strengthening techniques using various innovative materials, such as externally bonded carbon fibre reinforced polymer (CFRP) reinforcement, the shear strengthening of an I-shaped concrete girder is not straightforward. Several research studies have shown that externally bonded CFRP reinforcement might exhibit early debonding at the concave corners of the I-shape, resulting in a marginal increase in shear capacity. This research study aims to assess the performance of two different CFRP shear strengthening strategies for I-shaped concrete cross-sections. In the first strategy, CFRP was bonded along the I-shape of the cross-section with the provision of additional anchorage. In the second strategy, the I-shape was transformed into a rectangular shape by using in-fill blocks over which the CFRP was bonded in a U-configuration. In addition to the strengthening strategies, the investigated parameters included two different materials for the in-fill blocks (conventional and aerated concrete) and two different anchoring schemes (bolted steel plate anchor and CFRP spike anchor). To avoid testing on large-scale girders, a new test methodology has been implemented on concrete I-sections. The test results demonstrate the feasibility of comparing different shear strengthening configurations dedicated to I-sections. Among other findings, the results showed that the local transformation of the I-shape to an equivalent rectangular shape could be a viable solution, resulting in shear strength enhancement of 12% to 53% without and with the anchorages, respectively.

Redox-triggered debonding of mussel-inspired pressure sensitive adhesives: Improving efficiency through functional design.

Debondable pressure-sensitive adhesives (PSAs) promise access to recyclability in microelectronics in the transition toward a circular economy. Two PSAs were synthesized from a tetravalent thiol star-polyester forming thiol-catechol-connectivities (TCC) with either biorelated DiDopa-bisquinone (BY*Q) or fossil-based bisquinone A (BQA). The PSAs enable debonding by oxidation of TCC-catechols to quinones. The extent of debonding efficiency depends on the interaction modes, which are determined by the chemical structure differences of both TCC-motifs. BY*Q-TCC-PSA debonds with exceptional loss of 99% of its approx. 2 MPa shear strength. For BQA-TCC-PSA, a debonding efficiency of only approx. 60% was found, irrespective of its initial shear strength, which could be tuned up to approx. 7 MPa. The efficiency of debonding for BY*Q-TCC-PSA after TCC-oxidation is linked to the loss of synergistic interactions without strongly affecting the bulk glue properties, outperforming the purely catechol-based BQA-analogue.

Enhancing 3D printed ceramic components: The function of dispersants, adhesion promoters, and surface-active agents in Photopolymerization-based additive manufacturing.

In the domain of photopolymerization-based additive manufacturing (3D vat printing), ceramic photopolymer resins represent a multifaceted composite, predominantly comprising oligomers, ceramic fillers, and photoinitiators. However, the synergy between the ceramic fillers and polymer matrix, along with the stabilization and homogenization of the composite, is facilitated by specific additives, notably surface-active agents, dispersants, and adhesion promoters. Although these additives constitute a minor fraction in terms of volume, their influence on the final properties of the material is substantial. Consequently, their meticulous selection and integration are crucial, subtly guiding the performance and characteristics of the resultant ceramic matrix composites toward enhancement. This review delves into the array of dispersants and coupling agents utilized in the additive manufacturing of ceramic components. It elucidates the interaction mechanisms between these additives and ceramic fillers and examines how these interactions affect the additive manufacturing process. Furthermore, this review investigates the impact of various additives on the rheological behavior of ceramic slurries and their subsequent effects on the post-manufacturing stages, such as debinding and sintering. It also addresses the challenges and prospects in the optimization of dispersants and coupling agents for advanced ceramic additive manufacturing applications.

Effect of Er,Cr: YSGG laser debonding treatment on the optical properties and surface roughness of ceramic laminate veneers: An in vitro study.

PURPOSE: The objective of this study was to evaluate the effect of (Er,Cr: YSGG) laser debonding treatment on optical properties and surface roughness of veneers made of different ceramic materials. MATERIALS AND METHODS: Thirty bovine incisors were prepared to receive laminate veneers and divided into three groups (n = 10) according to ceramic material where group (E): IPS e.max CAD, group (S): Vita Suprinity, and group (C): Celtra Duo. Blocks were sectioned into 0.5 mm thickness plates and cemented on the labial surface of incisors using resin cement. The Er,Cr: YSGG laser was applied to each specimen at 4.5 W and 25 Hz for group E and at 6 W and 25 Hz for groups S and C. Color change (△E00), translucency parameter (TP) and surface roughness in µm (Ra) values were measured and calculated before and after laser treatment. Data were analyzed using two-way mixed model ANOVA at a significance level of p < 0.05. RESULTS: The highest mean △E00 value was recorded in group E (1.35 ± 0.09) followed by group S (1.08 ± 0.16) and then group C (0.93 ± 0.10) with a significant difference between them (p < 0.001). All groups exceeded the perceptibility threshold but remained below the acceptability threshold. No statistically significant difference was found in TP except for group E (p = 0.019). Ra values after laser debonding showed significantly higher values than before laser treatment in all three groups (p < 0.001). CONCLUSION: Er,Cr: YSGG laser can be safely used for debonding ceramic veneers without altering the optical properties but it does increase the roughness of debonded ceramic restorations.

Using nanosecond laser pulses to debond the glass-EVA layer from silicon photovoltaic modules.

The active silicon cell of a solar photovoltaic (PV) panel is covered by an ethylenevinylacetate (EVA) adhesive and a protective top glass layer. Separating this glass-EVA layer from the underlying silicon represents a bottleneck for recycling PV panels. Previous work has shown that the EVA-Si bond can be weakened by applying a continuous source of heat to melt the EVA. In this paper, a new method using nanosecond laser pulses is demonstrated to induce transient melting selectively at the EVA-Si interface. This impulsive heating method can cleanly separate the glass-EVA layer from the silicon in both model and commercial multicrystalline PV panels. The dependence of this debonding on parameters like laser pulse fluence (laser pulse energy per area), wavelength, applied pressure, and scan speed were characterized. For model PV panels, the single-pulse laser fluences required for spontaneous separation of the assembly under the force of gravity, were 0.23, 0.32 and 0.78 J/cm2 for 355 nm, 532 nm and 1064 nm, respectively. The use of shorter wavelengths reduces the laser fluence needed for debonding, while higher fluences can compensate for faster laser beam scanning rates. Optical and electron microscopy images of the Si surfaces before and after laser irradiation show that the textured antireflection layer is destroyed but the silver metal grid remains intact. Preliminary experiments using 532 nm pulses showed that the laser debonding method could remove the glass-EVA layer from sections of decommissioned commercial PV panels, even when the top glass layer was densely cracked.

Inspection of Liner Wall Thinning and Interface Debonding in Bimetallic Lined Pipes Using Pulsed Eddy Current Testing.

Bimetallic lined pipe (BLP) has been increasingly used in offshore and subsea oil and gas structures, but how to identify the invisible inner defects such as liner wall thinning and interface debonding is a challenge for future development. A nondestructive testing (NDT) method based on pulsed eddy current testing (PECT) has been proposed to face these difficulties. The inspection of the BLP specimen (AISI1020 base tube and SS304 liner) is implemented from outside of the pipe by using a transmitter-receiver-type PECT probe consisting of two induction coils. By simplifying the BLP specimen to stratified conductive plates, the electromagnetic field interaction between the PECT probe and specimen is analytically modeled, and the probe inspection signals due to liner wall thinning and interface debonding are calculated. In order to highlight the weak response (in microvolts) from the liner, the inspection signals are subtracted by the signal, which is calculated in the case of only having a base tube, yielding differential PECT signals. The peak voltage of the differential signal is selected to characterize the liner wall thinning and interface debonding due to its distinguishable and linear variation. Experiment verification is also carried out on a double-walled specimen simulated by a combination of a Q235 casing pipe and SS304 tubes of different sizes. The experimental results basically agree with the analytical predictions. The peak value of the PECT signal has an ascending and descending variation with the increase in the remaining liner wall thickness and debonding gap, respectively, while the negative peak value shows opposite changes. The peak value exhibits a larger sensitivity than the negative peak value. The proposed method shows potential promise in practical applications for the evaluation of the inner defects in BLP lines.

Efficacy of Lasers in Debonding Ceramic Brackets: Exploring the Rationale and Methods.

The development of ceramic brackets in orthodontics three decades ago emerged as a response to the increasing patient demand for less visible orthodontic appliances. While these brackets provide superior aesthetics, they are characterized by lower fracture toughness and higher bond strength in contrast to metal brackets. These properties present challenges during the debonding step, including the risk of enamel micro-fractures and cracks. Historically, various strategies have been developed to address challenges associated with debonding, reduce patient discomfort, and ensure that the bond failure site is confined to the bracket-adhesive interface. This included the use of specially designed debonding pliers, electrothermal debonding, ultrasonic technique, and chemical agents. Recently, there has been a shift towards utilizing different types of laser irradiation for this purpose. The burgeoning strategy, however, requires diligent scientific scrutiny to establish a standardized protocol with particular laser parameters and ultimately achieve the goal of enhancing the patient experience by reducing discomfort. This article offers a narrative review of laser-aided debonding of ceramic brackets, aimed at comparing different laser types, presenting their benefits and downsides, validating the efficiency of each method, and summarizing the published literature on this subject. It also provides insights for orthodontists on reducing patient discomfort that usually accompanies debonding ceramic brackets by delving into the science behind the use of lasers for this purpose.

Performance of two laser motion modes versus conventional orthodontic ceramic brackets debonding technique on enamel surface topography.

The risk of enamel deterioration that frequently coexists with debonding of orthodontic teeth brackets elevates the mandate for finding an optimum approach for debonding them without harmful effects. This in-vitro study is intended to compare the effects of two different laser modes (scanning and circular) and a conventional method on the enamel surface after debonding orthodontic brackets. 66 extracted premolars were assigned into 3 groups. After that, light-cure composite resin was used to attach the ceramic brackets to the teeth. Amongst the test groups, Group I: specimens that were debonded using conventional debonding using pliers; Group 2: specimens that were debonded using Er, Cr: YSGG laser applications using the circular motion method; and Group 3: specimens that were debonded using Er, Cr: YSGG laser applications using the scanning motion method. Adhesive Remnant Index (ARI) assessment, intra-pulpal temperature increase, enamel surface roughness after polishing, and assessment of the microstructure of enamel were carried out with scanning electron microscopy. The gathered information was examined statistically. The conventional debonding method had a significantly higher proportion of adhesive remnant index (ARI) scores of 2 and 3 in comparison to the circular (p < .004) and scanning laser groups (p < .001). There was no significant difference in ARI scores between the circular and scanning laser groups (p > .05). Moreover, the circular and scanning laser debonding methods resulted in a significantly higher proportion of Enamel Surface Roughness (ESR) scores of 0 and a lower proportion of ESR scores of 3 compared to the conventional technique group (p < .001). However, there was no significant difference in ESR scores between the circular and scanning laser methods (p = .945). Lastly, the average intra-pulpal temperature was significantly higher in the circular laser group (1.9 ± 0.5 ) compared to the scanning laser group (0.9 ± 0.2) with p < .001. Er, Cr: YSGG laser irradiation is a tool that shows promise for debonding ceramic brackets with minimal harm to the enamel surface. The scanning laser technique is more desirable due to the lower intra-pulpal temperature increase.

Synthesis and evaluation of fluorescent resins with europium-ß-diketonate complex for orthodontic use.

No effective technique exists for removing adhesive remnants following bracket debonding. We propose that fluorescence imaging using europium ions (Eu3+) offers an effective solution for minimizing iatrogenic enamel damage. This study aimed to assess the impact of different mixing ratios of monomer mixtures on the photoluminescence and flexural properties of a newly developed fluorescent adhesive. Four monomer blends with varying urethane dimethacrylate (UDMA) to triethylene glycol dimethacrylate (TEGDMA) ratios were prepared and polymerized. The blends contained 0.1 wt% of tris(1,3-diphenyl-1,3-propanedionato)(1,10-phenanthroline) Eu(III), [Eu(DBM)3Phen], as the phosphor. Optical measurements and flexural tests were conducted for each resin specimen. The emission spectra exhibited narrow bands corresponding to the 4f-4f transitions of the Eu3+ ions. The photoluminescence properties remained unaffected by the mixing ratio, whereas the mechanical properties tended to improve with higher UDMA content. We conclude that the Eu(DBM)3Phen-containing resin shows promise as a fluorescent orthodontic adhesive that contributes to preserving enamel health.

The effect of freezing on the fracture pattern of adhesive on debonding: an in-vitro study.

The purpose of this study was to quantitatively evaluate adhesive remnants on the enamel surface following bracket debonding using a freezing element. Thirty-six sound premolars were used in this study. In each case, a bracket was bonded onto each tooth with conventional light-cured composite resin and de-bonded after one week. Freezing of the underlying composite through the bracket was performed immediately before debonding with a portable cryosurgical system (-55 °C). Specimens were divided into three groups according to the duration of freezing: a control group without freezing was used as a reference and two interventional groups with different durations of freezing (15 or 40 s). Brackets were removed by using debonding pliers to squeeze the wings of the bracket in an occluso-gingival manner. Adhesive remnants on the tooth were then quantitatively evaluated by stereo-microscopy. Pearson's Chi-squared test was used to investigate the relationship between the proportion of remaining resin and the group of teeth. In the control group, 100% of the composite remained on the enamel surface of all specimens. Significantly less adhesive remnants were found in the intervention groups (p = 0.001 for the 15 s group and p = 0.043 for the 40 s group). There was no significant difference between the two interventions (p = 0.165) in terms of the proportion of remaining adhesive remnants. Freezing of the bracket and the underlying adhesive resin prior to bracket debonding may favorably alter the behavioral pattern of composite fracture, thus reducing the extent of adhesive remnants on the enamel. Increasing the freezing time from 15 to 40 s did not exert significant effects on adhesive remnants following debonding. Further research now needs to investigate the effect of freezing on the mechanical properties of the adhesive remnants and its in-vivo effect on pulp vitality over both short- and long-terms.