Generalized and Scalable Synthesis of Manganese Dioxide-Based Tubular Micromotors for Heavy Metal Ion Removal.

Synthetic nano- and micromachines hold immense promise in biomedicine and environmental science. Currently, bubble-driven tubular micro/nanomotors have garnered increasing attention owing to their exceptional high-speed self-propulsions. However, complex and low-yield preparation methods have hindered their widespread applications. Herein, we present a generalized, scalable, and low-cost electrospinning-based strategy to fabricate MnO2-based composite tubular micromotors (MnO2-TMs) for efficient heavy metal ion removal. The inherent flexibility of precursor nanofibers derived from diverse matrix materials enables the creation of MnO2-TMs with a wide range of morphologies. In response to morphology changes, the MnO2-TMs, based on a bubble-propelled mechanism, exhibit multimodal motion patterns, including linear, circular, and spiral to stochastic swinging. To elucidate the underlying morphology-to-motion relationship, we conducted systematic simulations of fluid dynamics around the MnO2-TMs. Furthermore, by incorporation of Fe3O4 nanoparticles, the capabilities of MnO2-TMs can be expanded to include magnetic manipulation for directional navigation and efficient retrieval. Benefiting from these attributes, MnO2-TMs excel in removing heavy metal ions from water. The developed MnO2-MnWO4@Fe3O4 TMs exhibit prominent adsorption capacities of 586.5 mg g-1 for Cu2+ and 156.4 mg g-1 for Pb2+. Notably, the magnetic property facilitates rapid separation and retrieval of the micromotors, and the absorbed ions can be simply recovered by pH adjustment. This work establishes a general framework for developing MnO2-based tubular micro/nanomotors to address environmental challenges.

Visible-light-prompted photoelectrochemical sensors fabricated using Er3NbO7/P@g-C3N4/SnS2 nanocomposite for detecting mercury ion in environmental water samples.

Photoelectrochemical (PEC) detection technology is key for fighting pollution, leveraging the photoelectric conversion of the photoelectrode material. A specialized photoelectrode was developed to detect Hg2+ ions with exceptional sensitivity, utilizing an anodic PEC sensor composed of Er3NbO7/P@g-C3N4/SnS2 ternary nanocomposite. Rare earth metal niobates (RENs) were chosen due to their underexplored potential, whose performance was enhanced through bandgap engineering and surface modification, facilitated by P@g-C3N4 as an immobilization matrix and SnS2, belonging to the I-IV semiconductors category fostering hybrid heterojunction formation for boasting optical properties and suitable redox potentials. Introducing Hg2+ into the system, a specific amalgamation reaction occurs between reduced Hg and Sn. This reaction obstructs electron transfer to the FTO electrode surface, leading to the recombination of charges. The proposed PEC sensor exhibited remarkable analytical performance for Hg2+ detection, high sensitivity, a detection limit of 0.019 pM, excellent selectivity, and a detectable concentration range of 0.002-0.15 nM. Additionally, it demonstrated good recovery and low relative standard deviation when analyzing Hg2+ in water samples, highlighting the potential application of the heterostructure in detecting heavy metal ions via PEC technology.

Emerging insights into the application of metal-organic framework (MOF)-based materials for electrochemical heavy metal ion detection.

Heavy metal ions are one of the main sources of water pollution, which has become a major global problem. Given the growing need for heavy metal ion detection, electrochemical sensor stands out for its high sensitivity and efficiency. Metal-organic frameworks (MOFs) have garnered much interest as electrode modifiers for electrochemical detection of heavy metal ions owing to their significant specific surface area, tailored pore size, and catalytic activity. This review summarizes the progress of MOF-based materials, including pristine MOFs and MOF composites, in the electrochemical detection of various heavy metal ions. The synthetic methods of pristine MOFs, the detection mechanisms of heavy metal ions and the modification strategies of MOFs are introduced. Besides, the diverse applications of MOF-based materials in detecting both single and multiple heavy metal ions are presented. Furthermore, we present the current challenges and prospects for MOF-based materials in electrochemical heavy metal ion detection.

Application of catalytic technology based on the piezoelectric effect in wastewater purification.

The demands of human life and industrial activities result in a significant influx of toxic contaminants into aquatic ecosystems. In particular, organic pollutants such as antibiotics and dye molecules, bacteria, and heavy metal ions are represented, posing a severe risk to the health and continued existence of living organisms. The method of removing pollutants from water bodies by utilizing the principle of the piezoelectric effect in combination with chemical catalytic processes is superior to other wastewater purification technologies because it can collect water energy, mechanical energy, etc. to achieve cleanliness and high removal efficiency. Herein, we briefly introduced the piezoelectric mechanisms and then reviewed the latest advances in the design and synthesis of piezoelectric materials, followed by a summary of applications based on the principle of piezoelectric effect to degrade pollutants in water for wastewater purification. Moreover, water purification technologies incorporating the piezoelectric effect, including piezoelectric effect-assisted membrane filtration, activation of persulfate, and battery electrocatalysis are elaborated. Finally, future challenges and research directions for the piezoelectric effect are proposed.

Thiol-Functionalized Adsorbents through Atomic Layer Deposition and Vapor-Phase Silanization for Heavy Metal Ion Removal.

The removal of toxic heavy metal ions from water resources is crucial for environmental protection and public health. In this study, we address this challenge by developing a surface functionalization technique for the selective adsorption of these contaminants. Our approach involves atomic layer deposition (ALD) followed by vapor-phase silanization of porous substrates. We utilized porous silica gel powder (∼100 µm particles, 89 m2/g surface area, ∼30 nm pores) as an initial substrate. This powder was first coated with ∼0.5 nm ALD Al2O3, followed by vapor-phase grafting of a thiol-functional silane. The modified powder, particularly in acidic conditions (pH = 4), showed high selectivity in adsorbing Cd(II), As(V), Pb(II), Hg(II), and Cu(II) heavy metal ions in mixed ion solutions over common benign ions (e.g., Na, K, Ca, and Mg). Langmuir adsorption isotherms and breakthrough adsorption studies were conducted to assess heavy metal binding affinity and revealed the order of Cd(II) < Pb(II) < Cu(II) < As(V) < Hg(II), with a significantly higher affinity for As(V) and Hg(II) ions. Time-dependent uptake studies demonstrated rapid removal of heavy metal ions from aqueous environments, with Hg(II) exhibiting the fastest adsorption kinetics on thiol-modified surfaces. These findings highlight the potential of ALD and vapor-phase silanization to create effective adsorbents for the targeted removal of hazardous contaminants from water.

A novel bio-based fluorescent N, P-CDs@CMC/PEI composite hydrogel for sensitive detection and efficient capture of toxic heavy metal ions.

To address the serious environmental pollution problems of toxic heavy metal ions in water bodies, a novel fluorescent composite hydrogel N, P-CDs@CMC/PEI with a bio-based polymer matrix of carboxylmethyl cellulose (CMC), polyethylenimine (PEI) as a second interpenetrating network and N, P-doped carbon dots (N, P-CDs) as a fluorescent probe was prepared for simultaneous detection and capture of HMIs by a facile and simple one-step approach. The morphology, chemical structure, swelling ratio, mechanical strength and fluorescence property of these composite hydrogels were studied through varied characterization methods. The composite hydrogel showed sensitive and selective fluorescence response with Hg(II) and Fe(III) and the according LOD values were 0.48 and 0.27 mg L-1, respectively. The relationship between the types of the adsorbent, pH value, HMIs concentration and temperature on the adsorption capacity of these composite hydrogels were studied. The pseudo-second-order model and Langmuir model were applicable to explain the adsorption process of CPH2 for Hg(II) and Cr(VI). The maximum calculated adsorption capacities for the above targeted HMIs by Langmuir model were 846.7 and 289.5 mg g-1, respectively. Coexisting inorganic salts and organic acids in low concentration had little effects on Hg(II) and Cr(VI) removal and the composite hydrogel showed good recyclability and stability for Hg(II) and Cr(VI) removal after four cycles. The electrostatic attraction and coordination covalent bonds were responsible for the adsorption process.

Single-drop electrodeposition of nanoneedle-like bismuth on disposable graphene electrode for on-site electrochemical detection of cadmium and lead.

A novel cost-effective disposable porous graphene electrode (P-GE) modified with bismuth nanoneedles (nano-BiNDs) is proposed as a "mercury-free" sensor for detecting heavy metals through smartphone-assisted electrochemical sensing. The P-GE was fabricated using screen-printing. Nano-BiNDs were generated on the P-GE by potentiostatic electrodeposition. Using an optimal potential of -1.20 V (vs. pseudo-Ag/AgCl) and a deposition time of 200 s, the nano-BiNDs had an average length and width of 189 ± 5 nm and 20 ± 2 nm, respectively. The analytical performances of the fabricated sensing platform were demonstrated by detecting Cd2+ and Pb2+ using square-wave anodic stripping voltammetry (SWASV) under optimized conditions. In the optimal conditions, the fabricated sensor exhibited sharp, well-defined stripping peaks for Cd2+ and Pb2+ with excellent peak-to-peak separation. The linear detection ranges were from 0.01 to 50 µg mL-1 for Cd2+ and 0.006-50 µg mL-1 for Pb2+. The detection limits for Cd2+ and Pb2+ were 3.51 and 2.10 ng mL-1, respectively. The developed portable sensor demonstrated high sensitivity, good repeatability, reproducibility, and anti-interference properties. The proposed portable sensor quantified Cd2+ and Pb2+ in commercial seaweed products with good accuracy, consistent with the results obtained using the standard ICP-OES method.

Ultrasensitive detection of Ag+and Ce3+ions using highly fluorescent carboxyl-functionalized carbon nitride nanoparticles.

The fluorescence quenching of carboxyl-rich g-C3N4nanoparticles was found to be selective to Ag+and Ce3+with a limit of detection as low as 30 pM for Ag+ions. A solid-state thermal polycondensation reaction was used to produce g-C3N4nanoparticles with distinct green fluorescence and high water solubility. Dynamic light scattering indicated an average nanoparticle size of 95 nm. The photoluminescence absorption and emission maxima were centered at 405 nm and 540 nm respectively which resulted in a large Stokes shift. Among different metal ion species, the carboxyl-rich g-C3N4nanoparticles were selective to Ag+and Ce3+ions, as indicated by strong fluorescence quenching and a change in the fluorescence lifetime. The PL sensing of heavy metal ions followed modified Stern-Volmer kinetics, and CNNPs in the presence of Ag+/Ce3+resulted in a higher value ofKapp(8.9 × 104M-1) indicating a more efficient quenching process and stronger interaction between CNNP and mixed ions. Sensing was also demonstrated using commercial filter paper functionalized with g-C3N4nanoparticles, enabling practical on-site applications.

Biofilm hydrogel derived from physical crosslinking (self-assembly) of xanthan gum and chitosan for removing Cd2+, Ni2+, and Cu2+ from aqueous solution.

This study aimed to fabricate a series of biodegradable hydrogel films by gelating/physically crosslinking a blend of xanthan gum (XG) and chitosan (CS) in various combinations using a facile, green, and low cost solution casting technique. The adsorption of Cd2+, Cu2+ and Ni2+ by the XG/CS biofilm in aqueous solution was studied in batch experiments to determine how the pH of the solution, contact time, dosage of adsorbent, initial metal ion concentration and ionic strength affect its adsorption. A highly pH-dependent adsorption process was observed for three metal ions. A maximum amount of Cd2+, Ni2+, and Cu2+ ions was adsorbable with 50 mg of the adsorbent at pH 6.0 for an initial metal concentration of 50 mg.L-1. An empirical pseudo-second-order model seems to fit the kinetic experimental data reasonably well. It was found that the Langmuir model correlated better with equilibrium isotherm when compared with the Freundlich model. For Cd2+, Ni2+, and Cu2+ ions at 25 °C, the maximum monolayer adsorption capacity was 152.33, 144.79, and 139.71 mg.g-1, respectively. Furthermore, the biofilm was capable of regenerating, allowing metal ions to adsorb and desorb for five consecutive cycles. Therefore, the developed biodegradable film offers the potential for remediation of specified metal ions.

Nanocellulose-stabilized nanocomposites for effective Hg(II) removal and detection: a comprehensive review.

Mercury pollution, with India ranked as the world's second-largest emitter, poses a critical environmental and public health challenge and underscores the need for rigorous research and effective mitigation strategies. Nanocellulose is derived from cellulose, the most abundant natural polymer on earth, and stands out as an excellent choice for mercury ion remediation due to its remarkable adsorption capacity, which is attributed to its high specific surface area and abundant functional groups, enabling efficient Hg(II) ion removal from contaminated water sources. This review paper investigates the compelling potential of nanocellulose as a scavenging tool for Hg(II) ion contamination. The comprehensive examination encompasses the fundamental attributes of nanocellulose, its diverse fabrication techniques, and the innovative development methods of nanocellulose-based nanocomposites. The paper further delves into the mechanisms that underlie Hg removal using nanocellulose, as well as the integration of nanocellulose in Hg detection methodologies, and also acknowledges the substantial challenges that lie ahead. This review aims to pave the way for sustainable solutions in mitigating Hg contamination using nanocellulose-based nanocomposites to address the global context of this environmental concern.

A Novel Thin-Layer Flow Cell Sensor System Based on BDD Electrode for Heavy Metal Ion Detection.

An electrochemical sensor based on a thin-layer flow cell and a boron-doped diamond (BDD) working electrode was fabricated for heavy metal ions determination using anodic stripping voltammetry. Furthermore, a fluidic automatic detection system was developed. With the wide potential window of the BDD electrode, Zn2+ with high negative stripping potential was detected by this system. Due to the thin-layer and fluidic structure of the sensor system, the electrodepositon efficiency for heavy metal ions were improved without using conventional stirring devices. With a short deposition time of 60 s, the system consumed only 0.75 mL reagent per test. A linear relationship for Zn2+ determination was displayed ranging from 10 µg/L to 150 µg/L with a sensitivity of 0.1218 µA·L·µg-1 and a detection limit of 2.1 µg/L. A high repeatability was indicated from the relative standard deviation of 1.60% for 30 repeated current responses of zinc solution. The system was applied to determine Zn2+ in real water samples by using the standard addition method with the recoveries ranging from 92% to 118%. The system was also used for the simultaneous detection of Zn2+, Cd2+, and Pb2+. The detection results indicate its potential application in on-site monitoring for mutiple heavy metal ions.

One-pot Synthesis of High-performance Green-emitting Carbon Dots for Cd2+ Sensing and Anti-counterfeiting Applications.

This study presents a facile one-pot solvothermal synthesis of high-performance green fluorescent carbon dots (G-CDs) using o-phenylenediamine and ethylenediamine as precursors. The G-CDs show excellent optical, temporal, and chemical stability. Notably, they exhibit the highest quantum yield of 24.2% in ethanol and a strong green emission peaking at 546 nm under 440-490 nm excitation. In addition, G-CDs have outstanding salt resistance and multi-solvent compatibility. Due to its bright photoluminescence, G-CDs can be used as a secure ink for anti-counterfeiting. More remarkably, Cd2+ ions can efficiently quench the fluorescence of G-CDs with a detection limit of 0.152 µmol/L, enabling accurate quantification of Cd2+ in water systems. The simple synthesis of high-performance G-CDs expands their applicability in sensing and bioimaging.

Efficient heavy metal ion removal by fluorographene nanochannel templated molecular sieve: a molecular dynamics simulation study.

Environmental water contamination, particularly by heavy metal ions, has emerged as a worldwide concern due to their non-biodegradable nature and propensity to accumulate in soil and living organisms, posing a significant risk to human health. Therefore, the effective removal of heavy metal ions from wastewater is of utmost importance for both public health and environmental sustainability. In this study, we propose and design a membrane consisting of fluorographene (F-GRA) nanochannels to investigate its heavy metal ion removal capacity through molecular dynamics simulation. Although many previous studies have revealed the good performance of lamellar graphene membranes for desalination, how the zero-charged graphene functionalized by fluorine atoms (fully covered by negative charges) affects the heavy metal ion removal capacity is still unknown. Our F-GRA membrane exhibits an exceptional water permeability accompanied by an ideal heavy metal ion rejection rate. The superior performance of F-GRA membrane in removing heavy metal ions can be attributed to the negative charge of the F-GRA surface, which results in electrostatic attraction to positively charged ions that facilitates the optimal ion capture. Our analysis of the potential of mean force further reveals that water molecule exhibits the lowest free energy barrier relative to ions when passing through the F-GRA channel, indicating that water transport is energetically more favorable than ion. Additional simulations of lamellar graphene membranes show that graphene membranes have higher water permeabilities compared with F-GRA membranes, while robustly compromising the heavy meal ion rejection rates, and thus F-GRA membranes show better performances. Overall, our theoretical research offers a potential design approach of F-GRA membrane for heavy metal ions removal in future industrial wastewater treatment.

Recyclable Fe3O4@UiO-66-PDA core-shell nanomaterials for extensive metal ion adsorption: Batch experiments and theoretical analysis.

With the ever-increasing challenge of heavy metal pollution, the imperative for developing highly efficient adsorbents has become apparent to remove metal ions from wastewater completely. In this study, we introduce a novel magnetic core-shell adsorbent, Fe3O4@UiO-66-PDA. It features a polydopamine (PDA) modified zirconium-based metal-organic framework (UiO-66) synthesized through a simple solvothermal method. The adsorbent boasts a unique core-shell architecture with a high specific surface area, abundant micropores, and remarkable thermal stability. The adsorption capabilities of six metal ions (Fe3+, Mn2+, Pb2+, Cu2+, Hg2+, and Cd2+) were systematically investigated, guided by the theory of hard and soft acids and bases. Among these, three representative metal ions (Fe3+, Pb2+, and Hg2+) were scrutinized in detail. The activated Fe3O4@UiO-66-PDA exhibited exceptional adsorption capacities for these metal ions, achieving impressive values of 97.99 mg/g, 121.42 mg/g, and 130.72 mg/g, respectively, at pH 5.0. Moreover, the adsorbent demonstrated efficient recovery from aqueous solution using an external magnet, maintaining robust adsorption efficiency (>80%) and stability even after six cycles. To delve deeper into the optimized adsorption of Hg2+, density functional theory (DFT) analysis was employed, revealing an adsorption energy of -2.61 eV for Hg2+. This notable adsorption capacity was primarily attributed to electron interactions and coordination effects. This study offers valuable insights into metal ion adsorption facilitated, by magnetic metal-organic framework (MOF) materials.

UV-light-responsive Ag/TiO2/PVA nanocomposite for photocatalytic degradation of Cr, Ni, Zn, and Cu heavy metal ions.

The rapid growth of industrialization has led to the uncontrolled pollution of the environment, and rapid action is needed. This study synthesized Ag/TiO2/polyvinyl alcohol (PVA) nano photocatalyst for promising light-derived photocatalytic removal of heavy metal ions. The design of experiment (DOE) was used to study the effect of important factors (pH, reaction time, and photocatalyst dosage) to maximize the final performance of the photocatalyst. In the optimized condition, the Ag/TiO2/PVA nano-photocatalyst removed more than 94% of Cr6+ in 180 min, and the efficiency was more than 70% for Cu2+, Zn2+, and Ni2+ metal ions. The adsorption of the heavy metal ions on the photocatalyst was described well with the Langmuir isotherm, while the pseudo-second-order linear kinetic model fitted with the experimental data. The nano-photocatalyst's stability was confirmed after maintaining its performance for five successive runs. The enhanced photocatalytic activity for the heavy metal ions removal can be attributed to the presence of metallic silver nanoparticles (electron transfer and plasmonic fields mechanisms) and PVA, which delayed the recombination of electron-hole. The synthesized ternary Ag/TiO2/PVA nano-photocatalyst showed promising performance for the elimination of heavy metal ions and can be used for environmental remediation purposes.

Performance and mechanism of amphiphilic polymeric chelator for enhanced removal of high concentrations of Cu(II) from wastewater.

An amphiphilic polymeric chelator (APC16-g-SX) grafted with sodium xanthate (SX) groups was successfully prepared for the efficient removal of high concentrations of Cu(II) from wastewater. The ordinary polymeric chelator (PAM-g-SX) based on linear polyacrylamide (PAM) was also prepared for comparative studies. The polymeric chelators were characterized by Fourier transform infrared spectroscopy (FT-IR), solid-state nuclear magnetic resonance (13C-NMR), gel permeation chromatography (GPC), elemental analyzer, and scanning electron microscope (SEM). The chelating performance of these polymeric chelators was investigated, and the mechanism of APC16-g-SX for enhanced removal of Cu(II) from wastewater was proposed based on fluorescence spectroscopy, cryo-scanning electron microscope (Cryo-SEM), energy-dispersive spectrometer (EDS), and X-ray photoelectron spectroscopy (XPS) tests. The results show that as the initial Cu(II) concentration in the wastewater increases, APC16-g-SX shows more excellent chelating performance than ordinary PAM-g-SX. For the wastewater with an initial Cu(II) concentration of 200 mg/L, the removal rate of Cu(II) was 99.82% and 89.34% for both 500 mg/L APC16-g-SX and PAM-g-SX, respectively. The pH of the system has a very great influence on the chelating performance of the polymeric chelators, and the increase in pH of the system helps to improve the chelating performance. The results of EDS and XPS tests also show that N, O, and S atoms in APC16-g-SX were involved in the chelation of Cu(II). The mechanism of enhanced removal of Cu(II) by APC16-g-SX can be attributed to the spatial network structure constructed by the self-association of hydrophobic groups that enhances the utilization of chelation sites.

Dual Fluorimetric Sensor for Tandem Detection of Cadmium and Cysteine: An Approach for Designing a Molecular Keypad Lock System.

A fluorimetric sensor for dual and sensitive detection of Cd2+ ion and Cysteine (based on 2-picolylamine platform) was developed.The sensor was designed and synthesized by simple condensation method and characterized by using common spectroscopic methods. The observations made from the kinetics of absorption and emission profile shows that probe Pdac behaves as ''ON-OFF'' fluorescent quenching sensor for cadmium ions. The probe exhibit selectivity in fluorescence quenching behaviour over other competitive metal ions, and also the Pdac-Cd2+ ensemble behave as an efficient ''OFF-ON'' type sensor for an essential amino acid Cysteine. Moreover, this dual sensing nature of the sensor makes it successfully applied for the designing of a molecular keypad lock system.

Enhanced sequestration of Pb2+ and Cu2+ by Artemia cyst shell supported nano-Mg composite and the potential photocatalytic performance of carbonized exhausted-adsorbent.

This study reported a new strategy for enhanced Pb2+ and Cu2+ sequestration by Artemia cyst shell (shell) supported nano-Mg from aqueous solutions and the carbonated exhausted-adsorbents sequenced potential application in photo-catalyst, which obtained two expected results. One is that the immobilization of nano-Mg onto Artemia cyst shell (shell-Mg) can greatly strengthen the adsorption effect of the neat cyst shell on Pb2+ and Cu2+. The adsorption capacities of shell-Mg for both metal ions reached to 622.01 and 313.91 mg/g, which was 10-15 and 30-50 times that of the neat shell respectively. And shell-Mg has strong selectivity, which was approximately 2-4 times that of shell. The shell-Mg can be used to retrieve Pb2+ and Cu2+ from aqueous solutions efficiently. Another is that the carbonated exhausted-adsorbents (C-shell-Mg-Pb and C-shell-Mg-Cu) showed their potential photocatalytic degradation effects on congo red under pH = 4 condition, the decolorization rate reached to 61.19% and 80.39% respectively. Reuse of exhausted adsorbents can avoid the secondary pollution caused by the regeneration, extend the utilization value of exhausted adsorbents, and provide a new viewpoint for the reuse of spent bio-nanomaterial adsorbents.

Mechanism of heavy metal ion biosorption by microalgal cells: A mathematic approach.

Microalgal biomasses have been established as promising biosorbents for biosorption to remove heavy metal ions (HMIs) from wastewaters and contaminated natural waterbodies. Understanding the mechanism is important for the development of cost-effective processes for large scale applications. In this paper, a simple mathematical model was proposed for the predication of biosorption capacity of HMI by microalgal cells based on single cell mass, cell size, and HMI radius. One fundamental assumption based on which this model was developed, i.e., the biosorption of HMI by microalgal cells is predominantly monolayer bio-adsorption, was established based on kinetic, isothermal, FTIR, and Pb(II) distribution data generated in this study and in literature. The model was validated using a combination of experimental and literature data as well, demonstrating its capability to provide reasonable estimations although with discrepancies. The biosorption capacities of HMIs (mmol/g) by Chlorella vulgaris were experimentally determined to be in the following order: Pb(II)(0.360)> Zn(II)(0.325)> Cu(II)(0.254)> Ni(II)(0.249)> Cd(II)(0.235)> Co(II)(0.182). We systematically investigated the deviations of the predicted biosorption capacities in term of the effects of a few important parameters that were unaccounted for in the model, including the nanostructures on cell surface, HMI electronegativity, and biosorption buffer pH. Results suggest that the nanostructures on cell wall, likely the hairlike fibers, might be the primary locations where the binding sites for HMI were housed. Furthermore, isothermal data, which is suported by the predictions of this model, indicate the each effective binding site on C. vulgaris cell surface could bind to more than one Co(II) in biosorption while each of the other five HMIs tested in this study required more than one binding sites.

Light-Augmented Multi-ion Interaction in MXene Membrane for Simultaneous Water Treatment and Osmotic Power Generation.

The mixing of wastewater and natural water releases abundant osmotic energy. Harvesting this energy could significantly reduce the energy and economic cost of water treatment, leading to sustainable wastewater treatment technology. Yet, such energy harvesting is highly challenging because it requires a material that is highly permeable to nontoxic ions while rejecting toxic ions in wastewater to reach high power density and prevent environmental pollution. In this work, we demonstrate that a light-augmented biomimetic multi-ion interaction in an MXene membrane can simultaneously realize high permeability of Na+ ions for enhanced osmotic power generation and high selectivity to heavy metal ions up to a ratio of 2050 for wastewater treatment. The Na+ permeability is enhanced by the photothermal effect of the MXene membrane. The transport of heavy metal ions, however, is suppressed because, under angstrom-confinement, heavy metal ions are strongly electrostatically repelled by the increased number of permeating Na+ ions. As a result, the membrane can stably generate osmotic power from simulated industrial wastewater, and the power density can be enhanced by 4 times under light illumination of approximate 1 sun intensity. This work highlights the importance of multi-ion interaction for the transport properties of ionic materials, which remains rarely investigated and poorly understood in previous studies.