Water dispersible carbon nanomaterials reduced N, P, and K leaching potential in sandy soils: A column leaching study.

Carbon nanomaterials (CNMs) - amendments with carbon in nanoscale form -could potentially enhance fertilizer delivery efficiency in agriculture, but their interaction with soil properties and nutrient co-mobility, especially in coarse-textured soils, remain poorly understood. We conducted a column leaching study in repacked soil columns to compare the co-leaching of novel water-dispersible CNMs and soil nutrients across two levels of CNMs applications (200 & 400 mg kg-1), two fertilization rates (low:80 mg kg-1 of N, P and K and high: 200 mg N kg-1, 100 mg P kg-1, 200 mg K kg-1, applied as ammonium nitrate, potassium phosphate, and potassium nitrate) and two soils (Spodosol with pH = 5.1, Alfisol with pH = 6.5). We imposed 12 leaching events to each column, with each leaching event adding water equivalent to the soil-pore volume (250 mL), resulting in cumulative leaching of 3000 mL of water through each column. CNMs applications reduced cumulative leaching losses of NO3-N (Spodosol: 8-12 %, Alfisol: 9-19 %), NH4-N (Spodosol: 2-14 %, Alfisol: 9-14 %), P (Spodosol: 23-27 %, Alfisol: 23-36 %) and K (Spodosol: 17-23 %, Alfisol: 24-26 %) compared to fertilized columns without CNMs. CNMs increased soil pH by up to 0.3 units (Spodosol) or 0.5 units (Alfisol), while lowering electrical conductivity by 15-20 % at the high fertilization rate in both soils. Columns with water-dispersible CNMs accumulated 25-30 % more total C in the base sections of the Alfisol compared to the Spodosol, indicating faster downward movement through the soil profile. Overall, we demonstrated that CNMs have the potential to reduce nutrient leaching in coarse-textured soils, which could be particularly beneficial in high-input intensive agricultural systems.

Reducing Phosphorus Loss in Short-Cycle Horticultural Production Using Activated Aluminum-Amended Substrates and Modified Fertigation Practices.

To support growth, short-cycle horticultural crops require readily available nutrients. However, this often leads to nutrient leaching. Implementing best management practices in production decisions like incorporating fertilizer retaining amendments to substrates or modifying fertilization programs can mitigate nutrient losses to the environment and associated costs. This study examined using an activated aluminum (AA) material as a substrate amendment to retain phosphorus (P) within containers while also assessing methods to reduce P fertilization in Tagetes production over a six-week production cycle. A commercial peat moss substrate (PL) pre-loaded with nutrients was amended with AA, enabling comparisons between substrates with and without AA. Enhanced fertilizer practices involved supplementing the initial nutrients by applying a weekly fertigation solution including nitrogen and potassium over the six weeks, but P for either 0, 2, 4, or 6 weeks. The incorporation of AA significantly reduced P leaching losses by 89.5-97.7%, compared to the PL substrates receiving P the entire six weeks. Regardless of substrate or fertilizer management, all Tagetes had equivalent sizes (growth index) and aboveground biomass. The results indicate that amending substrates with AA and/or reducing additional P inputs are effective strategies to minimize P leaching without compromising Tagetes quality.

Dataset from an investigation of the effect of natural zeolite particle size reduction as a material for the manufacture of slow-release potassium fertilizer in oil palm seedlings growth with peat soil planting media.

Particle size is one-factor influencing zeolite's ion exchange properties. This study used natural zeolite with a particle size of ±0.147 mm and ±500 nm as a carrier for K-zeolite-based fertilizer. K in the zeolite-based fertilizer was expected to be released slowly and more effectively in supplying K for oil palm seedlings on peat soil media compared to conventional K fertilizer (Muriate of Potash, or MoP). The study was arranged using a completely randomized design (CRD) with eight treatments and three replications. The treatments tested were: (1) control/no fertilization; (2) MoP fertilizer; (3) fine-polite-fertilizer formula-1 (FPF-1); (4) fine-polite-fertilizer formula-2 (FPF-2); (5) fine-polite-fertilizer formula-3 (NPF-3); (6) micro-polite-fertilizer formula-1 (MPF-1); (7) micro-polite-fertilizer formula-2 (MPF-2); and (8) micro-polite-fertilizer formula-3 (MPF-3). K zeolite-based fertilizers generally had better effectiveness than MoP, where formula 2 (50 % zeolite: 50 % MoP fertilizer) was the best among the three K zeolite-based fertilizer formulas. There were no significantly different effects of zeolite with a particle size of ±500 nm and ±0.147 mm on the growth and K uptake of oil palm seedlings and the amount of leached K from the peat soil. This data set could be helpful for researchers who want to develop an environmentally friendly fertilizer to implement sustainable agriculture.

Manipulating geological phosphorus resources for improved production and environmental outcomes during plant establishment.

Phosphorus (P) fertilisers are under scrutiny due to resource constraints and environmental impacts. Simple rock phosphate (RP) modifications with acids and co-applied with microbial inoculum could offer sustainable alternative P fertiliser products. We evaluated the effects of acid-treated rock phosphate (RP) in combination with fungal inoculum on plant establishment, environmental impacts (nutrient leaching) and soil quality in a 5-month pot trial. The treatments were evaluated in a clayey Vertisol and a silty Acrisol using cotton (Gossypium hirsutum) as a model plant. The RP treatments - apart from the unmodified and HCl products - were effective in promoting plant establishment with two of the microbial formulations superior to conventional P fertilisers by an average factor of 2 in both soil types (p < 0.05). All RP products restricted P leaching compared with conventional P fertilisers (p < 0.05), by an average factor of 5 for diammonium phosphate (DAP) in both soil types and 3 for the triple superphosphate TSP (only in Acrisol). Nitrate leaching from all treatments was high although much lower from the RP treatments compared with the conventional fertilisers towards the end of the establishment trial, by an average factor of 1.5 (p < 0.05). Ranking analysis revealed that some RP treatments showed evidence for improved ongoing soil quality, including decreased P leaching and soil acidification risks. Microbial analysis showed complex interactions between treatment and soil type. Nonetheless, inoculum persistence at the end of the plant establishment phase was observed for all pots analysed. Our results demonstrate that relatively simple modifications to RP could pave the way for developing sustainable P fertilisers.

Addition of softwood biochar did not reduce N2O emissions or N leaching from peat soil in the short term.

Drained agricultural peat soils pollute both the atmosphere and watercourses. Biochar has been observed to decrease greenhouse gas (GHG) emissions and nutrient loading in mineral soils. We studied effects of three biochar types with two application rates (10 and 30 Mg ha-1) on GHG fluxes as well as N and P leaching on peat soil. Peat monoliths were drilled from a long-term cultivated field and were watered either slightly (five dry periods) or heavily (four rainfall periods) during an 11-month laboratory experiment with intact peat columns. The incubation of bare peat profiles enhanced peat decomposition leading to high CO2 (up to 1300 mg CO2 m-2 h-1) and N2O emissions (even 10,000-50,000 µg N2O m-2 h-1) and NO3--N leaching (even 300-700 mg L-1) in all treatments. In the beginning of the experiment, the lower application rate of pine bark biochars increased N2O emission compared to control, but otherwise none of the biochars or their application rates significantly affected gas fluxes or nutrient leaching. These results indicate that moderate softwood biochar application does not help to mitigate the environmental problems of agricultural peat soils. Higher application rate of biochar pyrolyzed at high temperature is recommended for further studies with peat soils.

Nutrient transport, shear strength and hydraulic characteristics of topsoils amended with mulch, compost and biosolids.

Anthropogenic disturbance of soils can disrupt soil structure, diminish fertility, alter soil chemical properties, and cause erosion. Current remediation practices involve amending degraded urban topsoils lacking in organic matter and nutrition with organic amendments (OA) to enhance vegetative growth. However, the impact of OAs on water quality and structural properties at rates that meet common topsoil organic matter specifications need to be studied and understood. This study tested three commonly available OAs: shredded wood mulch, leaf-based compost, and class A Exceptional Quality stabilized sewage sludge (or biosolids) for nutrient (nitrogen and phosphorus) water quality, soil shear strength, and hydraulic properties, through two greenhouse tub studies. Findings showed that nitrogen losses to leachate were greater in the biosolids amended topsoils compared to leaf-compost, mulch amended topsoils, and control treatments. Steady-state mean total nitrogen (N) concentrations from biosolids treatment exceeded typical highway stormwater concentrations by at least 25 times. Soil total N content combined with the carbon:nitrogen ratio were identified to be the governing properties of N leaching in soils. Study soils, irrespective of the type of amendment, reduced the applied (tap) water phosphorus (P) concentration of ∼0.3 mg-P/L throughout the experiment. Contrary to the effects on N leaching, P was successfully retained by the biosolids amendment, due to the presence of greater active iron contents. A breakthrough mechanism for P was observed in leaf compost amended soil, where the effluent concentrations of P continued to increase with each rainfall application, possibly due to an saturation of soil adsorption sites. The addition of OAs also improved the strength and hydraulic properties of soils. The effective interlocking mechanisms between the soil and OA surfaces could provide soil its required strength and stability, particularly on slopes. OAs also improved soil fertility to promote turf growth. Presence of vegetative root zones can further reinforce the soil and control erosion.

[Effects of Microplastics on the Leaching of Nutrients and Cadmium from Soil].

The environmental effects of microplastics, which are considered a type of emerging contaminants, have attracted increasing concern due to their small size, large specific surface area, strong adsorption capacity, and low degradability. Microplastics can change soil properties and affect the migration ability of nutrients and pollutants in soil, but their effects on the leaching of soil nutrients and heavy metals have not been sufficiently studied. A soil column leaching experiment was conducted to explore the effects of polystyrene (PS) and polylactic acid (PLA) microplastics at different mass fractions (0%, 0.2%, and 2%) on the leaching of nutrients and cadmium under simulated rainfall scenarios. The results showed that increasing rainfall intensity enhanced the leaching of nutrients and cadmium from soil. During downpour conditions, 2% PS significantly increased the leaching of total nitrogen and the content of available phosphorus in soil and reduced the leaching of inorganic phosphorus and the content of ammonium nitrogen in the soil, whereas it increased the content of available potassium during heavy rain. By comparison, 2% PLA reduced the leaching of nitrate nitrogen during heavy rain and intense rainfall and decreased the content of ammonium nitrogen in soil during intense rainfall and downpour conditions and the content of total nitrogen in soil during downpours. In addition, 0.2% PLA significantly increased cadmium leaching during downpours. To conclude, the effects of microplastics on the leaching of nutrients and cadmium were dependent on the type and concentration of microplastics, as well as the rainfall level. Our findings showed that the microplastics derived from both nondegradable PS and biodegradable PLA could affect the leaching of nutrients and heavy metals from soil.

Effects of Microplastics on the Transport of Soil Dissolved Organic Matter in the Loess Plateau of China.

Microplastics (MPs) pollution and dissolved organic matter (DOM) affect soil quality and functions. However, the effect of MPs on DOM and underlying mechanisms have not been clarified, which poses a challenge to maintaining soil health. Under environmentally relevant conditions, we evaluated the major role of polypropylene particles at four micron-level sizes (20, 200, and 500 µm and mixed) in regulating changes in soil DOM content. We found that an increase in soil aeration by medium and high-intensity (>0.5%) MPs may reduce NH4+ leaching by accelerating soil nitrification. However, MPs have a positive effect on soil nutrient retention through the adsorption of PO43- (13.30-34.46%) and NH4+ (9.03-19.65%) and their leached dissolved organic carbon (MP-leached dissolved organic carbon, MP-DOC), thereby maintaining the dynamic balance of soil nutrients. The regulating ion (Ca2+) is also an important competitor in the MP-DOM adsorption system, and changes in its intensity are dynamically involved in the adsorption process. These findings can help predict the response of soil processes, especially nutrient cycling, to persistent anthropogenic stressors, improve risk management policies on MPs, and facilitate the protection of soil health and function, especially in future agricultural contexts.

The role of agricultural drainage, storm-events, and natural filtration on the biogeochemical cycling capacity of aquatic and sediment environments in Lake Erie's drainage basin.

Lake Erie is the most at risk of the Great Lakes for degraded water quality due to non-point source pollution caused by agricultural activities in the lake's watershed. The extent and temporal patterns of nutrient loading from these agricultural activities is influenced by the timing of agronomic events, precipitation events, and water flow through areas of natural filtration within the watershed. Downstream impacts of these nutrient loading events may be moderated by the co-loading of functionally relevant biogeochemical cycling microbial communities from agricultural soils. This study quantified loading patterns of these communities from tile drain sources, assessed whether functional communities from agricultural sources influenced downstream microbial functionality, and investigated how distance from agricultural sources, storm events, and areas of natural filtration altered nutrient cycling and nutrient fluxes in aquatic and sediment environments. Water and sediment samples were collected in the Wigle Creek watershed in Ontario, from tile drains through to Lake Erie, from May to November 2021, and microbial nitrogen (N) and phosphorous (P) cycling capacity (quantitative PCR), and nutrient levels were evaluated. Results showed that N and P functional groups were co-loaded with nutrients, with increased loading occurring during storm events and during agricultural activities including fertilization and harvest. Overall functional capacity in the aquatic environment decreased with distance from the agricultural sources and as water transited through natural filtration areas. In contrast, the sediment environment was more resilient to both agricultural disturbances and abiotic factors. This study expands our understanding of when and where different stages of N and P cycling occurs in agriculturally impacted watersheds, and identifies both seasons and regions to target with nutrient mitigation strategies.

Simplification of soil biota communities impairs nutrient recycling and enhances above- and belowground nitrogen losses.

Agriculture is a major source of nutrient pollution, posing a threat to the earth system functioning. Factors determining the nutrient use efficiency of plant-soil systems need to be identified to develop strategies to reduce nutrient losses while ensuring crop productivity. The potential of soil biota to tighten nutrient cycles by improving plant nutrition and reducing soil nutrient losses is still poorly understood. We manipulated soil biota communities in outdoor lysimeters, planted maize, continuously collected leachates, and measured N2 O- and N2 -gas emissions after a fertilization pulse to test whether differences in soil biota communities affected nutrient recycling and N losses. Lysimeters with strongly simplified soil biota communities showed reduced crop N (-20%) and P (-58%) uptake, strongly increased N leaching losses (+65%), and gaseous emissions (+97%) of N2 O and N2 . Soil metagenomic analyses revealed differences in the abundance of genes responsible for nutrient uptake, nitrate reduction, and denitrification that helped explain the observed nutrient losses. Soil biota are major drivers of nutrient cycling and reductions in the diversity or abundance of certain groups (e.g. through land-use intensification) can disrupt nutrient cycling, reduce agricultural productivity and nutrient use efficiency, and exacerbate environmental pollution and global warming.

Experimental analysis to assess the hydrological efficiency and the nutrient leaching behavior of a new green wall system.

Green Walls represent a sustainable solution to mitigate the effects due to climate change and urbanization. However, although they have been widely investigated in different fields of science, studies on the potential of these systems to manage urban stormwater are still few. Moreover, even if these systems provide multiple benefits, as other nature-based solutions, they leach nutrients due to growing media, decomposed vegetation, and the possibility of fertilizer use. In this regard, several studies have evaluated the nutrient concentrations in the runoff from green roofs, while studies that have analyzed the nutrient-leaching behavior of green walls are still limited. To bridge these scientific gaps, this study presents experimental findings on the hydrological efficiency and nutrient-leaching behavior of an innovative modular living wall system. Some rainfall-runoff tests were carried out to assess the hydrological response of a new green wall system in retaining stormwater. To evaluate the concentration of the nutrients, the collected outflow was analyzed by spectrophotometer UV-visible. The findings show that the developed green wall panel presents good retention capacity by considering different simulated rainfalls and varying the initial soil moisture conditions. The results in terms of nutrient concentrations highlight that the vegetation life cycle and the fertilizer uses affect the quality of the water released from the green wall panel. The concentration of the analyzed nutrients is influenced by the simulated rainfall's hydrological characteristics and the days between the planting phase and the test. However, the overall results show that the concentrations of each analyzed nutrient are low, except after the fertilizer use, highlighting that the choice of vegetation that does not need external nutrients should be preferred during the design of a green wall.

Enhancing cation and anion exchange capacity of rice straw biochar by chemical modification for increased plant nutrient retention.

Biochar, a potential alternative of infield crop residue burning, can prevent nutrient leaching from soil and augment soil fertility. However, pristine biochar contains low cation (CEC) and anion (AEC) exchange capacity. This study developed fourteen engineered biochar by treating a rice straw biochar (RBC-W) first separately with different CEC and AEC enhancing chemicals, and then with their combined treatments to increase CEC and AEC in the novel biochar composites. Following a screening experiment, promising engineered biochar, namely RBC-W treated with O3-HCl-FeCl3 (RBC-O-Cl), H2SO4-HNO3-HCl-FeCl3 (RBC-A-Cl), and NaOH-Fe(NO3)3(RBC-OH-Fe), underwent physicochemical characterization and soil leaching-cum nutrient retention studies. RBC-O-Cl, RBC-A-Cl, and RBC-OH-Fe recorded a spectacular rise in CEC and AEC over RBC-W. All the engineered biochar remarkably reduced the leaching of NH4+-N, NO3- -N, PO43--P and K+ from a sandy loam soil and increased retention of these nutrients. RBC-O-Cl at 4.46 g kg-1 dosage emerged as the most effective soil amendment increasing the retention of above ions by 33.7, 27.8, 15.0, and 5.74 % over a comparable dose of RBC-W. The engineered biochar could thus enhance plants' nutrient use efficiency and reduce the use of costly chemical fertilizers that are harmful to environmental quality.

Microplastics change the leaching of nitrogen and potassium in Mollisols.

Nowadays, the dynamics of nutrients leaching from the soils and their driving mechanism have been focused on, however, it is still unclear how microplastics (MPs) influence the nutrients' leaching in soils. In this study, five concentrations (w/w, 0.0 %, 0.5 %, 1 %, 2 %, 3 %) and three sizes of MPs of polyethylene (PE) (0.15-0.36 mm, 0.36-0.60 mm and 0.60-1.00 mm) influencing the leaching of NO3--N and water-soluble potassium (WSK) was simulated by a column method in Mollisols, and both the pre-fertilization and post-fertilization were considered. The results showed that, before KNO3 addition, there was a negative power function relationship between the NO3--N concentration and the leaching solution volume/leaching time. The amount and concentration of NO3--N leaching was higher in the early leaching stage. Compared with the CK, PE0.5% significantly reduced the leaching amount of WSK, while increased the leaching amount of NO3--N but not significantly. The leaching amount of WSK decreased with the increasing size of PEMP when the PEMP concentration was the same, while NO3--N was opposite. PE0.60-1.00 increased the leaching amount of NO3--N, while reduced the leaching amount of WSK. After KNO3 addition, compared with CK, PE1% significantly reduced the leaching amount of NO3--N, and PE1% had the lowest leaching amount of WSK. However, when the PEMP concentration in the soil reached a certain threshold (w/w, >1 %), the leaching amount of NO3--N and WSK increased gradually with PEMP increasing. PE0.60-1.00 reduced the leaching amount of NO3--N and WSK most obviously. In general, low concentrations (w/w, <1 %) and large sizes (0.60-1.00 mm) of PEMP promoted NO3--N leaching and inhibited the WSK leaching from the soil before the addition of KNO3, however, they both inhibited the leaching of NO3--N and WSK from the soil after addition of KNO3.

Recycling eutrophic lake sediments into grass production: A four-year field experiment on agronomical and environmental implications.

Inefficient use of phosphorus (P) fertilizers leads to the transfer of P into water bodies, causing their eutrophication. Sediment removal is a promising lake restoration strategy that removes nutrients including P accumulated in lake sediments, and opens the opportunity to use removed nutrients in agriculture. In the present study, we investigated the effects of using a thick layer of sediment from the eutrophic Lake Mustijärv on plant growth, and estimated the environmental impacts of different sediment application methods by analyzing greenhouse gas emissions, N and P leaching, aggregate stability, and soil biota. The field experiment (2017-2020) was established on the lake shore with the following treatments: the agricultural control soil (Soil) surrounding the lake, pure sediment (Sed), biochar-treated sediment (SB), and biochar and soil mixed with sediment (SSB). The sediment-based treatments resulted in a similar grass growth performance to the Soil. The availability of most macro- and micronutrients including P (75 vs. 21 g m-3) were far greater in the Sed compared to the Soil. The sediment-based growing media emitted more CO2 than the Soil (579 vs. 400 mg CO2 - C m-2 h-1) presumably due to the high rate of organic matter decomposition. The bacterial and fungal community structures of the Sed were strongly differentiated from those of Soil. Also, Sed had lower bacterial diversity and a higher abundance of the bacterial phyla associated with solubilizing P including Proteobacteria and Chloroflexi. Sediment-based growing media increased more than seven times the risk of mineral N and P leaching, and the biochar treatment only had a short-lived beneficial effect on reduction of the sediment's leached P concentration. The sediment application rate should be adjusted to match the crop requirements to minimize greenhouse gas emissions and nutrient leaching when upscaling the case study to larger lakes with similar sediment properties.

Effects of digestate-encapsulated biochar on plant growth, soil microbiome and nitrogen leaching.

The increasing amount of food waste and the excessive use of mineral fertilizers have caused detrimental impacts on soil, water, and air quality. Though digestate derived from food waste has been reported to partially replace fertilizer, its efficiency requires further improvement. In this study, the effects of digestate-encapsulated biochar were comprehensively investigated based on growth of an ornamental plant, soil characteristics, nutrient leaching and soil microbiome. Results showed that except for biochar, the tested fertilizers and soil additives, i.e., digestate, compost, commercial fertilizer, digestate-encapsulated biochar had positive effects on plants. Especially, the digestate-encapsulated biochar had the best effectiveness as evidenced by 9-25% increase in chlorophyll content index, fresh weight, leaf area and blossom frequency. For the effects of fertilizers or soil additives on soil characteristics and nutrient retention, the digestate-encapsulated biochar leached least N-nutrients (<8%), while the compost, digestate and mineral fertilizer leached up to 25% N-nutrients. All the treatments had minimal effects on the soil properties of pH and electrical conductivity. According to the microbial analysis, the digestate-encapsulated biochar has the comparable role with compost in improving the soil immune system against pathogen infection. The metagenomics coupling with qPCR analysis suggested that digestate-encapsulated biochar boosted the nitrification process and inhibited the denitrification process. This study provides an extensive understanding into the impacts of the digestate-encapsulated biochar on an ornamental plant and offers practical implications for the choice of sustainable fertilizers or soil additives and food-waste digestate management.

Interspecific variations in leaf litter decomposition and nutrient release from tropical mangroves.

Efficient nutrient cycling through decomposition of leaf litter often regulates the high productivity and subsequent carbon sequestration of mangrove ecosystems along the land-ocean boundary. To understand the characteristics and the potentials of mangrove leaf litter in supplying organic carbon and nutrients to the coastal waters, four major mangrove species (A. officinalis, R. mucronata, H. littoralis and S. apetala) of Bhitarkanika mangrove forest, Odisha, India, were examined in controlled environmental conditions. Half-life time (t0.5), estimated for decomposition of those mangrove leaf litter materials ranged from 18 to 52 days. During the incubation experiment, organic carbon from mangrove leaf litter was released primarily through physical processes and was available for heterotrophic respiration. Among the four species, leaf litter of S. apetala with the lowest initial C/N ratios, released organic carbon with low molecular weight (labile substances) that has a relatively higher potential to support the aquatic food web. On the contrary, leaf litter of R. mucronata released organic material with relatively higher molecular weight (humic substances, higher aromaticity), which revealed its superior non-labile characteristics in this unique environment. The mean total heterotrophic bacterial (THB) population in the incubation was around nine-fold higher than the control. THB population growth and Chromophoric Dissolved Organic Matter (CDOM) spectral data further suggested the rapid release of highly labile and recalcitrant carbon from S. apetala and R. mucronata (between 7th and 21st day of incubation), respectively. The mean litter fall from the Bhitarkanika mangrove forest was estimated to be 11.32 ± 1.57 Mg ha-1 y-1 and its corresponding carbon content was 5.43 ± 0.75 Mg C ha-1. The study revealed the role of leaf litter leachates as an important food source to microbial communities in the adjacent coastal waters, in addition to a potential carbon sequesterer through long-term burial in mangrove soil and export to the deep sea.

Impacts of soil, climate, and phenology on retention of dissolved agricultural nutrients by permanent-cover buffers.

Nutrient losses from farms affects environmental and human health, but retention by riparian buffers can vary by nutrient identity, flow path, soil texture, seasonality, and buffer width. On conventional farms with corn, we test the relationships between levels of dissolved nitrogen (N) and phosphorus (P) in downslope surface-water, and flow paths relating to porewater in soils (to 40 cm deep), groundwater of the saturated zone (to 2.5 m deep), soil nutrient pools, and changes in plant biomass and tissue quality by season. We found that the major drivers of surface-water nutrients were multi-factor and nutrient-specific, variously relating to soil, climate, vegetation uptake, and tiling on clay soils. N retention was best explained by soil type, with 10 times more surface-water N in the sand versus clay setting, despite identical fertilization rates on corn. P retention was best explained by precipitation and time of year. Vegetation uptake was strongest for shallow-soil porewater, and was greatest in buffers where root biomass was 20 times greater by weight. We were unable to detect any impact of vegetative uptake on groundwater nutrients. Overall, peak nutrient inputs to surface-water were in early summer, fall, and winter - all times when plant uptake is low. Buffers appear to be a necessary component of nutrient capture on farms, but insufficient unless partnered with measures that reduce nutrient flows at times when plants are inactive.

Synthesizing biochar-based slow-releasing fertilizers using vermicompost leachate, cow dung, and plant weed biomass.

Biochar-based slow-releasing fertilizers (BSRF) have been recommended widely for efficient soil nutrient management and crop production. In this study, we examined the N, P, and K release behaviour of pyrolysed (at 350 °C) cow dung (CDB), vermicompost (VCB), and Lantana (LB) weed and impregnated LB (LBVW) and CDB (CDBVW) with vermicompost leachate (1:1 v/v) under a lab-scale trial. BSRFs (CDB, VCB, LBVW and VCBVW) characterization (FT-IR, SEM-EDX and surface area analysis) was done and then tested for its suitability for soil-plant applications. Soil incubation study indicated the slow-releasing behaviour of BSRFs and overall P, N, and K release was found to be in the ranges of 72.3-84.5%, 73.1-79.0%, and 43.1-85.3%, respectively in different BSRFs setups. Furthermore, lab trials suggested the highest P (64.5%), N (75.3%), and K (86.8%) uptakes by the plant (Vigna radiata) in CDBVW and LBVW setups. Moreover, pot trails with moong bean (Vigna radiata) suggested a high growth in shoot and root and plant yield as well in seedlings cultivated with BSRFs. This study indicates that animal manure, vermicompost and terrestrial weed Lantana biochar can be used effectively to prepare BSRFs for efficient soil-plant nutrient management with multiple environmental benefits.

Co-composting of digestate and garden waste with biochar: effect on greenhouse gas production and fertilizer value of the matured compost.

Biogas digestate is a nitrogen (N) rich waste product that has potential for application to soil as a fertilizer. Composting of digestate is recognized as an effective step to reduce potentially negative consequences of digestate application to soils. However, the structure of the digestate and the high N content can hinder effective composting. Biochar, which can be produced through the pyrolysis of waste biomass, has shown the potential to improve compost structure and increase N retention in soils. We studied how a high-temperature wood biochar affects the composting process, including greenhouse gas emissions, and the fertilizer value of the compost product including nutrient content, leachability and plant growth. The high Biochar dose (17% w/w) had a significantly positive effect on the maximum temperature (5°C increase vs. no biochar) and appeared to improve temperature stability during composting with less variability between replicates. Biochar addition reduced cumulative N2O emission by 65-70%, but had no significant effect on CO2 and CH4 emission. Biochar did not contribute to greater retention of nitrogen (N) contained in the digestate, but had a dilution effect on both N content and mineral nutrients. Fertilization with compost enhanced plant growth and nutrient retention in soil compared to mineral fertilization (NPK), but biochar had no additional effects on these parameters. Our results show that biochar improves the composting of digestate with no subsequent negative effects on plants.

Dataset about the adoption of winter cover crops at the municipality level for mainland France.

Winter soil cover by vegetation is associated with multiple benefits, such as increasing soil carbon storage and reducing erosion and nutrient leaching. This dataset provides an estimate of winter soil cover before spring-sown crops at municipality level for mainland France for two years (2018 and 2019). These estimates were obtained through the monitoring of all plots with spring-sown crops, declared within the context of the European Common Agricultural Policy. Detection of plots with winter soil cover was achieved through the analysis of Normalized Difference Vegetation Index (NDVI) time series, computed from Sentinel-2 multispectral images. For this dataset, it was considered that soil cover had to exceed 50% for a plot to be considered as covered by vegetation. Based on the literature, this corresponds to a threshold NDVI value between 0.45 and 0.59. To allow for sensitivity and uncertainty analyses for future studies that may be conducted using these data, three estimates of winter soil cover are given: minimum (based on the cultivated area exceeding the upper NDVI threshold of 0.59), maximum (considering the lower NDVI threshold of 0.45) and best estimate (mean NDVI threshold of 0.52). This dataset may be useful primarily to researchers working on biogeochemical cycle modeling or to government agencies, as several public policies (such as the Nitrates Directive) aim at developing winter cover crops.