Effects of near-bed turbulence on microplastics fate and transport in streams.

Quantifying the impact of hyporheic exchange is crucial for understanding the transport and fate of microplastics in streams. In this study, we conducted several Computational Fluid Dynamics (CFD) simulations to investigate near-bed turbulence and analyze vertical hyporheic exchange. Different arranged spheres were used to represent rough and permeable sediment beds in natural rivers. The velocities associated with vertical hyporheic flux and the gravitational force were compared to quantify the susceptibility of microplastics to hyporheic exchange. Four scenario cases representing different channel characteristics were studied and their effects on microplastics movements through hyporheic exchange were quantitatively studied. Results show that hyporheic exchange flow can significantly influence the fate and transport of microplastics of small and light-weighted microplastics. Under certain conditions, hyporheic exchange flow can dominate the behavior of microplastics with sizes up to around 800 µm. This dominance is particularly evident near the sediment-water interface, especially at the top layer of sediments. Higher bed porosity enhances the exchange of microplastics between water and sediment, while increased flow conditions extend the vertical exchange zone into deeper layers of the bed. Changes in the bedform lead to the most pronounced vertical hyporheic exchange, emphasizing the control of morphological features on microplastics transport. Furthermore, it is found that sweep-ejection events are prevailing near the bed surface, serving as a mechanism for microplastics transport in rivers. As moving from the water column to deeper layers in the sediment bed, there's a shift from sweeps dominance to ejections dominance, indicating changes of direction in microplastics movement at different locations.

Combined use of high-resolution dialysis, diffusive gradient in thin films (DGT) technique, and conventional methods to assess trace metals in reservoir sediments.

Recently, reservoirs in southern China are witnessing incidents involving black water, which are harmful to the aquatic ecosystem. This study unravels the cause of the black water events by studying the occurrence and the ecological risks of contaminants (Pb, Cu, Cd, Zn, Ni, TFe, Mn, S, P, and DOC) in sediments of Tianbao reservoir. Due to the significantly high concentration of TFe, Mn, and P in the sediments, the study further used the thin film diffusion gradient (DGT) technology and high-resolution dialysis method to investigate the movement of Fe2+, Mn2+, S2-, and reactive P within the sediments. The ecological risk assessment (threshold effect level and probable effect level) showed that the sediments had a low concentration of Pb, Cu, Cd, Zn, and Ni. High organic matter from the Eucalyptus plantation surrounding the reservoir, as well as the intense thermal stratification of the reservoir, caused the hypolimnion to be hypoxic (DO < 2 mg/L). The diffusion fluxes at the water-sediment boundary (WSB) demonstrated a significant movement of Fe2+, Mn2+, and PO43- from the sediments into the overlying water, while the movement of S2- was in both directions due to hypoxia. A high correlation Fe-DOC (r = 0.9), Fe-S (r = 0.8), and Mn-S (r = 0.7) and the redox interaction of Fe2+, Mn2+, S2-, P, and DOC at the hypoxic WSB caused the production of black substances in the hypolimnion contributing to the so-called black water reservoir.

Uranium storage mechanisms in wet-dry redox cycled sediments.

Biogeochemical redox processes that govern radionuclide mobility in sediments are highly sensitive to forcing by the water cycle. For example, episodic draining and intrusion of oxidants into reduced zones during dry seasons can create biogeochemical seasonal hotspots of enhanced and changed microbial activity, affect the redox status of minerals, initiate changes in sediment gas and water transport, and stimulate the release of organic carbon, iron, and sulfur by oxidation of solid reduced species to aqueous oxic species. In the Upper Colorado River Basin, water-saturation of organic-enriched sediments locally promotes reducing conditions, denoted 'Naturally Reduced Zones' (NRZs), that accumulate strongly U(IV)sol. Subsequently, fluctuating hydrological conditions introduce oxidants, which may reach internal portions of these sediments and reverse their role to become secondary sources of Uaq. Knowledge of the impact of hydrological variability on the alternating import and export of contaminants, including U, is required to predict contaminant mobility and short- and long-term impacts on water quality. In this study, we tracked U, Fe, and S oxidation states and speciation to characterize the variability in redox processes and related Usol solubility within shallow fine-grained NRZs at the legacy U ore processing site at Shiprock, NM. Previous studies have reported U speciation and behavior in permanently saturated fine-grained NRZ sediments. This is the first report of U behavior in fine-grained NRZ-like sediments that experience repeated redox cycling due to seasonal fluctuations in moisture content. Our results support previous observations that reducing conditions are needed to accumulate Usol in sediments, but they counter the expectation that Usol predominantly accumulates as U(IV)sol; our data reveal that Usol may accumulate as U(VI)sol in roughly equal proportion to U(IV)sol. Surprisingly high abundances of U(VI)sol confined in transiently saturated fine-grained NRZ-like sediments suggest that redox cycling is needed to promote its accumulation. We propose a new process model, where redox oscillations driven by annual water table fluctuations, accompanied by strong evapotranspiration in low-permeability sediments, promote conversion of U(IV)sol to relatively immobile U(VI)sol, which suggests that Usol is accumulating in a form that is resistant to redox perturbations. This observation contradicts the common idea that U(IV)sol accumulated in reducing conditions is systematically re-oxidized, solubilized and transported away in groundwater.

Residue levels and spatial distribution of phthalate acid esters in water and sediment from urban lakes of Guangzhou, China.

The residue levels and composition profiles of phthalate acid esters (PAEs) in water and sediment samples were investigated in eight urban lakes of Guangzhou, China. A total of 23 water and 16 sediment samples were collected. Results showed that all target PAEs were detected with dimethyl phthalate and di(2-ethylhexyl) phthalate as the most abundant compounds. The total concentrations of PAEs from different urban lakes were in the range of 273-1173 ng/L for water and 16.5-242 ng/g for sediments, with the geometric mean of 515 ng/L and 75.0 ng/g, respectively. Zhongshan Park Lake and Liwan Lake were the most highly contaminated with PAEs in water and in sediment, respectively. The spatial distribution of PAEs exhibited that distribution coefficients of PAEs between sediment and water are consistent with hydrophilicity of PAEs, and pollution levels and characteristics of PAEs in different lakes had a close relationship with the geographical location of the lake, industrial and commercial types, population density, and the association between the lake and the Pearl River. According to Pearson correlation analysis, PAEs would be derived from similar or identical sources. Risk assessment suggested that the exposure of PAEs in Guangzhou has a moderate toxicity at the current level.

Difference in attenuation among Mn, As, and Fe in riverbed sediments.

We report, for the first time, a detailed study at river water and hyporheic zone systems through collection and analyses of shallow sediments and selected source rocks, pore water, and river water from forty-two locations at the Chianan Plain (CP), SW Taiwan. The study was focused to understand the possible changes in the river water and sediment chemistry as a consequence of high arsenic (mean±SD=71.28±16.24µg/L, n=46) groundwater discharge to three major rivers in the plain. The study shows, except few locations, As concentration in river sediments corresponds to average As concentration in soil and upper crustal abundance and of source rock. Sequential extraction indicates that As is mostly bound to FeOOH. No enrichment of arsenic in river sediments or depletion of aqueous As and iron in pore water was observed down to the maximum sampling depth of 1.7m although manganese is enriched in sediments. Dissolved As concentrations in the river sediments are much lower compared to the hotspots in the CP aquifers. This suggests that no As attenuation processes are active or they cannot be detected in this zone. Mn precipitates at higher redox level compared to Fe and As and thus attenuates in the studied zone.

Occurrence and behavior of antibiotics in water and sediments from the Huangpu River, Shanghai, China.

This study aims to determine the occurrence and behavior of five classes of 20 antibiotics in both water and sedimentary phases in the Huangpu River, which supplies drinking water to Shanghai City, China. Of the 20 antibiotics, sulfonamides showed the highest concentrations in water samples (34-859 ng L(-1)) while tetracyclines (average concentration at 18 µg kg(-1) dry weight) and macrolides (12 µg kg(-1) dry weight) dominated in sediment samples. The spatial distribution of antibiotics showed that the main polluting sources into the river were animal farming sites and the tributaries downstream of the Yuanxie River. In addition, linear relationships between logKoc and logKow, and between logKoc and log molecular weight, were demonstrated, suggesting the importance of contaminant properties in inter-phase behavior. The environmental risk assessment revealed that some antibiotics, in particular sulfamethoxazole could cause medium damage to daphnid in the aquatic ecosystem.