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1.
Polymers (Basel) ; 16(14)2024 Jul 17.
Artigo em Inglês | MEDLINE | ID: mdl-39065355

RESUMO

Solution styrene-butadiene rubber (SSBR) is widely used to improve the properties of tire tread compounds. Tire wear particles (TWPs), which are generated on real roads as vehicles traverse, represent one of significant sources of microplastics. In this study, four SSBR compounds were prepared using two SSBRs with high styrene (STY samples) and 1,2-unit (VIN samples) contents, along with dicyclopentadiene resin. The abrasion behaviors were investigated using four different abrasion testers: cut and chip (CC), Lambourn, DIN, and laboratory abrasion tester (LAT100). The abrasion rates observed in the Lambourn and LAT100 abrasion tests were consistent with each other, but the results of CC and DIN abrasion tests differed from them. The addition of the resin improved the abrasion rate and resulted in the generation of large wear particles. The abrasion rates of STY samples in the Lambourn and LAT100 abrasion tests were lower than those of VIN samples, whereas the values in the CC and DIN abrasion tests were higher than those of VIN samples. The wear particles were predominantly larger than 1000 µm, except for the VIN sample in the DIN abrasion test. However, TWPs > 1000 µm are rarely produced on real roads. The size distributions of wear particles > 1000 µm were 74.0-99.5%, 65.9-93.4%, 7.2-95.1%, and 37.5-83.0% in the CC, Lambourn, DIN, and LAT100 abrasion tests, respectively. The size distributions of wear particles in the Lambourn and LAT100 abrasion tests were broader than those in the other tests, whereas the distributions in the CC abrasion test were narrower. The abrasion patterns and the morphologies and size distributions of wear particles generated by the four abrasion tests varied significantly, attributable to differences in the bound rubber contents, crosslink densities, and tensile properties.

2.
Materials (Basel) ; 17(14)2024 Jul 17.
Artigo em Inglês | MEDLINE | ID: mdl-39063835

RESUMO

Quinacridone (QA) and 2,9-dimethylquinacridone (DQA) are synthetic substances suitable as a hard, abrasion-resistant, self-organizing gliding layer on ice and snow. For sustainable use, a large number of parameters must be considered to demonstrate that these non-biogenic substances and their by-products and degradation products are harmless to humans and the environment in the quantities released. For this task, available experimental data are used and supplemented for all tautomers by numerous relevant physical, chemical, toxicological and ecotoxicological estimated values based on various Quantitative Structure Activity Relationship (QSAR) methods. On the one hand, the low solubility of QA and DQA leads to stable gliding layers and thus, low abrasion and uptake by plants, animals and humans. On the other hand, the four hydrogen bond forming functional groups per molecule allow nanoparticle decomposition and enzymatic degradation in natural environments. All available data justify a sustainable use of QA and DQA as a gliding layer. The assessment of the toxicological properties is complemented by an investigation of the size and morphology of DQA particles, as well as field tests indicating excellent performance as a gliding layer on snow.

3.
Materials (Basel) ; 17(14)2024 Jul 19.
Artigo em Inglês | MEDLINE | ID: mdl-39063874

RESUMO

The paper investigates various methods of microfinishing and arrives at the best technique to produce a very smooth surface. Various setups, with and without oscillation, were developed, together with a microfinishing attachment used on conventional lathes and milling machines. The workpiece material used was an amorphous nickel-phosphorus Ni-P alloy. The surface roughness parameters, such as Sa, Sv, and Sp, were measured with the TalySurf CCI6000 instrument. For the measurement of the surface protrusions, an "analysis of islands" technique was used at various levels of cut-off. The 2BA method-machining below the workpiece axis with oscillation-turned out to be the most effective method applied because it had the highest density of protrusions while having the smallest value of surface roughness. Non-oscillation with the machining zone below the axis also becomes effective, indicating that repositioning can compensate for a lack of oscillation. Already, the very compact surface structure achieved with minimized depths in the valleys by the 2BA method supported the improvement in tribological performance and increase in load-carrying capacity, together with lubricant retention enhancement. These results show that the microfinishing process can be optimized by parameter tuning, and also, non-oscillating methods could come to be a practical alternative, probably reducing the complexity of equipment and cutting costs. Further studies need to be aimed at the scalability of these methods and their application to other materials and fields.

4.
PeerJ ; 12: e17717, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-39026539

RESUMO

Background: Different methods for removing dental carious lesions exist, including conventional rotary caries removal and new advanced technology like polymer-based burs, chemomechanical agents, air abrasion, and laser. Objectives: This study shows the differences in features of dentin (smear layer, patency of dentinal tubules, surface irregularities, intertubular micro porosities, and exposed dentinal tubules) among different types of caries removal techniques. Materials and Methods: An in vitro study was done on 60 primary molars with occlusal class I active caries. Teeth were divided into three groups according to a method of caries removal (G1: chemomechanical, G2: mechanical with a smart bur, and G3: air-abrasion). After complete caries excavation, the teeth were examined under a scanning electronic microscope (SEM) with the power of magnification 4,000x and 8,000x to show the morphological dentinal features with SEM microphotographs. Data obtained was analyzed using the SPSS program where Fisher exact, Kruskal-Wallis and multiple Wilcoxon sum rank tests were used. The level of significance is when the p-value is less than 0.05. Results: Generally, SEM showed the highest ratio of score 1 of smear layer presence, surface irregularities, and microporosity in all groups in both magnifications. The patency of tubules showed the highest ratio of score 1 in G1, scores 2 in both G2 and G3 in magnification 4,000x, while 8,000x there was the highest ratio of its score 1 in G1 and G2 while the G3 has score 2 as the highest score. The exposed dentinal tubules showed the highest ratio in G1 in score 3, in G2 in score 2, and in G3 in score 1 in magnification 4,000x, while 8,000x there was the highest ratio of its score 2 in both G1 and G3 while the G3 has highest score 1. The study with magnification 4,000x showed a significant difference (S) among three groups in exposed dentinal tubules with a p-value (0.012), and there was S between chemomechanical and smart, chemomechanical and air-abrasions groups with a p-value (0.041, 0.001 subsequentially). Other dentin features showed non-significant differences (NS) among or between groups in both magnifications (4,000x, 8,000x). Conclusions: All groups were effective in removing caries and can successfully treat young, scared or stressed patients. All methods of caries removal produce clinically parametric changes in the residual dentin.


Assuntos
Cárie Dentária , Dentina , Microscopia Eletrônica de Varredura , Dente Molar , Cárie Dentária/terapia , Cárie Dentária/patologia , Humanos , Dente Molar/cirurgia , Técnicas In Vitro , Abrasão Dental por Ar/métodos , Preparo da Cavidade Dentária/métodos , Preparo da Cavidade Dentária/instrumentação , Propriedades de Superfície
5.
Environ Monit Assess ; 196(8): 707, 2024 Jul 06.
Artigo em Inglês | MEDLINE | ID: mdl-38970695

RESUMO

Microplastics (MP) are omnipresent in a wide range of environments, constituting a potential threat for aquatic and terrestrial wildlife. Effects in consumers range from physical injuries to pathological reactions. Due to potential bioaccumulation of MP, predators are of particular concern for MP induced health effects. The Eurasian otter is an apex predator in (semi-)aquatic habitats feeding primarily on fish. Furthermore, the species is classified as "near threatened" on the IUCN Red List. Thus, the Eurasian otter is of conservation concern and may serve as a bioindicator for MP pollution. Feces can be used to detect pollutants, including MP. Initial studies confirmed the presence of MP in otter feces (= spraints). However, as specific, validated protocols targeting at an efficient and standardized extraction of MP from otter spraints are missing, experimental results reported from different groups are challenging to compare. Therefore, we (i) present steps towards a standardized protocol for the extraction of MP from otter feces, (ii) give recommendations for field sample collection of otter spraints, and (iii) provide a user-friendly step-by-step workflow for MP extraction and analysis. Applying this framework to field samples from five study sites along the River Inn (n = 50), we detected MP of different sizes and shapes (ranging from microfibers to road abrasion and tire wear) in all otter spraint samples.


Assuntos
Monitoramento Ambiental , Fezes , Microplásticos , Lontras , Rios , Poluentes Químicos da Água , Animais , Monitoramento Ambiental/métodos , Rios/química , Fezes/química , Poluentes Químicos da Água/análise , Microplásticos/análise
6.
Sensors (Basel) ; 24(13)2024 Jun 23.
Artigo em Inglês | MEDLINE | ID: mdl-39000857

RESUMO

Tactile texture sensors are designed to evaluate the sensations felt when a human touches an object. Prior studies have demonstrated the necessity for these sensors to have compliant ridges on their surfaces that mimic human fingerprints. These features enable the simulation of contact phenomena, especially friction and vibration, between human fingertips and objects, enhancing the tactile sensation evaluation. However, the ridges on tactile sensors are susceptible to abrasion damage from repeated use. To date, the healing function of abraded ridges has not been proposed, and its effectiveness needs to be demonstrated. In this study, we investigated whether the signal detection capabilities of a sensor with abraded epidermal ridges could be restored by healing the ridges using polyvinyl chloride plastisol as the sensor material. We developed a prototype tactile sensor with an embedded strain gauge, which was used to repeatedly scan roughness specimens. After more than 1000 measurements, we observed significant deterioration in the sensor's output signal level. The ridges were then reshaped using a mold with a heating function, allowing the sensor to partially regain its original signal levels. This method shows potential for extending the operational lifespan of tactile texture sensors with compliant ridges.


Assuntos
Dermatoglifia , Tato , Humanos , Tato/fisiologia , Dedos/fisiologia , Propriedades de Superfície , Técnicas Biossensoriais/métodos , Técnicas Biossensoriais/instrumentação
7.
Int J Dent Hyg ; 2024 Jul 12.
Artigo em Inglês | MEDLINE | ID: mdl-38997790

RESUMO

AIM: To determine the efficacy of a water flosser (WF) compared to an interdental brush (IDB) in reducing gingival inflammation. Additionally, the products were compared on the incidence of gingival abrasion. METHODS: Young adults with moderate gingivitis and ≥4 accessible interdental spaces by IDB in each quadrant were selected for this study. Participants were randomly assigned a WF or an IDB as an adjunct to manual toothbrushing. Clinical signs of inflammation were measured in two randomly assigned contralateral quadrants by bleeding on pocket probing (BOPP) or bleeding on marginal probing (BOMP). Gingival Abrasion Score (GAS) was assessed per quadrant. Data was recorded at the baseline, 2 weeks and 4 weeks. RESULTS: Both groups WF (n = 40) and IDB (n = 38) showed a significant reduction (p = 0.000) in BOMP and BOPP from the baseline to 4 weeks for all sites and the interdental sites only. At 4 weeks the WF group compared to the IDB group showed significantly lower BOPP (p = 0.030) and BOMP scores (p = 0.003) for all sites. For the interdental sites WF showed compared to IDB for BOMP significant (p = 0.019) lower values but not for BOPP (p = 0.219). There were no differences between the groups for GAS at any time point. CONCLUSION: In patients with moderate gingivitis, after 4 weeks use the WF is more effective than the IDB in obtaining marginal gingival health.

8.
Artigo em Inglês | MEDLINE | ID: mdl-39039367

RESUMO

The building sector is growing at a rapid rate, leading to an increased demand for construction materials. Concrete made with Ordinary Portland Cement (OPC) has long been the preferred choice due to its excellent bonding properties and versatility as demanded by construction process. However, the manufacturing of Ordinary Portland Cement (OPC) leads to negative impacts on the environment, with the cement sector responsible for around 5-8% of global CO2 emissions. In addition, the manufacture of OPC necessitates significant amounts of natural raw materials and energy. Contrastingly, using geopolymers promises to save substantial amounts of energy and reduce CO2 emissions. This potential has sparked growing interest in the application of geopolymers within transportation infrastructure. For pavements, the workability requirement is less, and hence, geopolymer concrete (GPC) is a viable option, but fatigue-resistance of GPC is not seen reported in literatures. This article evaluates the properties of geopolymer concrete with low-calcium fly ash partially replaced with ground granular blast furnace slag (GGBS) with 8 M NaOH alkaline solution and cured under ambient atmospheric conditions to evaluate its usage in pavements and develop an environmentally sustainable and durable GPC capable of withstanding heavy traffic. The study involves adjusting the pavement quality concrete (PQC) mix design; evaluating the mechanical characteristics, abrasion resistance, and shrinkage strain of the GPC; and analyzing its microstructure. Additionally, the study compares the fatigue life of GPC to that of PQC using various Weibull distribution approaches. The results showed that GPC4 (70% Fly ash and 30% GGBS) mix achieved best results at 28 days, with a compressive strength of 45.68 MPa, split tensile strength of 3.76 MPa, and flexural strength of 4.62 MPa. Also, shrinkage strains were nearly 31% lesser than PQC at 90 days. In addition, developing GPC needs 27% lesser embodied energy than PQC. Fatigue analysis prove that ambient cured fly ash-GGBS based geopolymer concrete with 8 M NaOH exhibits less stress development than PQC at medium loads, even though it is brittle. Thus, the study proves that it is suitable as a material for pavements to resist medium-loaded traffic-resisting pavements.

9.
Cureus ; 16(5): e59455, 2024 May.
Artigo em Inglês | MEDLINE | ID: mdl-38826928

RESUMO

The most common aesthetic issue that affects people's smiles is gingival pigmentation, especially in those with high smile lines. This pigmented gingiva is thought to be naturally occurring melanin pigments that add to the gingiva's endogenous pigmentation. The goal of plastic periodontal surgery known as "gingival depigmentation" is to lighten the dark gingiva by scraping off the gingival epithelium. Gingival depigmentation has been performed with a variety of techniques, including bur abrasion, scraping, partial thickness flap, cryotherapy, electrocautery, and laser. The present case comprised a split-mouth design in which depigmentation using an electrosurgical unit and soft tissue trimming bur was used for the maxillary sections, and evaluated the difference in pain felt by the patient and healing of the surgical site between the sites treated with the electrosurgical unit and bur abrasion method. A visual analog scale (VAS) was used to quantify pain felt by the patient on the seventh day, whereas healing was assessed on the seventh day and at a one-month interval visually. The results of this study showed that the electrocautery-treated site showed better results in terms of pain experienced by the patient and also with the surgical site healing.

10.
Materials (Basel) ; 17(12)2024 Jun 19.
Artigo em Inglês | MEDLINE | ID: mdl-38930369

RESUMO

As a renewable, environmentally friendly, natural, and organic material, wood has been receiving extensive attention from various industries. However, the hydrophilicity of wood significantly impacts the stability and durability of its products, which can be effectively addressed by constructing superhydrophobic coatings on the surface of wood. In this study, tung oil, carnauba wax, and silica nanoparticles were used to construct superhydrophobic coatings on hydrophilic wood surfaces by a facile two-step dip-coating method. The surface wettability and morphology of the coatings were analyzed by a contact angle meter and scanning electron microscope, respectively. The results suggest that the coating has a micron-nanosized two-tiered structure, and the contact angle of the coating is higher than 150° and the roll-off angle is lower than 10°. Sandpaper abrasion tests and UV diffuse reflectance spectra indicate that the coatings have excellent abrasion resistance and good transparency. In addition, the coated wood shows excellent self-cleaning and water resistance, which have great potential for applications in industry and furniture manufacturing.

11.
Materials (Basel) ; 17(12)2024 Jun 20.
Artigo em Inglês | MEDLINE | ID: mdl-38930390

RESUMO

The risk of the releasing of nanometric particles from construction materials with nanometric components might be one of the biggest threats to further development of them. One of the possible ingress routes to human organisms is the respiratory system. Therefore, it is crucial to determine the risk of emission of nanometric particles during material usage. In the presented paper, abrasion of mortar samples with nanometric TiO2 was investigated. A special abrasion test setup was developed to reflect everyday abrasion of the concrete surface of pavements. In the study, three TiO2-modifed mortar series (and respective reference series) underwent the developed test protocol and the grains were mobilized from their surface due to the applied load analyzed (granulation, morphology, and chemical composition). For a comparative analysis, an abrasion parameter was developed. Based on the obtained results, the modification of cementitious composites with nanometric TiO2 contributed to a reduction in the emission of aerosols and, therefore, confirmed the compatibility between TiO2 and cement matrix.

12.
Polymers (Basel) ; 16(12)2024 Jun 17.
Artigo em Inglês | MEDLINE | ID: mdl-38932075

RESUMO

The mechanical properties of textile materials play a crucial role in determining their comfort, functionality, performance, safety, and aesthetics. Understanding and optimizing these properties is essential to meet consumer demands. Key aspects of mechanical properties, such as surface roughness, abrasion resistance, and compression, have a significant impact on the touch and durability of the material, as demonstrated by various research studies. This study focuses on analyzing the mechanical properties of materials produced of different polymer yarns and their changes under combined aging factors. The findings emphasize the significance of textile abrasion resistance and surface roughness measurement, particularly for aged materials. Although the use of recycled polyester yarn is sustainable and offers advantages such as higher tensile strength, the results have shown that the use of conventional polyester yarn is more advantageous overall as it has higher abrasion resistance, a smoother surface texture, and better elasticity retention after aging. The insights presented are vital for designing high-performance sportswear, which is crucial in today's competitive environment.

13.
Sci Total Environ ; 944: 173948, 2024 Sep 20.
Artigo em Inglês | MEDLINE | ID: mdl-38880134

RESUMO

Microparticles such as tire-road wear particles (TRWPs) and road pavement wear particles (RPWPs) are generated by the friction between tire tread and road surface. TRWPs and RPWPs on roads are dispersed through traffic and transferred to rivers and seas via runoff to accumulate in sediments. However, research on the generation of both TRWP and RPWP has rarely been conducted. In this study, the generation of both TRWP and RPWP was investigated using a novel tire abrasion simulator equipped with paved road and bus tire, and their contributions to the generation of microparticles were examined. Two types of model paved roads, asphalt and concrete pavements (AP and CP, respectively), were applied. TRWPs generated from the simulator exhibited morphologies very similar to those on real roads. The abrasion rate for the CP was 2.8 times higher than that for the AP. The wear particle size distributions peaked at the size ranges of 63-106 µm and 212-500 µm for the AP and CP, respectively. Totals of 84 wt% and 89 wt% of the wear particles were distributed in size ranges of 38-212 µm for the AP and 106-1000 µm for the CP. The tire wear particle (TWP) contents in the total wear particles of 38-500 µm were 21.7 wt% and 30.0 wt% for the AP and CP, respectively, and decreased as the particle size decreased. The weight of RPWP was higher than that of TWP in TRWP. Contributions from road pavement to the generation of wear particles of 38-500 µm were 3.6 and 2.3 times higher than those from tire tread for the AP and CP, respectively, and the contribution increased as the wear particle size decreased.

14.
Vet Q ; 44(1): 1-11, 2024 Dec.
Artigo em Inglês | MEDLINE | ID: mdl-38832661

RESUMO

Hemorrhagic bowel syndrome (HBS) is characterized by a dissecting intramucosal hematoma at the small bowel, causing obstruction and severe hemorrhage in dairy cattle. Recent investigation revealed the presence of early-stage lesions in cows affected by HBS. These are presumed to be the initial stage of the hematoma, as both share unique dissection of the lamina muscularis mucosae (LMM) as histological hallmark. Early-stage lesions of HBS have not been characterized in greater detail, and neither has the hypothesis of mucosal abrasion as etiology been explored. Therefore, the first objective of the present study was to characterize the morphology of early-stage lesions, by gross examination, histochemistry, immunohistochemistry and transmission electron microscopy. The second objective was to determine the effect of mucosal abrasion to the small intestine in an ex vivo model. A total of 86 early-stage lesions from 10 cows with HBS were characterized. No underlying alterations at the LMM were evident which could explain their occurrence. However, degeneration at the ultrastructural level of the LMM smooth muscle cells was present in 3 of 4 lesions, it is however unclear whether this is primary or secondary. Bacteriological examination did not reveal any association with a specific bacterium. Experimental-induced and early-stage lesions were gross and histologically evaluated and scored in three cows with HBS and seven controls. Experimentally induced lesions in both affected cows and controls, were histologically very similar to the naturally occurring early-stage lesions. Altogether, the results are suggestive for mucosal trauma to play a role in the pathogenesis of HBS.


Assuntos
Doenças dos Bovinos , Hemorragia Gastrointestinal , Mucosa Intestinal , Animais , Bovinos , Doenças dos Bovinos/patologia , Mucosa Intestinal/patologia , Mucosa Intestinal/ultraestrutura , Feminino , Hemorragia Gastrointestinal/veterinária , Hemorragia Gastrointestinal/patologia , Microscopia Eletrônica de Transmissão/veterinária , Intestino Delgado/patologia , Imuno-Histoquímica/veterinária , Enteropatias/veterinária , Enteropatias/patologia
15.
Healthcare (Basel) ; 12(11)2024 May 24.
Artigo em Inglês | MEDLINE | ID: mdl-38891145

RESUMO

Dental wear arises from mechanical (attrition or abrasion) and chemical (erosion) factors. Despite its prevalence and clinical significance, accurately measuring and understanding its causes remain challenging in everyday practice. This one-year study with 39 participants involved comprehensive examinations and full-arch intraoral scans at the start and after 12 months. Volume loss exceeding 100 µ on each tooth's surfaces (buccal, lingual/palatine and incisal/occlusal) was measured by comparing three-dimensional scans from both time points. This study also assessed factors such as abrasion and erosion through clinical exams and questionnaires. There were no significant differences in dental wear in participants with sleep bruxism. However, noticeable wear occurred in the front teeth of those with waking bruxism and joint-related symptoms. Increased wear was associated with frequent consumption of acidic drinks, regular swimming, dry mouth, nocturnal drooling and heartburn, while no significant wear was found in patients with reflux. The used methodology proved effective in accurately assessing the progression of dental wear, which is important as many patients may initially be asymptomatic. The variability observed in dental wear patterns underscores the need to develop specific software applications that allow immediate and efficient comparison of wear areas based on extensive analysis of patient databases.

16.
Polymers (Basel) ; 16(11)2024 May 24.
Artigo em Inglês | MEDLINE | ID: mdl-38891435

RESUMO

This study investigates the impact of mechanical alteration on resin composite surfaces and its subsequent effect on repair bond strength. A total of 100 resin composite disks were prepared and were allocated for 24 h or 1 year of artificial aging. Specimens were embedded in epoxy resin, and the composite surfaces were mechanically altered using either diamond burs or air abrasion with aluminum oxide or glass beads. A universal bonding material was applied and a 2 mm circular and 3 mm high repair composite cylinder were prepared using a Teflon mold. Then, the specimens were tested for their shear bond strength, and the de-bonded specimens were observed under a scanning electron microscope to determine the failure pattern. SPSS 26.0 statistical software was used to analyze the data. Two-way ANOVA showed a statistically significant effect of mechanical alteration and aging on the shear bond strength of S-PRG-filler-based resin composite (p < 0.05). Surface modification with a fine diamond bur showed a significantly higher bond strength in both 24-h- and 1-year-aged specimens. Surface modification with alumina significantly increased the bond strength of 1-year-aged specimens; however, it was statistically insignificant for 24 h-aged specimens. Mechanical alteration with a fine diamond bur and 50-micron alumina can improve the repair bond strength of the composite.

17.
Res Sq ; 2024 Jun 04.
Artigo em Inglês | MEDLINE | ID: mdl-38883773

RESUMO

Background: Despite potential benefit, outpatient use of topical ophthalmic anesthetics can result in poor healing, infection, scar, and blindness. An unbiased analysis of randomized controlled trials (RCTs) is needed to examine their effectiveness and safety compared with placebo or other treatments for corneal abrasions. Methods: Cochrane Central Register of Controlled Trials, MEDLINE, Embase.com, Latin American and Caribbean Health Sciences, ClinicalTrials.gov, and the World Health Organization International Clinical Trials Registry Platform were searched on February 10, 2023, without restriction on language or publication date. Results: Systematic review and meta-analysis of nine RCTs describing 314 participants with post-traumatic abrasions and 242 participants with post-surgical abrasions, with a median study length of 7 days (interquartile range, 7-14), show no evidence of a difference in pain control between anesthetics and placebo at 24 hours in post-trauma cases. Self-reported pain at 24 hours is reduced with anesthetics plus topical nonsteroid anti-inflammatory drug in post-surgical participants (mean difference [MD], -5.72 on a 10-point scale; 95% CI, -7.35 to -4.09; 1 RCT; 30 participants) and at 48 hours with anesthetics alone in post-trauma participants (MD, -5.68; 95% CI, -6.38 to -4.98; 1 RCT; 111 participants). Anesthetics are associated with 37% increased risk of non-healing defects (risk ratio, 1.37; 95% CI, 0.78 to 2.42; 3 RCTs; 221 post-trauma participants). All evidence is of very low certainty. Over 50% of trials have an overall high risk of bias. Conclusions: Available evidence is insufficient to support outpatient use of topical anesthetics for corneal abrasions with respect to pain, re-epithelialization, and complication risk.

18.
ACS Appl Mater Interfaces ; 16(25): 32633-32648, 2024 Jun 26.
Artigo em Inglês | MEDLINE | ID: mdl-38864608

RESUMO

The lack of a comprehensive force field and understanding at the mesoscale for hydrated calcium silicate (CSH)/polyvinyl alcohol (PVA) fiber has hindered the upscaling and bridging of nanoscale to macroscale phenomena. In this study, we propose a coarse-grained (CG) force field that incorporates bond-breaking operations to endow fiber reactivity, abrasion, and fracture properties. By employing a cubic lattice modeling, we effectively address the challenges associated with semicrystalline relaxation of fibers. For the first time, quasi-reaction CG simulation successfully replicates slip-hardening behaviors and surface abrasion. We demonstrate that abrasion improves interface load transfer and triggers slip-hardening by redistributing stress. Additionally, the influences of single and coupled factors, such as nonbonding interactions and surface roughness, are investigated. Mesoscale understanding provides insights for enabling precise control of load transfer paths and fabrication of interface damage-predictable materials.

19.
Clin Cosmet Investig Dent ; 16: 191-199, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-38835853

RESUMO

Objective: This study aimed to evaluate the bond strength of a universal adhesive to dentin (µTBS) using different time periods of airborne particle abrasion (APA) and two types of acid etching. Methods: Seventy-two human third molars were divided into 9 groups (n=8) according to dentin pretreatment: APA duration (0, 5, or 10s) and acid etching (no acid - NA, 37% phosphoric acid - PhoA, or 1% phytic acid - PhyA). APA was performed at a 0.5 cm distance and air pressure of 60 psi using 50 µm aluminum oxide particles. Afterwards, two coats of Single Bond Universal adhesive (3M) were applied to the dentin surface. Composite blocks were built using the incremental technique, sectioned into 1×1 mm slices and subjected to microtensile bond strength (µTBS) testing. Fracture patterns and surface topography of each dentinal pretreatment were evaluated using a Scanning electron microscope (SEM). Bond strength data were analyzed using two-way ANOVA and Bonferroni post-hoc tests. Results: The group that received pretreatment with 5s APA and PhoA presented higher µTBS values among all groups, which was statistically different when compared with the PhoA, 10APA+PhoA, and 5APA+PhyA groups. PhyA did not significantly influence the bond strength of the air-abraded groups. Finally, adhesive failure was considered the predominant failure in all groups. Conclusion: Dentin pretreated by airborne particle abrasion using aluminum oxide demonstrated an increase in bond strength when abraded for 5 seconds and conditioned with phosphoric acid in a universal adhesive system.

20.
Materials (Basel) ; 17(10)2024 May 18.
Artigo em Inglês | MEDLINE | ID: mdl-38793496

RESUMO

This study investigates the surface topography of microfinishing abrasive films and their machining capability on the Nimonic 80A superalloy, a high-performance nickel-based alloy commonly used in aerospace and gas turbine engine applications. Surface analysis was conducted on three abrasive films with nominal grain sizes of 30, 15, and 9 µm, exploring wear patterns, contact frequency, and distribution. To assess the distribution of grain apexes, Voronoi cells were employed. Results revealed distinct wear mechanisms, including torn abrasive grains and cracked bond surfaces, highlighting the importance of efficient chip removal mechanisms in microfinishing processes. Larger grain sizes exhibited fewer contacts with the workpiece but provided more storage space for machining products, while smaller grain sizes facilitated smoother surface finishes. The research demonstrated the effectiveness of microfinishing abrasive films in reducing surface irregularities. Additionally, surface analysis of worn abrasive tools provided insights into wear mechanisms and chip formation, with the segmentation of microchips contributing to efficient chip removal. These findings underscore the significance of selecting appropriate abrasive films and implementing effective chip removal mechanisms to optimize microfinishing processes and improve surface finishing quality in advanced material machining applications. It is worth emphasizing that no prior research has investigated the microfinishing of components crafted from Nimonic 80A utilizing abrasive films, rendering this study truly unique in its contribution to the field.

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