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1.
Fundam Res ; 4(4): 868-881, 2024 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-39156573

RESUMO

In this work, two kinds of primary batteries, both of which included a Zn anode, C rod cathode, copper wire and electrolyte composed of Cd2+-contaminated water or soil, were constructed in the first attempt to both remove Cd2+ and generate electricity. Unlike traditional technologies such as electrokinetic remediation with high energy consumption, this technology could realize Cd2+ migration to aggregation and solidification and generate energy at the same time through simultaneous galvanic reactions. The passive surface of Zn and C was proven via electrochemical measurements to be porous to maintain the relatively active galvanic reactions for continuous Cd2+ precipitation. Cd2+ RE (removal efficiency) and electricity generation were investigated under different conditions, based on which two empirical models were established to predict them successfully. In soil, KCl was added to desorb Cd2+ from soil colloids to promote Cd2+ removal. These systems were also proven to remove Cd2+ efficiently when their effects on plants, zebrafish, and the soil bacterial community were tested. LEDs could be lit for days by utilizing the electricity produced herein. This work provides a novel, green, and low-cost route to remediate Cd2+ contamination and generate electricity simultaneously, which is of extensive practical significance in the environmental and energy fields.

2.
Heliyon ; 10(15): e34770, 2024 Aug 15.
Artigo em Inglês | MEDLINE | ID: mdl-39157354

RESUMO

The emergence of simulators and their integration into teaching practice in the world of education have offered us technological opportunities to enhance and promote learning. Science students' abilities to observe, measure, predict, control variables, formulate hypotheses, and interpret data can all be activated by including simulations into the curriculum. The aim of this work is to study the effects of integrating an "evolution of electrical systems" simulator in improving students' motivation, participation and school results in learning and teaching electricity lessons in Moroccan secondary schools. Two study groups of 34 and 35 students were chosen to examine the research hypothesis. They both meet the standards for this research (same teacher, same school level, coming from the same socio-economic environment, and almost similar results in their school careers). Before beginning the process of incorporating simulation sequences in teaching, a diagnostic test was administered to both groups to assess the prerequisites for the RC and RL dipoles, and the results were evaluated. Then we designated one of the two groups as the test group, which received instruction using simulation sequences, and the other group as the control group, which received traditional teaching. Both groups took an Achievement test to evaluate the impact of this integration on the learning of physics. After examining the test data (Charts Comparison and Student's t-test), we came to the conclusion that the use of simulation sequences in the classroom produced significantly more positive and satisfactory results than the traditional approach (Mt = 12,09 for the test group and Mc = 9,69 for the control group). We saw during the sessions that the experimental class students were more motivated and engaged in their learning than the control group. We collected this data by closely observing behavioral shifts, participation rates, and student involvement in the design of the course. These new techniques contribute at improving the experimental part of electricity in secondary schools.

3.
Heliyon ; 10(14): e33943, 2024 Jul 30.
Artigo em Inglês | MEDLINE | ID: mdl-39092239

RESUMO

The recent COVID-19 pandemic has precipitated drastic changes in economic and lifestyle conditions, significantly altering residual electricity demand behavior. This alteration has expanded the demand gap between actual and forecasted electricity usage based on pre-pandemic data, highlighting a critical global issue. Many studies in the pandemic have explored the features of this widening gap, which is impacted by major social events like fast virus spread and lockdowns. However, the influence of factors like economic shifts and lifestyle changes on this demand remains largely unexplored, primarily due to the pandemic's significant effects in these areas. Understanding the essential factors affecting the demand gap is crucial for stakeholders in the electricity sector to develop effective strategies. This study examines the hourly electricity consumption and related factors during the specified period. We present a method combining time-series forecasting and sparse modeling. This helps identify critical factors affecting the electricity demand gap during the pandemic, highlighting the most crucial variables. Utilizing this method, we identify the variables that have undergone significant changes during the pandemic and evaluate their effects on the electricity demand gap. The effectiveness is proven by applying it to the dataset collected in German.

4.
Heliyon ; 10(14): e34470, 2024 Jul 30.
Artigo em Inglês | MEDLINE | ID: mdl-39114057

RESUMO

Understanding electrical hazards and implementing safety measures is paramount to protecting lives and property. Therefore, this research investigates electrical hazards in households and safety measures taken by residents in Sokode-Etoe, Ghana. The primary objective is to identify gaps in knowledge regarding electrical hazards among domestic electricity consumers and offer recommendations to enhance safety and mitigate the risks. The data were systematically collected from 200 participants, including both homeowners and tenants, using a structured questionnaire. The results were presented using Likert scale analysis, sample t-test, binary logistic regression analysis, involving statistical hypothesis testing of predictor variable coefficients, Importance-Performance Map Analysis (IPMA) and Necessary Condition Analysis (NCA). Participants showed a high awareness of electrical hazards, yet demonstrated a weaker grasp of safety practices, correct emergency procedures, and infrequent testing of wiring systems by homeowners. The predominant electrical accident that emerged was electrical shock. Most homeowners have not engaged certified electrical inspectors for a decade, reflecting uncertainty about the safety protocols in place. Furthermore, respondents expressed a degree of uncertainty regarding the safety measures implemented in their households concerning electricity usage. This study underscores the pressing need to raise awareness and promote safe electrical practices in residential environments. Such an educational initiative could utilize a variety of communication channels, social media influencers, renowned personalities, customised mobile applications and other platforms. This research stands out as the inaugural investigation offering a comprehensive examination of the hazards related to energy consumption and safety precautions in Ghana. It focuses on an often-overlooked demographic of electricity users in Ghana, shedding light on domestic electrical safety issues and the growing hazards.

5.
Sensors (Basel) ; 24(15)2024 Jul 30.
Artigo em Inglês | MEDLINE | ID: mdl-39123972

RESUMO

This study introduces an orbital monitoring system designed to quantify non-technical losses (NTLs) within electricity distribution networks. Leveraging Sentinel-2 satellite imagery alongside advanced techniques in computer vision and machine learning, this system focuses on accurately segmenting urban areas, facilitating the removal of clouds, and utilizing OpenStreetMap masks for pre-annotation. Through testing on two datasets, the method attained a Jaccard index (IoU) of 0.9210 on the training set, derived from the region of France, and 0.88 on the test set, obtained from the region of Brazil, underscoring its efficacy and resilience. The precise segmentation of urban zones enables the identification of areas beyond the electric distribution company's coverage, thereby highlighting potential irregularities with heightened reliability. This approach holds promise for mitigating NTL, particularly through its ability to pinpoint potential irregular areas.

6.
J Colloid Interface Sci ; 677(Pt A): 983-993, 2024 Aug 02.
Artigo em Inglês | MEDLINE | ID: mdl-39128292

RESUMO

Direct lignin fuel cells (DLFC) are one of the important forms of high value-added utilization of lignin. In this study, lignin was studied not only as a fuel but also as a catalyst. Specifically, Kraft lignin was modified with ZnCl2, KOH and THF (Tetrahydrofuran) respectively, and added to the catalyst after activation. The results of scanning electron microscope (SEM), transmission electron microscope (TEM), energy dispersive spectrometer (EDS), Brunauer - Emmett - Teller (BET), X-ray photoelectron spectroscopy (XPS), X-ray diffractometer (XRD), Fourier transform infrared spectroscopy (FT-IR) and Raman spectra shown that AL/FePc-NrGO (activated lignin/iron phthalocyanine/nitrogen-doped reduction of graphene oxide) three-dimensional composite catalyst has been synthesized. The results showed that KOH-activated Kraft lignin had the best performance as an oxygen reduction reaction (ORR) catalyst, with a half-wave potential (E1/2) of 0.73 V and a limiting diffusion current density of 4.3 mA cm-1. The THF-modified catalyst showed similar stability and methanol resistance to 20 % Pt/C at ORR. The ORR catalyst applied to the DLFC has the best electrical performance with an open circuit voltage (OCV) was 0.53 V and the maximum power density it could reach 95.29 mW m-2 when the catalyst was modified with THF. It is encouraging that the AL/FePc-NrGO catalyst has better-generated electricity performance than 20 % Pt/C. This work has provided a new idea for developing non-noble metal catalysts and studying direct biomass liquid fuel cells.

7.
ACS Nano ; 2024 Aug 21.
Artigo em Inglês | MEDLINE | ID: mdl-39168863

RESUMO

The natural water cycle on the Earth carries an enormous amount of energy as thirty-five percent of solar energy reaching the Earth's surface goes into water. However, only a very marginal part of the contained energy, mostly kinetic energy of large volume bulk water, is harvested by hydroelectric power plants. Natural processes in the water cycle, such as rainfall, water evaporation, and moisture adsorption, are widespread but have remained underexploited in the past due to the lack of appropriate technologies. In the past decade, the emergence of hydrovoltaic technology has provided ever-increasing opportunities to extend the technical capability for energy harvesting from the water cycle. Featuring electricity generation from mechanical-electric coupling at the water-solid interface, hydrovoltaic technology embraces almost all dynamic processes associated with water, including raining, waving, flowing, evaporating, and moisture adsorbing. This versatility in dealing with various forms of water and associated energy renders hydrovoltaic technology a solution for fossil fuel-caused environmental problems. Here, we review the current progress of hydrovoltaic energy harvesting from water motion, evaporation, and ambient moisture. Device configuration, energy conversion mechanism mediated by mechanical-electric coupling at various water-solid interfaces, as well as materials selection and functionalization are discussed. Useful strategies guided by established mechanisms for device optimization are then covered. Finally, we provide an outlook on this emerging field and outline the challenges of improving output performance toward potential practical applications.

8.
Environ Sci Technol ; 2024 Aug 22.
Artigo em Inglês | MEDLINE | ID: mdl-39171721

RESUMO

Although Africa contributes less than 5% to global greenhouse gas (GHG) emissions, its role in global climate action is pivotal. To date, 53 African countries have submitted their Nationally Determined Contributions (NDCs), and four have committed to a net-zero target. However, many of Africa's NDCs are vaguely expressed and without specific focus on explicit sectoral decarbonization targets. Furthermore, Africa's huge land-based carbon dioxide removal (CDR) potential remains unclear in the context of enabling net-zero emissions within the continent. This study achieves two objectives: Under a NZ GHG emission trajectory in Africa, we uncover the implications of a targeted zero-emission electricity sector by 2030, on the energy landscape and other sustainability factors. This study also features the role of land-based biological removal methods─bioenergy carbon capture and storage (BECCS) and afforestation/reforestation (A/R)─in net zero actualization in Africa. Our results reveal a unified but disparate actualisation of the mid-century net zero emission goal across the continent, as all regions except North Africa achieve carbon neutrality. The industrial sector faces significant difficulties in transitioning and contributes substantially to positive emissions on the continent, with its share of total residual emissions reaching 49-64% by 2050. This difficulty persists even with targeted sectoral decarbonization of the electricity sector, although it is significantly reduced by the availability of BECCS as a CDR option. Under thezero-emission electricity pathway, emissions in buildings and transport sectors are reduced due to rapid electrification. A trade-off emerges in the net zero pathway concerning land allocation for negative emissions versus other land use activities. A key result shows that achieving a net zero target in Africa leads to a cumulative loss of $102 billion in fossil fuel infrastructure within the electricity sector by mid-century, which doubles when the zero-emission electricity goal is achieved.

9.
J Environ Manage ; 367: 121958, 2024 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-39094413

RESUMO

One of the main current focuses of global economies and decision-makers is the efficiency of energy utilization in cryptocurrency mining and trading, along with the reduction of associated carbon emissions. Understanding the pattern of Bitcoin's energy consumption and its bubble frequency can greatly enhance policy analysis and decision-making for energy efficiency and carbon emission reduction. This research aims to assess the validity of the random walk hypothesis for Bitcoin's electricity consumption and carbon footprint. We employed both traditional methods (ADF and KPSS) and recently proposed unit root techniques that account for structural breaks and non-linearity in the data series. Our analysis covers daily data from July 2010 to December 2021. The empirical results revealed that traditional unit root techniques did not confirm the stationarity of both bitcoin's electricity consumption and carbon footprint. However, novel structural break (SB) and linearity tests conducted enabled us to discover five SB episodes between 2012 and 2020 and non-linearity of the variables, which informed our application of the newly developed non-linear unit root tests with structural breaks. With the new methods, the results indicated stationarity after accommodating the SB and non-linearity. Furthermore, based on Phillips and Shi (2019)'s test, we identified certain bubble episodes in the bitcoin energy and carbon variables between 2013 and 2021. The major drivers of the bubbles in bitcoin energy consumption and carbon footprint are variables relating to the bitcoin and financial markets activities and risks, including the global economic and political risks. The study's conclusion based on the above findings informs several policy implications drawn for energy and environmental management including the encouragement of green investments in cryptocurrency mining and trading.


Assuntos
Pegada de Carbono , Eletricidade , Carbono
10.
J Environ Manage ; 367: 122082, 2024 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-39111005

RESUMO

China's renewable energy industry is facing the challenge of overcapacity. The environmental management literature suggests that consumers' participation in the green electricity market holds immense potential in addressing renewable energy consumption concerns. However, the question of how payment policies influence China's consumers' willingness to pay for green electricity remains unresolved. Based on 2854 valid questionnaires from a survey conducted in China's four first-tier cities in 2023, our research findings reveal: (1) While 97.9% of consumers express a willingness to use green electricity, only 63.1% are willing to pay a higher cost, indicating the existence of a "value-action" gap between environmental awareness and actual willingness to pay. (2) China's consumers' willingness to pay for green electricity is approximately 38.4 RMB per month. This figure has decreased by 5.7 RMB compared to our survey in 2019. (3) Consumers' willingness to pay will be influenced by the attitudes of those around them. (4) The voluntary payment policy positively impacts consumers' willingness to pay for green electricity. (5) Male, younger, lower education level, higher income, and larger household size consumers exhibit a higher willingness to pay. (6) Electricity price sensitivity weakens the impact of payment policies on willingness to pay.


Assuntos
Cidades , Eletricidade , China , Inquéritos e Questionários , Humanos , Comportamento do Consumidor , Conservação dos Recursos Naturais
11.
ACS Appl Mater Interfaces ; 16(33): 44298-44304, 2024 Aug 21.
Artigo em Inglês | MEDLINE | ID: mdl-39108070

RESUMO

Obtaining water and renewable energy from the atmosphere provides a potential solution to the growing energy shortage. Leveraging the synergistic inspiration from desert beetles, cactus spines, and rice leaves, here, a multibioinspired hybrid wetting rod (HWR) is prepared through simple solution immersion and laser etching, which endows an efficient water collection from the atmosphere. Importantly, benefiting from the bionic asymmetric pattern design and the three-dimensional structure, the HWR possesses an omnidirectional fog collection with a rate of up to 23 g cm-2 h-1. We further show that the HWR could be combined with a droplet-based electricity generator to convert kinetic energy from falling droplets into electrical energy with a maximum output voltage of 200 V and a current of 2.47 µA to light up 28 LEDs. Collectively, this research provides a strategy for synchronous fog collection and power generation, which is promising for environmentally friendly energy production.

12.
ACS Nano ; 18(34): 22648-22663, 2024 Aug 27.
Artigo em Inglês | MEDLINE | ID: mdl-39143807

RESUMO

Solar-driven water-electricity cogeneration is a promising strategy for tackling water scarcity and power shortages. However, comprehensive reviews on performance, scalability, commercialization, and power density are lacking. This Perspective presents an overview of recent developments and insights into the challenges and future outlooks for practical applications in this area. We summarize recent advances in high-efficiency water production, focusing on rapid evaporation and condensation. Then we categorize power-water cogeneration systems by power generation mechanisms like steam, evaporation, salinity gradient, photovoltaics, and temperature gradient, providing a comprehensive summary of the performance and applicability of these systems in different scenarios. Finally, we highlight challenges in current systems, considering nanoscale mechanisms and large-scale manufacturing, while also exploring potential trends for future practical applications.

13.
Bioresour Technol ; 411: 131301, 2024 Aug 15.
Artigo em Inglês | MEDLINE | ID: mdl-39153694

RESUMO

This study investigated the technical feasibility of using electrogermination to activate dormant cysts as an inoculum for subsequent 14-d photosynthetic astaxanthin production in Haematococcus lacustris. Electrotreatment affected the cell viability, surface charge, and morphology of H. lacustris cysts. At an optimal voltage of 2 V for 60 min, the cyst germination rate peaked at 44.6 % after 1 d, representing a 2.2-fold increase compared with that of the untreated control. Notably, electrogermination significantly enhanced both the astaxanthin content (44.9 mg/g cell) and productivity (13.2 mg/L/d) after 14 d of photobioreactor cultivation, corresponding to 1.7- and 1.5-fold increases compared with those in control, respectively. However, excessive electrotreatment, particularly at voltages exceeding 2 V or for durations beyond 60 min, did not enhance the astaxanthin production capability of H. lacustris. Proper optimization of renewable electrogermination can enable sustainable algal biorefinery to produce multiple bioactive products without compromising cell viability and astaxanthin productivity.

14.
Sci Total Environ ; 951: 175599, 2024 Aug 20.
Artigo em Inglês | MEDLINE | ID: mdl-39173775

RESUMO

Indole and pyridine, which are highly produced refractory compounds in the industrial wastewater, exhibit poor degradation capabilities in natural environments. In this study, we developed an anaerobic digestion system coupled with weak electric mediation (ED), and investigated the promoting effect of weak electricity on indole and pyridine biodegradation. The degradation characteristics were systematically explored, and the results showed that the degradation rate and mineralization of indole and pyridine were significantly enhanced, the production of CH4 was increased 1.4-fold, and the optimal voltages were 1.0 V and 0.8 V in the ED, respectively. Moreover, simultaneous removal of carbon and nitrogen was achieved. Gas chromatography-mass spectrometry analysis verified the transformation products, and possible pathways were proposed. Several byproducts of indole and pyridine were identified, with oxindole and glutaric dialdehyde being the main metabolites, respectively. Additionally, density functional theory (DFT) analysis was performed to investigated the radical indices and stabilities of the molecules to further confirm the degradation pathway. Microbial structure analysis demonstrated that the electrically mediated enhanced metabolism and activity of functional microbes, led to the promotion of indole and pyridine mineralization. Moreover, such species as degrading bacteria (Alicycliphilus, Shinella) and electroactive bacteria (Achromobacter), anaerobic ammonia-oxidizing bacteria (SM1A02), and denitrifying bacteria (Thiobacillus) coexisted. This study demonstrates that weak electric mediation is a promising methodology for enhancing the removal of indole and pyridine from wastewater under anaerobic conditions.

15.
Heliyon ; 10(13): e33112, 2024 Jul 15.
Artigo em Inglês | MEDLINE | ID: mdl-39027622

RESUMO

This study evaluates the performance dynamics of Oman's principal part of electricity generation. Emphasis is placed on capturing the influence of the COVID-19 pandemic on the industry's performance indicators. We utilised the Malmquist Index method to analyse the changes in overall performance indicators over time. This approach allows us to distinguish between efficiency and technology changes. In addition, we employed the analysis of variance approach to test hypotheses related to COVID-19. Data is collected from twelve electricity producers across Oman's power sector. These consist of companies listed on the Stock Exchange Market in Oman, accounting for about 60 % of the total electricity production in the Sultanate. The predominant findings indicate that COVID-19 detrimentally impacted the sector's aggregate performance in 2020 but had a swift recovery in 2021. The analysis of the sample firm's productivity indices verifies that the decline in productivity in 2020 due to the Pandemic is attributable to a decrease in average efficiency indices and a negative shift in the projected frontier. These are probable consequences of the recessionary effects caused by the Pandemic. Despite a considerable decrease in average efficiency scores, a positive change in the frontier has facilitated a rapid recovery in 2021. This recovery can be attributed to the implementation of advanced technical upgrades in particular enterprises, which began as early as 2018/2019, well before the onset of the Pandemic.

16.
Adv Mater ; : e2407856, 2024 Jul 20.
Artigo em Inglês | MEDLINE | ID: mdl-39032113

RESUMO

Wetting behaviors can significantly affect the transport of energy and signal (E&S) through vapor, solid, and liquid interfaces, which has prompted increased interest in interfacial science and technology. E&S transmission can be achieved using electricity, light, and heat, which often accompany and interact with each other. Over the past decade, their distinctive transport phenomena during wetting processes have made significant contributions to various domains. However, few studies have analyzed the intricate relationship between wetting behavior and E&S transport. This review summarizes and discusses the mechanisms of electrical, light, and heat transmission at wetting interfaces to elucidate their respective scientific issues, technical characteristics, challenges, commonalities, and potential for technological convergence. The materials, structures, and devices involved in E&S transportation are also analyzed. Particularly, harnessing synergistic advantages in practical applications and constructing advanced, multifunctional, and highly efficient smart systems based on wetted interfaces is the aim to provide strategies.

17.
ACS Appl Mater Interfaces ; 16(28): 36272-36280, 2024 Jul 17.
Artigo em Inglês | MEDLINE | ID: mdl-38978170

RESUMO

Manipulating the crystallization of perovskite in thin films is essential for the fabrication of any thin-film-based devices. Fabricating tin-based perovskite films from solution poses difficulties because tin tends to crystallize faster than the commonly used lead perovskite. To achieve optimal device performance in solar cells, the preferred method involves depositing tin perovskite under inert conditions using dimethyl sulfoxide (DMSO), which effectively retards the formation of the tin-bromine network, which is crucial for perovskite assembly. We found that under ambient conditions, a DMSO-based tin perovskite salt solution resulted in the formation of a two-phase system, SnBr4(DMSO)2 and MABr, whereas a dimethylformamide-based solution resulted in the formation of vacancy-ordered double perovskite MA2SnBr6. Humidity is known to solvate MABr to form the solvated ions, and so we used the two-phase system for the application in moisture to electricity conversion. The importance of the presence of the scaffold can be seen with the negligible power output from the vacancy-ordered double perovskite obtained with MA2SnBr6. We have fabricated a device with two-phase system that can generate an open-circuit potential of 520 mV and a short-circuit current density of 30.625 µA/cm2 at 85% RH. Also, the device charges a 10 µF capacitor from 150 mV at 51% RH to 500 mV at 85% RH in 6 s at a rate of 52.5 mV/s. Moreover, the output can be scaled by connecting devices in series and parallel configurations. A 527 nm green LED was powered by connecting five devices in series at 75% RH. This indicates a potential for utilizing these moisture-to-electricity conversion devices in powering low-energy requirement devices.

18.
J Environ Econ Manage ; 124: 1-19, 2024 Mar.
Artigo em Inglês | MEDLINE | ID: mdl-39022448

RESUMO

I study battery electric vehicle (BEV) usage and ownership characteristics with fundamental implications for the electrification of passenger transportation. Using data covering the entire BEV population in New York, I quantify BEV mileage and electricity consumption and highlight the important role of vehicle utilization in contributing to real-world pollution damages and their spatial variation. I then study the factors influencing how much BEVs are driven with a focus on estimating the electricity price elasticity of BEV mileage. Understanding how drivers respond to these changes in operating costs may help align the social and private costs of BEV driving and illustrates how electric utilities may affect transportation outcomes in the future. I find a 10% increase in residential electricity prices reduces mileage by 1%, but responsiveness falls as public charging stations-where prices are often decoupled from electricity costs-become available.

19.
J Colloid Interface Sci ; 674: 1019-1024, 2024 Nov 15.
Artigo em Inglês | MEDLINE | ID: mdl-38968874

RESUMO

In response to the energy crisis caused by the exhaustion of fossil energy sources, as well as to combat global warming and achieve carbon neutrality, a sandwiched-structure fabric-based moisture-enabled electricity generator (SMEG) has been developed. Cotton fabric coated with MWCNT and PEDOT: PSS solution is used as the upper and bottom electrodes, while the acid-treated cotton fabric with coating PVA and HCl hydrogel electrolyte serves as the middle layer. A single SMEG can generate a maximum open-circuit voltage (Voc) of 0.44 V and a maximum short-circuit current (Isc) of 30 µA. When a drop of LiCl is dripped on one side of SMEGs, the maximum Voc and Isc increases to 0.57 V and 66 µA, respectively. The decline in output performance slows down when LiCl is applied. The Voc increases almost linearly in series and reaches 3.55 V when six SMEGs are connected, while the Isc increases linearly in parallel and reaches 204 µA when six SMEGs are connected. The maximum power density of a single SMEG yields 0.29 µW/cm2 with an external resistance of 1 kΩ. The series connection of six SMEGs successfully lit an LED and a calculator under ambient humidity conditions, demonstrating their potential application in small electronics.

20.
J Environ Manage ; 367: 121966, 2024 Sep.
Artigo em Inglês | MEDLINE | ID: mdl-39068783

RESUMO

In this study, Co3O4@MoS2 is prepared as anodic catalytic material for microbial fuel cells (MFCs). As the mass fraction of MoS2 is 20%, the best performance of Co3O4@MoS2 composite catalytic material is achieved, and the addition of MoS2 enhances both the electrical conductivity and catalytic performance of the composite catalyst. Through the structural characterization of Co3O4@MoS2 composite catalytic material, nanorod-like Co3O4 and lamellar MoS2 interweaved and stacked each other, and the agglomeration of Co3O4 is weakened. Among the four groups of single-chamber MFCs constructed, the Co3O4@MoS2-MFC shows the best power production performance with a maximum stable output voltage of to 539 mV and a maximum power density of up to 2221 mW/m2. Additionally, the ammonia nitrogen removal rate of the MFCs loaded with catalysts is enhanced by about 10% compared with the blank carbon cloth MFC. Overall, the findings suggest that Co3O4@MoS2 composite catalysts can significantly improve the performance of MFCs, making them more effective for both energy production and wastewater treatment.


Assuntos
Fontes de Energia Bioelétrica , Molibdênio , Molibdênio/química , Catálise , Dissulfetos/química , Cobalto/química , Óxidos/química , Eletrodos
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