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1.
Small ; : e2405577, 2024 Oct 02.
Artigo em Inglês | MEDLINE | ID: mdl-39359023

RESUMO

Since the inception of the concept of nanozymes, there has been a growing interest in the rational design and controllable synthesis of nanozymes with adjustable activities. In this study, onion-liked carbon (OLC) with remarkable peroxidase-like (POD) activity are developed through delicately controlling the sp2/sp3 configuration. The investigation reveals that enzymatic activity of OLC increases first and then decreases with the increased graphitic degree, with the highest activity observed at a moderate sp2/sp3 ratio of 17.17%. A series of experiments and theoretical calculations are conducted to elucidate the catalytic mechanism, and the structure-dependent activity is attributed to a synergistic effect of surface adsorption and electron transfer processes. The POD activity enables the OLC to catalyze the decomposition of H2O2, producing reactive oxygen species for eradicating Gram-positive and Gram-negative bacteria. Additionally, toxicity tests based on nematode and mouse models confirmed the excellent biocompatibility of OLC. Furthermore, the OLC exhibited antibacterial ability and promoted bacterial-infected wound healing in a mouse model. This work not only gives a deeper understanding of the structure-activity relationship and catalytic mechanism of carbon-based nanozymes, but also unveils a novel avenue for antibacterial therapy and wound healing applications.

2.
Plants (Basel) ; 13(17)2024 Sep 06.
Artigo em Inglês | MEDLINE | ID: mdl-39273983

RESUMO

The olive tree is crucial to the Mediterranean agricultural economy but faces significant threats from climate change and soil-borne pathogens like Verticillium dahliae. This study assesses the dual role of an onion extract formulation, rich in organosulfur compounds, as both biostimulant and antifungal agent. Research was conducted across three settings: a controlled climatic chamber with non-stressed olive trees; an experimental farm with olive trees under abiotic stress; and two commercial olive orchards affected by V. dahliae. Results showed that in the climatic chamber, onion extract significantly reduced MDA levels in olive leaves, with a more pronounced reduction observed when the extract was applied by irrigation compared to foliar spray. The treatment also increased root length by up to 37.1% compared to controls. In field trials, irrigation with onion extract increased the number of new shoots by 148% and the length of shoots by 53.5%. In commercial orchards, treated trees exhibited reduced MDA levels, lower V. dahliae density, and a 26.7% increase in fruit fat content. These findings suggest that the onion extract effectively reduces oxidative stress and pathogen colonization, while enhancing plant development and fruit fat content. This supports the use of the onion extract formulation as a promising, sustainable alternative to chemical treatments for improving olive crop resilience.

3.
ACS Appl Mater Interfaces ; 16(38): 51512-51520, 2024 Sep 25.
Artigo em Inglês | MEDLINE | ID: mdl-39269327

RESUMO

We report complex macrophase and microphase transitions of rigid amphiphiles with spherical Keggin molecular clusters as the solvophilic block and rod-like rigid oligofluorene (OF) as the solvophobic block in mixed solvents of water and polar organic solvent. By properly adjusting the solvent polarity, the amphiphiles are found to respond accordingly by self-assembling into multilayered incomplete onion-like structures (10-25 vol % THF), single-layered vesicular structures (60 vol % THF), and an unexpected macrophase separation in the middle (40-50 vol % THF), which is due to the anomalous trends in Keggin solubility as a result of the nature of TBA+ counterions. The rigidity of the OF block prevents the amphiphile from assembling by following the rule of packing parameters; instead, interdigitation among different rods leads to the formation of the solvophobic domain to achieve self-assembly. The incomplete onion structures are controlled by the interdigitation of rigid rods for the number of layers and the electrostatic interaction among Keggin head groups for the interlayer distance. When the degree of interdigitation becomes lower, the self-assembly process shows a trend that can be explained by the traditional rule of packing parameter. This study demonstrates the formation of different self-assembled structures by rigid amphiphiles and their transitions induced by solvent composition. The self-assembly (microphase separation) of rigid amphiphiles in a dilute solution could indeed represent a broad area containing complicated, uncharted rules.

4.
Foods ; 13(17)2024 Aug 27.
Artigo em Inglês | MEDLINE | ID: mdl-39272485

RESUMO

This study investigates the effect of daily consumption of a concentrated garlic and onion extract on COVID-19 symptoms among elderly nursing home residents. Volunteers consumed a daily capsule of the concentrated powder rich in organosulfur compounds over 36 weeks during lunch. The incidence and severity of COVID-19 symptoms between the treatment and control groups were compared, along with monitoring the safety of consumption, incidence of other diseases, and medicine usage. The treatment group showed a significant reduction in both the number and severity of COVID-19 symptoms compared to the control group, with no significant adverse effects observed. No significant reduction in symptom duration was detected. This study provides preliminary evidence that concentrated garlic and onion extract may aid in the treatment of COVID-19 among older adults. These findings suggest potential public health benefits, emphasizing the need for further research to explore the immunomodulatory properties of these natural compounds.

5.
Sci Rep ; 14(1): 20816, 2024 09 06.
Artigo em Inglês | MEDLINE | ID: mdl-39242593

RESUMO

The impact of premade beef patty (BBP) with red onion skin powder (OSP) at 0, 1, 2, and 3% levels on color, lipid, and protein oxidative stability, and infection degree of microorganisms during cold storage was investigated. The objective was to determine the effect of color by L*, a*, b*, and the content of MetMb. The inhibitory effect of OSP on the oxidation of lipid and protein was studied based on TBARS and the carbonyl content of protein in samples at different storage times. TVB-N content was used to characterize the degree of infection of microorganisms and their effect on meat quality. The results showed that the addition of OSP reduced the pH, L *, a*, and b * values of BBP, and improved the hardness, springiness, gumminess, and cohesiveness of BBP, but had no significant effect on the chewiness of BBP (p > 0.05). After 12 days of storage, the carbonyl group and TBARS content in the BBP supplemented with 3%OSP was significantly lower than that in the control group (p < 0.05). Furthermore, the addition of OSP significantly inhibited the TVB-N increase during beef patty storage. These results indicated that OSP has a good research prospect as a natural antioxidant or preservative.


Assuntos
Cor , Armazenamento de Alimentos , Cebolas , Oxirredução , Cebolas/química , Animais , Bovinos , Armazenamento de Alimentos/métodos , Pós , Lipídeos/química , Carne Vermelha/análise , Substâncias Reativas com Ácido Tiobarbitúrico/metabolismo , Substâncias Reativas com Ácido Tiobarbitúrico/análise , Temperatura Baixa , Conservação de Alimentos/métodos
6.
Microb Ecol ; 87(1): 115, 2024 Sep 13.
Artigo em Inglês | MEDLINE | ID: mdl-39266780

RESUMO

A significant number of microorganisms inhabit the intestinal tract or the body surface of insects. While the majority of research on insect microbiome interaction has mainly focused on bacteria, of late multiple studies have been acknowledging the importance of fungi and have started reporting the fungal communities as well. In this study, high-throughput sequencing was used to compare the diversity of intestinal fungi in Delia antiqua (Diptera: Anthomyiidae) at different growth stages, and effect of differential fungi between adjacent life stages on the growth and development of D. antiqua was investigated. The results showed that there were significant differences in the α and ß diversity of gut fungal communities between two adjacent growth stages. Among the dominant fungi, genera Penicillium and Meyerozyma and family Cordycipitaceae had higher abundances. Cordycipitaceae was mainly enriched in the pupal and adult (male and female) stages, Penicillium was mainly enriched in the pupal, 2nd instar and 3rd instar larval stages, and Meyerozyma was enriched in the pupal stage. Only three fungal species were found to differ between two adjacent growth stages. These three fungal species including Fusarium oxysporum, Meyerozyma guilliermondii and Penicillium roqueforti generally inhibited the growth and development of D. antiqua, with only P. roqueforti promoting the growth and development of female insects. This study will provide theoretical support for the search for new pathogenic microorganisms for other fly pests control and the development of new biological control strategies for fly pests.


Assuntos
Dípteros , Fungos , Microbioma Gastrointestinal , Larva , Animais , Dípteros/microbiologia , Dípteros/crescimento & desenvolvimento , Fungos/classificação , Fungos/isolamento & purificação , Fungos/genética , Larva/microbiologia , Larva/crescimento & desenvolvimento , Masculino , Feminino , Pupa/microbiologia , Pupa/crescimento & desenvolvimento , Biodiversidade , Estágios do Ciclo de Vida , Micobioma
7.
Nat Prod Res ; : 1-5, 2024 Aug 08.
Artigo em Inglês | MEDLINE | ID: mdl-39116426

RESUMO

Facile synthesis and characterisation of three natural compounds and their two synthetic analogues based on onion skin content were performed. Both OSE and 2,4,6-trihydroxyphenylglyoxylic acid was induced effect on cell proliferation during barley germination with a difference of approximately %4 compared to the control group.

8.
Front Microbiol ; 15: 1442912, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-39119140

RESUMO

Introduction: The application of mineral fertilizers deteriorates soil properties and affects crop yield and nutritional properties. However, plant growth-promoting microorganisms (PGPM- Serendipita indica, phosphorus solubilizing bacteria (PSB), and vesicular arbuscular mycorrhizae (VAM)) have great potential to reduce fertilizers and improve soil fertility, crop yield, and nutrient uptake and mitigate the environmental effect of mineral fertilizers. Material and methods: Hence, a field experiment was conducted involving nine treatments to evaluate the effects of PGPM along with 50% or 100% of the recommended dose of fertilizers on plant growth, soil fertility, nutrient uptake, and onion productivity. Results and discussion: Results indicated that 100% RDF combined with S. indica or PSB led to improved plant growth, and higher nutrient concentrations in both leaves and bulbs of onions compared to RDF alone. Moreover, the application of 100% RDF with S. indica increased total dry matter yield by 11.5% and 7.6% in the 2018-2019 and 2019-2020 seasons, respectively, compared to 100% RDF alone. This treatment also resulted in the highest nutrient uptake, with N uptake increasing by 6.9%-29.9%, P by 13.7%-21.7%, K by 20.0%-23.7%, and S by 18.1%-23.4%. Additionally, the combination of 100% RDF with S. indica inoculation led to a notable increase in bulb yield, with increments of 16.2% and 13.9% observed in 2018-2019 and 2019-2020, respectively, compared to 100% RDF alone. Similarly, the application of 100% RDF along with PSB inoculation resulted in an increase in bulb yield by 7.2% and 9.4% in the respective years. However, VAM did not exhibit satisfactory performance or improvements in the onion crop. Conclusion: Overall, the study suggests that combining 100% RDF with S. indica or PSB can enhance onion productivity and nutrient use efficiency. The present study may open a new avenue of PGPM application in enhancing onion yield and improving the bulb quality as well as soil health. However, field trials across different regions and soil types are necessary to validate these findings for practical adoption by farmers.

9.
Heliyon ; 10(15): e35485, 2024 Aug 15.
Artigo em Inglês | MEDLINE | ID: mdl-39166064

RESUMO

Biochar production from unconventional biomass, specifically onion peel (OP) and chicken feathers (CF), was investigated in this study. Two distinct biochars were produced by doping each biomass with the other, with the aim of exploring the synergistic effects of different feedstock combinations on biochar properties. The biochar production process was conducted using a retort heating method and characterized using several techniques. A yield of 36 % was obtained for OP-doped biochar (OP92CF8-BC) and 23 % for CF-doped biochar (F92OP8-BC). Fourier Transform Infrared Spectroscopy analysis revealed characteristic functional groups from cellulose, hemicellulose, and lignin in OP92CF8-BC, while CF92OP8-BC displayed keratin-related peaks. Scanning Electron Microscopy imaging showed surface morphology differences, with OP92CF8-BC exhibiting a rougher and more porous structure compared to CF92OP8-BC. Energy-Dispersive X-ray Spectroscopy analysis confirmed the elemental composition, with OP92CF8-BC having higher carbon, calcium, and sulfur contents and CF92OP8-BC having higher nitrogen and oxygen contents. The biochar had specific surface areas of 342.4 and 200.80 m2/g for OP92CF8-BC and CF92OP8-BC, respectively. According to the results, using biochar treatments-more especially, CF92OP8-BC-can significantly enhance cob weight. This could be good for agricultural productivity. These findings highlight the influence of feedstock composition on the properties of biochar and provide insights for its potential applications in soil amendment and pollutant removal.

10.
Int J Environ Health Res ; : 1-12, 2024 Jul 31.
Artigo em Inglês | MEDLINE | ID: mdl-39086172

RESUMO

Onions contain valuable phytochemical compounds, including quercetin derivatives. This study explores the potential of onion extract as a natural additive in chicken patties. The optimized conditions involved sonication at 80% for 5 min with a 75% ethanol concentration. The onion extract exhibited total phenolic and flavonoid compound values of 255.63 mg GAE g-1 DR and 196.87 mg QE g-1 DR, respectively. The antioxidant activity of the onion extract was characterized by an IC50 of 12.74 µg/mL. This onion extract was dominated by quercetin derivatives (quercetin 4'-O-ß-glycoside and quercetin-3-O-ß-glycoside and quercetin-3,4'-O-ß-diglycoside). Chicken patties treated with 2% onion extract exhibited superior pH stability, lowest thiobarbituric acid reactive substances level (0.40 mg/kg) and peroxide index (0.77 mEq O2/kg meat) and maintained color stability. Comparative analysis with BHT demonstrated the efficacy of onion extract in reducing lipid oxidation. These findings highlight the potential of a 2% onion extract as effective ingredient for enhancing the quality of chicken products.

11.
Neuropathology ; 2024 Aug 06.
Artigo em Inglês | MEDLINE | ID: mdl-39105360

RESUMO

Eosinophilic angiocentric fibrosis (EAF) is a rare, benign fibroinflammatory condition primarily affecting the sinonasal and upper respiratory tract, with a few cases reported beyond these regions. Primary intracranial EAF is rare. To date, only one case of intracranial EAF has been reported; ours is the second. This case report presents a case of EAF in a 55-year-old man, initially misdiagnosed as meningioma based on clinical and radiological features. The patient complained of a persistent dull headache for six months without associated neurological symptoms. Brain magnetic resonance imaging revealed a dural-based lesion with characteristics suggestive of meningioma. However, histopathological examination post-surgical resection revealed a nodular vascular lesion with concentric angiocentric fibrosis, a distinctive onion skin pattern, and an inflammatory infiltrate rich in eosinophils, plasma cells, and histiocytes. Immunohistochemistry ruled out IgG4-related disease, and other systemic disorders were ruled out based on combined clinical and histological features. This case underscores the need for considering EAF in the differential diagnosis of dural-based lesions. Awareness of its potential mimicking of meningioma is crucial for accurate diagnosis and appropriate management, emphasizing the importance of histopathological examination in challenging cases.

12.
Heliyon ; 10(14): e34749, 2024 Jul 30.
Artigo em Inglês | MEDLINE | ID: mdl-39130470

RESUMO

Climate change is an imminent threat, particularly affecting agricultural productivity, which relies heavily on weather conditions. Understanding the specific impacts of climate change on key crops is crucial for developing effective adaptation strategies to ensure food security. The growth patterns of onions and garlic were observed at over ten different locations in South Korea, and the yield data from the past 40 years were analyzed. The yield was significantly correlated with temperature and strongly affected by the frequent and unexpected patterns of precipitation. The increase in mean temperature during winter and the spatial and temporal concentration of precipitation are expected to be the most influential factors for Allium crop production in the future. In addition, the yields of onions and garlic can serve as good indicators for predicting the impacts of weather on agricultural productivity, given their extended cultivation periods and significant correlations with temperature and precipitation. As climate change scenarios become available, the results of this study can serve as a basis for predicting changes in agricultural production in the future and identifying opportunities to adapt cultivation systems for food security.

13.
Heliyon ; 10(15): e35033, 2024 Aug 15.
Artigo em Inglês | MEDLINE | ID: mdl-39157387

RESUMO

This study aimed to determine residues of organochlorine pesticides (OCPs) in tomato and onion samples collected from selected markets in the Jimma zone. A QuEChERS (Quick, Easy, Cheap, Effective, Rugged, and Safe) method was used for sample preparation followed by gas chromatography-mass spectrometry (GC-MS) for OCPs analysis. The method used showed wide linear ranges from 5-50 µg/L for all eight pesticides, with R2 values ≥ 0.992. The LOD values for the pesticides tested ranged from 0.14 µg/kg for p,p'-DDE to 2.40 µg/kg for p,p-DDT. LOQ values ranged from 0.46 µg/kg for p,p-DDE to 8.32 µg/kg for p,p'-DDT. The recoveries ranged from 74.84 - 109.45 % except for ß-BHC (67.82 %). While most of the OCPs in the onion and tomato samples met European Union (EU) and Codex standards, some exceeded the limits. Methoxychlor and p,p'-DDT in onions, and methoxychlor, p,p'-DDT, α-BHC, and δ-BHC in some tomatoes, were detected above the permitted levels. Specific OCPs were not detected in some samples including aldrin in Meki Tomato (Mek-T), γ-chlordane in Agaro Tomato (Ag-T), and p,p'-DDE in Gera Tomato (Ger-T). The residual concentrations of OCPs varied among the samples. Among tomatoes, Gera had the highest percentage of detected OCPs contaminants (37 %), followed by Agaro (34.34 %) and Meki (28.55 %). Similarly, Sire onion (SrO) had the highest percentage of detected OCPs (28 %) compared to Minjer (25.16 %), Shewa Robit (25.10 %), and Sudan onion (22.25 %). In conclusion, most tomato and onion samples analyzed in this study contained OCP residues highlighting the importance of conducting a consumer health risk assessment.

14.
Nutrients ; 16(16)2024 Aug 22.
Artigo em Inglês | MEDLINE | ID: mdl-39203947

RESUMO

Hypercholesterolemia plays a pivotal role in the development and progression of cardiovascular diseases, and its prevention seems to be a crucial healthcare strategy to ameliorate these conditions. Subjects with mild hypercholesterolemia are frequently advised against using cholesterol-lowering drugs due to potential side effects, with an emphasis instead on prioritizing dietary adjustments and lifestyle modifications as the primary strategy. In this context, the use of dietary supplements based on medicinal plants may be recommended as a complementary approach to managing elevated cholesterol levels. The aim of this study was to investigate the safety and potential therapeutic effectiveness of a standardized formulation containing extracts from garlic and onions in addressing the health concerns of individuals with slightly elevated cholesterol levels. A controlled, randomized, double-blind, two parallel-group study was conducted over 8 weeks, with clinical visits scheduled at baseline, weeks 2 and 4, as well as at the end of the study. The results revealed significant reductions in both low-density lipoprotein cholesterol and total cholesterol levels among participants who received the extract. Additionally, improvements in blood pressure, as well as in oxidative and inflammatory markers were observed, thus suggesting its potential as a valuable therapeutic intervention for managing mild hypercholesterolemia.


Assuntos
LDL-Colesterol , Suplementos Nutricionais , Alho , Hipercolesterolemia , Cebolas , Extratos Vegetais , Humanos , Alho/química , Extratos Vegetais/farmacologia , Masculino , Método Duplo-Cego , Feminino , Adulto , Hipercolesterolemia/tratamento farmacológico , Hipercolesterolemia/sangue , LDL-Colesterol/sangue , Pessoa de Meia-Idade , Cebolas/química , Voluntários Saudáveis , Anticolesterolemiantes , Pressão Sanguínea/efeitos dos fármacos , Biomarcadores/sangue
15.
Nanomaterials (Basel) ; 14(14)2024 Jul 18.
Artigo em Inglês | MEDLINE | ID: mdl-39057898

RESUMO

Poly(3,4-ethylenedioxythiophene) (PEDOT) and PEDOT-functionalized carbon nanoparticles (f-CNPs) were synthesized by in situ chemical oxidative polymerization and pyrolysis methods. f-CNP-PEDOT nanocomposites were prepared by varying the concentration of PEDOT from 1 to 20% by weight (i.e., 1, 2.5, 5, 10, and 20 wt%). Several characterization techniques, such as field-emission scanning electron microscopy (FESEM), attenuated total reflectance-Fourier transform infrared (ATR-FTIR), X-ray diffraction (XRD), N2 Brunauer-Emmett-Teller (BET) and Barrett-Joyner-Halenda (BJH) analyses, as well as cyclic voltammetry (CV), galvanostatic charge discharge (GCD), and electrochemical impedance spectroscopy (EIS), were applied to investigate the morphology, the crystalline structure, the N2 adsorption/desorption capability, as well as the electrochemical properties of these new synthesized nanocomposite materials. FESEM analysis showed that these nanocomposites have defined porous structures, and BET surface area analysis showed that the standalone f-CNP exhibited the largest surface area of 801.6 m2/g, whereas the f-CNP-PEDOT with 20 wt% exhibited the smallest surface area of 116 m2/g. The BJH method showed that the nanocomposites were predominantly mesoporous. CV, GCD, and EIS measurements showed that f-CNP functionalized with 5 wt% PEDOT had a higher capacitive performance compared to the individual f-CNPs and PEDOT constituents, exhibiting an extraordinary specific capacitance of 258.7 F/g, at a current density of 0.25 A/g, due to the combined advantage of enhanced electrochemical activity induced by PEDOT doping, and highly developed porosity of f-CNPs. Symmetric aqueous supercapacitor devices were fabricated using the optimized f-CNP-PEDOT doped with 5 wt% of PEDOT as active material, exhibiting a high capacitance of 96.7 F/g at 1.4 V, holding practically their full charge, after 10,000 charge-discharge cycles at 2 A/g, thus providing the highest electrical electrodes performance. Hereafter, this work paves the way for the potential use of f-CNP-PEDOT nanocomposites in the development of high-energy-density supercapacitors.

16.
Data Brief ; 55: 110679, 2024 Aug.
Artigo em Inglês | MEDLINE | ID: mdl-39044903

RESUMO

Digital image datasets for Precision Agriculture (PA) still need to be available. Many problems in this field of science have been studied to find solutions, such as detecting weeds, counting fruits and trees, and detecting diseases and pests, among others. One of the main fields of research in PA is detecting different crop types with aerial images. Crop detection is vital in PA to establish crop inventories, planting areas, and crop yields and to have information available for food markets and public entities that provide technical help to small farmers. This work proposes public access to a digital image dataset for detecting green onion and foliage flower crops located in the rural area of Medellín City - Colombia. This dataset consists of 245 images with their respective labels: green onion (Allium fistulosum), foliage flowers (Solidago Canadensis and Aster divaricatus), and non-crop areas prepared for planting. A total of 4315 instances were obtained, which were divided into subsets for training, validation, and testing. The classes in the images were labeled with the polygon method, which allows training machine learning algorithms for detection using bounding boxes or segmentation in the COCO format.

17.
Luminescence ; 39(7): e4817, 2024 Jul.
Artigo em Inglês | MEDLINE | ID: mdl-39019841

RESUMO

Alternate antibiotics developed through the involvement of nanomaterials are gaining interest due to their economical and lower toxicity concerns. A newly developed biopolymer-based polyvinylpyrrolidone/zinc oxide (PVP/ZnO) nanocomposite (NCs) was efficiently synthesized by an environment-friendly approach, utilizing onion and garlic peel extract as a bio-surfactant, zinc acetate as the source, PVP as the stabilizing agent, and sodium hydroxide as the precipitant. Fourier transform infrared spectroscopy (FT-IR) and X-ray diffraction (XRD) investigations verified the crystalline properties of ZnO, PVP, and PVP/ZnO-based NCs. The structure of the biopolymer-linked ZnO particles interpolated inside the PVP array was seen to have a layered and flaky structure, as validated by field emission scanning electron microscopy (FE-SEM) analysis, which revealed its occurrence in the nanometer range. The XRD examination verified that the surface topographical image of PVP/ZnO NCs had an average thickness of 21 nm. The PVP/ZnO nanocrystals demonstrated exceptional photocatalytic efficacy, with a breakdown rate of 88% and almost 92% for the methylene blue dye. Therefore, the PVP/ZnO matrix exhibits superior antibacterial activity compared to other extracts, resulting in greater microbial suppression. The results above indicate that the ZnO-intercalated PVP array has a stronger reinforcing effect than other components. Hence, PVP/ZnO nanocrystals exhibit enormous potential as a favorable substance for environmental and biomedical intentions.


Assuntos
Antibacterianos , Nanocompostos , Processos Fotoquímicos , Povidona , Óxido de Zinco , Óxido de Zinco/química , Óxido de Zinco/farmacologia , Povidona/química , Nanocompostos/química , Catálise , Antibacterianos/farmacologia , Antibacterianos/química , Antibacterianos/síntese química , Testes de Sensibilidade Microbiana , Luminescência , Tamanho da Partícula , Substâncias Luminescentes/química , Substâncias Luminescentes/síntese química , Azul de Metileno/química
18.
J Chromatogr A ; 1730: 465151, 2024 Aug 16.
Artigo em Inglês | MEDLINE | ID: mdl-39002509

RESUMO

Onion peels (OP) are byproduct of food processing industries that poses economic and environmental challenges. However, being rich source of bioactive compounds like Quercetin (Qt), a polyphenolic antioxidant with potential health benefits, harnessing value from such waste can imbibe sustainable practices and protect environment. With this view, the present study targets selective recovery of Qt from OP waste using rationally designed molecularly imprinted polymer (MIP). Density Functional Theory (DFT) was used for the theoretical selection of the best conformer of Qt (template), methacrylic acid (MAA) as functional monomer, ratio of Qt-MAA for getting stable pre-polymerization complex, and to avoid hit and trial experiments. The theoretical results were validated experimentally by synthesizing MIP/ control polymer (NIP) using MAA as functional monomer, EGDMA as a cross-linker and AIBN as initiator. Synthesized MIP/NIP were characterized using various characterization techniques to confirm successful imprinting. Prepared MIP and NIP could effectively rebind the Qt molecule with binding capacity of 46.67 and 20.89 mg g-1 respectively. Furthermore, synthesized MIP could selectively recover 62.81 % of Qt from 1 g of dry onion peel powder. This study can be effectually used for sustainable recovery of Qt in large scale for various foods, cosmetic and pharmaceutical applications.


Assuntos
Polímeros Molecularmente Impressos , Cebolas , Quercetina , Quercetina/química , Quercetina/isolamento & purificação , Cebolas/química , Polímeros Molecularmente Impressos/química , Impressão Molecular , Resíduos Sólidos/análise , Teoria da Densidade Funcional , Extração em Fase Sólida/métodos , Antioxidantes/química , Antioxidantes/isolamento & purificação , Metacrilatos/química , Polímeros/química , Cromatografia Líquida de Alta Pressão
19.
Front Nutr ; 11: 1350534, 2024.
Artigo em Inglês | MEDLINE | ID: mdl-38962447

RESUMO

Allium species are among the most widely cultivated vegetables for centuries for their positive effects on human health and their variety of uses in food preparation and cooking. Preparation and cooking processes create chemical changes that can affect the concentration and bioavailability of bioactive molecules. Understanding the changes in bioactive compounds and bioactive activities in Allium vegetables resulting from preparation and cooking processes is essential for better retention of these compounds and better utilization of their health benefits. This study aimed to investigate the effects of different preparation and cooking processes on the bioactive molecules of Allium vegetables. This review concludes that bioactive compounds in Allium vegetables are affected by each preparation and cooking process depending on variables including method, time, temperature. Owing to differences in the matrix and structure of the plant, preparation and cooking processes show different results on bioactive compounds and bioactive activities for different vegetables. Continued research is needed to help fill gaps in current knowledge, such as the optimal preparation and cooking processes for each Allium vegetable.

20.
J Econ Entomol ; 2024 Jul 19.
Artigo em Inglês | MEDLINE | ID: mdl-39028319

RESUMO

Onion thrips, Thrips tabaci Lindeman, is a global pest of onion crops, causing substantial economic damage by diminishing bulb yields and transmitting plant pathogens. Insecticides are used to manage T. tabaci infestations with control decisions traditionally based on action thresholds that require visually counting thrips on a fixed, predetermined number of onion plants per field. However, this approach for treatment decisions is inefficient when thrips populations are well above or below the action threshold. The aim of this research was to develop a sequential sampling plan that would provide a rapid and reliable classification of thrips populations in commercial onion fields above or below prespecified management thresholds. The study was conducted in a total of 24 commercial onion fields in New York in 2021 and 2022. Taylor's power law and Wald's Sequential Probability Ratio Test were used in concert to develop each sampling plan. Simulated and historical field data of thrips populations were used to further validate the efficacy of each sampling plan. Results demonstrated the sequential sampling plan required an average of 78% fewer samples to make a control decision compared with the traditional fixed-sampling approach. Treatment decisions were reached in 72% of cases after inspecting only 10 plants, while only 6% of the cases required examining more than 25 plants. Comparisons with fixed-sample sizes ranging from 23 to 68 plants revealed a 96% agreement in decision-making and a 78% reduction in sampling effort when using the sequential sampling plans.

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