Terpolymer Donor with Inside Alkyl Substituents on Thiophene π-Bridges toward Thiazolothiazole A2 -Unit Enables 18.21% Efficiency of Polymer Solar Cells.

PM6 is a widely used D-A copolymer donor in the polymer solar cells (PSCs). Incorporating second electron-withdrawing (A2 ) units into PM6 backbone by ternary D-A1 -D-A2 random copolymerization strategy is an effective approach to further improve its photovoltaic performance. Here, the authors synthesize the PM6-based terpolymers by introducing thiazolothiazole as the A2 units connecting with thiophene π-bridges attaching alkyl substituent towards the A2 unit (PMT-CT) or towards D-unit (PMT-FT), and study the effect of the alkyl substituent position on the photovoltaic performance of them. Two terpolymers PMT-FT-10 and PMT-CT-10 are obtained by incorporating 10% A2 units in the terpolymers. The film of PMT-CT-10 shows slightly up-shifted highest occupied molecular orbital (HOMO) energy levels while better co-planar structure than that of PMT-FT-10. Meanwhile, the PMT-CT-10:Y6 blend film exhibits better molecular packing properties, more proper phase separation and more balanced hole and electron mobilities, which are beneficial to more efficient exciton dissociation, efficient charge transport and weaker bimolecular recombination. Consequently, the PMT-CT-10 based PSCs obtain the highest power conversion efficiency of 18.21%. The results indicate that side chain position on the thiophene π-bridges influence the device performance of the terpolymer donors, and PMT-CT-10 is a high efficiency polymer donor for the PSCs.

Effects of the Selective Alkoxy Side Chain Position in Quinoxaline-Based Polymer Acceptors on the Performance of All-Polymer Solar Cells.

The effects of the position of alkoxy side chains in quinoxaline (Qx)-based polymer acceptors (PAs) on the characteristics of materials and the device parameters of all-polymer solar cells (all-PSCs) are investigated. The alkoxy side chains are selectively located at the meta, para, and both positions in pendant benzenes of Qx units, constructing PAs denoted as P(QxCN-T2)-m, P(QxCN-T2)-p, and P(QxCN-T2), respectively. Among them, P(QxCN-T2)-m exhibits the deepest energy levels owing to the enhanced electron-withdrawing effect of meta-positioned alkoxy chains, which is in contrast to P(QxCN-T2)-p where para-positioned alkoxy chains have an electron-donating property. In addition, the meta-positioned alkoxy chains induce good electron-conducting pathways, while the para-positioned ones significantly interrupt crystallization and intermolecular interactions between the conjugated backbones. Thus, when the PAs are applied to all-PSCs, a power conversion efficiency (PCE) of 5.07% is attained in the device using P(QxCN-T2)-m with efficient exciton dissociation and good electron-transporting ability. On the contrary, the P(QxCN-T2)-p-based counterpart has a PCE of only 1.62%. These results demonstrate that introducing alkoxy side chains at a proper location in the Qx-based PAs is crucial for their application to all-PSCs.