Simultaneous extraction of tocochromanols and flavan-3-ols from the grape seeds: Analytical and industrial aspects.

Grape processing generates large amounts of by-products, including seeds rich in hydrophilic and lipophilic antioxidants. This study demonstrates, for the first time, that subjecting grape seeds to a single ultrasound-assisted extraction (UAE) with aqueous ethanolic solutions yields both flavan-3-ols and tocochromanols in the final extract. Notably, the water content in ethanol significantly influences the extractability of tocochromanols more than flavan-3-ols. Solid-to-solvent ratios of 1:50 to 1:2 were tested for both analytical and industrial applications. A sustainable analytical approach for recovering flavan-3-ols and tocochromanols using 60% and 96.4% ethanol extractions was validated and employed to profile nineteen genotypes of lesser-studied interspecific grape crosses (Vitis spp.). Different genotypes showed a wide range of concentrations of tocopherols (1.6-6.3 mg/100 g), tocotrienols (1.0-17.4 mg/100 g), and flavan-3-ols (861-9994 mg/100 g). This indicated that the genetic background and maturity of the plant material are crucial factors from an industrial perspective due to the initial concentration of bioactive compounds. Finally, the study also discussed the fundamental aspects of hydrophobic antioxidant extractability from the lipid matrix with aqueous ethanol solutions and the limitations of the workflow, such as the non-extractable tocochromanols and their esters and the losses of these lipophilic antioxidants during extraction.

Evaluating complementaries among urban water, energy, infrastructure, and social Sustainable Development Goals in China.

Urban areas' performance in water, energy, infrastructure, and socio-economic sectors is intertwined and measurable through Sustainable Development Goals (SDGs) 6-13. Effective synergy among these is critical for sustainability. This study constructs an indicator framework that reflects progress towards these urban SDGs in China. Findings indicate underperformance in SDGs 8-11, suggesting the need for transformative actions. Through network analysis, the research reveals complementarities among these SDGs. Notably, the SDG space divides into socio-economic and ecological clusters, with SDG 6 (Clean Water and Sanitation) central to both. Additionally, SDG 8 (Decent Work and Economic Growth) and SDG 9 (Industry, Innovation, and Infrastructure) act as bridges, while greater synergies exist between SDG 12 (Responsible Consumption and Production) and SDG 13 (Climate Action). An in-depth view at the indicator-level shows a core-periphery structure, emphasizing indicators like SDG 6.2 (Wastewater Treatment Rate) and SDG 6.6 (Recycled Water Production Capacity per capita) as pivotal. This study confirms the urban SDG space's stability and predictiveness, underscoring its value in steering well-aligned policy decisions for sustainable growth.

Micro-bacterial assessment of disposable gowns with a focus on green endoscopy in gastrointestinal endoscopy procedures: A Japanese pilot study for healthcare waste reduction.

Objective: This study aimed to implement green endoscopy through the microbiological assessment of gowning techniques during endoscopy to reduce carbon emissions and separate medical waste. Methods: Twenty-five patients who performed esophagogastroduodenoscopy from March to May 2024 were included in this study. Four sections of the isolation gowns (anterior, posterior, right, and left) were cut into 2 cm2 after endoscopy, and the rate of microbial contamination was examined using the stamp method. Results: The endoscopic examination time was 8 min (6-12), and endoscopy was performed by 10 expert endoscopists, six endoscopists, and nine residents. The overall isolation gown contamination rate was 56%, with 25%, 20.8%, 20.8%, and 33.3% in the front, back, as well as right and left arms, respectively. The rates of isolation gown contamination rates in the expert endoscopists, endoscopists, and residents groups were 30%, 50%, and 77.8%, respectively, with a higher rate in the residents group. Regardless of the physician's performance, bacterial detection was consistently higher in the left arm (42.9% vs. 40% vs. 25%; p = 0.093). The detected bacteria comprised 58% Gram-positive and 42% Gram-negative organisms, including those from tap water used for endoscopy bacteria and obtained from the participant's skin or mouth. No pathogenic organisms were detected. Conclusions: The bacteria detected in disposable gowns after gastrointestinal endoscopy were non-pathogenic. Thus, our findings suggest that changing all personal protective equipment of respective endoscopes might not be essential. We advocate for green endoscopy to achieve sustainable development goals and reduce medical waste.

Optimizing sustainable development in arid river basins: A multi-objective approach to balancing water, energy, economy, carbon and ecology nexus.

The ongoing water crisis poses significant threats to the socioeconomic sustainability and ecological security of arid and semi-arid river basins. Achieving Sustainable Development Goals (SDGs) within a complex socio-ecological nexus requires effective and balanced resource management. However, due to the intricate interactions between human societies and environmental systems, the tradeoffs and synergies of different SDGs remain unclear, posing a substantial challenge for collaborative management of natural resources. Here we introduce a gray fractional multi-objective optimization (GFMOP) model to balance multi-dimensional SDGs through a novel water-energy-economy-carbon-ecology nexus perspective. The model was applied to a typical arid river basin in Northwest China, where thirty-two scenarios were explored, considering factors such as shared socioeconomic pathways, carbon removal rates, water conveyance efficiencies, and ecological requirements. The results reveal a strong tradeoff between marginal benefit and carbon emission intensity, indicating that improving the economic efficiency of water use can simultaneously reduce emissions and protect the environment. Given the immense power generation potential, wind power development should be prioritized in the future, with its share in the energy structure projected to increase to 23.3% by 2060. Furthermore, promoting carbon capture technologies and expanding grassland coverage are recommended to achieve regional carbon neutrality, contributing 39.5% and 49.1% to carbon absorption during 2021-2060, respectively. Compared with traditional single-objective models, GFMOP demonstrates a superiority in uncovering interrelationships among multiple SDGs and identifying compromised alternatives within the compound socio-ecological nexus. The model also provides detailed strategies for resource allocation and pollutant control, offering valuable guidance to policymakers and stakeholders in pursuing sustainable and harmonious watershed management.

The Grenada Learning and Memory Scale: Psychometric features and normative data in Caribbean preschool children.

OBJECTIVE: Neuropsychological assessment of preschool children is essential for early detection of delays and referral for intervention prior to school entry. This is especially pertinent in low- and middle-income countries (LMICs), which are disproportionately impacted by micronutrient deficiencies and teratogenic exposures. The Grenada Learning and Memory Scale (GLAMS) was created for use in limited resource settings and includes a shopping list and face-name association test. Here, we present psychometric and normative data for the GLAMS in a Grenadian preschool sample. METHODS: Typically developing children between 36 and 72 months of age, primarily English speaking, were recruited from public preschools in Grenada. Trained Early Childhood Assessors administered the GLAMS and NEPSY-II in schools, homes, and clinics. GLAMS score distributions, reliability, and convergent/divergent validity against NEPSY-II were evaluated. RESULTS: The sample consisted of 400 children (190 males, 210 females). GLAMS internal consistency, inter-rater agreement, and test-retest reliability were acceptable. Principal components analysis revealed two latent factors, aligned with expected verbal/visual memory constructs. A female advantage was observed in verbal memory. Moderate age effects were observed on list learning/recall and small age effects on face-name learning/recall. All GLAMS subtests were correlated with NEPSY-II Sentence Repetition, supporting convergent validity with a measure of verbal working memory. CONCLUSIONS: The GLAMS is a psychometrically sound measure of learning and memory in Grenadian preschool children. Further adaptation and scale-up to global LMICs are recommended.

Light-Driven Site-Selective Glycosylation of Native Carbohydrates.

Carbohydrates constitute the largest source of biomass on Earth, but their synthetic modification is highly challenging due to their high content of oxygen functionalities. The site- and stereoselective modification of native sugars is a definitive goal of glycochemistry research. Recent efforts to bypass the need for protecting groups, leveraging selective activation through photochemical mechanisms for site-selective C-C bond formation from native sugars, are likely to largely impact all glycochemistry-related areas. Davis, Koh, and co-workers have recently presented their use of photocatalysis to develop a "cap and glycosylate" approach for the site- and stereoselective C-glycosylation of native sugars. The modernization of a direct radical functionalization of in situ formed thioglycoside using photocatalysis was used in the synthetic manipulation of unprotected carbohydrates. This allowed reaching complex saccharides, and post-translational modification of proteins.

Mechanical Properties of 3D Printed Parts and Their Injection Molded Alternatives Subjected to Environmental Aging.

Additive manufacturing is the technology used in medical, industrial, or lifestyle applications. The scientific literature include works reporting various manufacturing parameters' influence on changes in additive manufacturing components' mechanical behavior, especially with fused filament fabrication (FFF). The changes in mechanical strength and toughness of FFF compared to injection molding parts were studied. In the study, the FFF and injection molded parts were aged in buffered saline solution in temperature of 37°C. The results show that by differentiating the orientation of the fibers during fabricating, it is possible to reach strength values similar to injection molded parts. Therefore, it was reported that the mechanical strength and toughness changed significantly after aging, and the FFF components lost strength more quickly than their injected alternatives. The research results can be useful during the fabrication of mechanically stable and biodegradable components, which can be more easily recycled than their injected alternatives when used with warmer temperatures and humidity. This article completes the present state of the art on the problem of environmental aging of parts produced from biodegradable materials. Especially, the research was related to the multilayer laminate structure.

Transition in action: toward a social theory of the governance of transitions.

This article explores how a re-interpretation of the socio-technical, socio-ecological and transition design approaches to transition from the point of view of Niklas Luhmann's general systems theory of society. The need to understand and promote changes that include a technological and ecological dimension has led to different approaches, such as socio-technical or socio-environmental approaches, to incorporate links with society. While these approaches often include sociological insights, they rarely offer a general understanding of how these are embedded into society. We need a new environmental sociology that helps catalyze change processes with a collectively reorganized society, empowering more radically transformative actions to change the current structures and processes that have led us to where we are today. The article offers a cross-sectional look at the socio-ecological and socio-technical systems literature, specifically for what concerns their understanding of the 'systems' in transition and how they can be governed, and re-interpret it from the theoretical lens of the deep sociological knowledge, which refers to the profound understanding of social systems and their dynamics, embedded in Luhmann's theory of social systems. From here, we suggest the second-order coupling for a sociologically grounded understanding of the interactions that comprise socio-ecological and socio-technical systems, heterogeneous and almost self-organizing assemblies of social, technical, and natural elements and processes. At the same time, third-order couplings are analyzed, focused on governance, relationships between operations, and structures mediated by a deliberate attempt to ensure coherence and coordination against the autonomy and heterogeneity of socio-techno-ecological systems. Therefore, this manuscript offers a deeper conceptual and methodological understanding of socio-techno-ecological couplings and systems in the context of sustainability transformation and gives insights into its governance.

Linkages between Soil Security and One Health: implications for the 2030 Sustainable Development Goals.

Soil provides multiple and diverse functions (e.g., the provision of food and the regulation of carbon), which underpin the health of animals, humans, the environment and the planet. However, the world's soils face existential challenges. To this end, the concept of Soil Security was developed, compelled to: "maintain and improve soils worldwide so that they can continue to provide food, fiber and fresh water, contribute to energy and climate sustainability and help to maintain biodiversity and the overall protection of ecosystem goods and services." In parallel, the concept of One Health likewise works across the human-animal-environment interface, highly relevant for the goals of Soil Security. In this review, we evaluated the roles which both the Soil Security and One Health concepts have served in the literature between 2012 and 2023 and explore the potential linkages between both concepts. We outline that both concepts are used in disparate fields, despite considerable overlap in aims and objectives. We highlight the Soil Health concept as a potential connector between Soil Security and One Health. Overall, we argue that both Soil Security and One Health are highly complementary fields of scientific inquiry with solid leverage for translation into policy and practice. However, there is a need to define One Health dimensions, as has been done for Soil Security. As such, we proffer five measurable dimensions for One Health, the "5Cs"-Capacity, Condition, Capital, Connectivity and Codification-to allow for an overall measure of One Health. Finally, we advocate for a biosphere-focused framework to collectively make progress toward the 2030 Sustainable Development Goals and other global existential challenges.

Assessing the nonlinear impact of green space exposure on psychological stress perception using machine learning and street view images.

Introduction: Urban green space (GS) exposure is recognized as a nature-based strategy for addressing urban challenges. However, the stress relieving effects and mechanisms of GS exposure are yet to be fully explored. The development of machine learning and street view images offers a method for large-scale measurement and precise empirical analysis. Methods: This study focuses on the central area of Shanghai, examining the complex effects of GS exposure on psychological stress perception. By constructing a multidimensional psychological stress perception scale and integrating machine learning algorithms with extensive street view images data, we successfully developed a framework for measuring urban stress perception. Using the scores from the psychological stress perception scale provided by volunteers as labeled data, we predicted the psychological stress perception in Shanghai's central urban area through the Support Vector Machine (SVM) algorithm. Additionally, this study employed the interpretable machine learning model eXtreme Gradient Boosting (XGBoost) algorithm to reveal the nonlinear relationship between GS exposure and residents' psychological stress. Results: Results indicate that the GS exposure in central Shanghai is generally low, with significant spatial heterogeneity. GS exposure has a positive impact on reducing residents' psychological stress. However, this effect has a threshold; when GS exposure exceeds 0.35, its impact on stress perception gradually diminishes. Discussion: We recommend combining the threshold of stress perception with GS exposure to identify urban spaces, thereby guiding precise strategies for enhancing GS. This research not only demonstrates the complex mitigating effect of GS exposure on psychological stress perception but also emphasizes the importance of considering the "dose-effect" of it in urban planning and construction. Based on open-source data, the framework and methods developed in this study have the potential to be applied in different urban environments, thus providing more comprehensive support for future urban planning.

Ecology and Diversity of Arbuscular Mycorrhizal Fungi (AMF) in Rice (Oryza sativa L.) in South India: An Ecological Analysis of Factors Influencing AMF in Rice Fields.

AIMS: This study examined the diversity of arbuscular mycorrhizal fungi (AMF), mean spore density (MSD), and root colonization in relation to factors such as agroclimatic zones, rice varieties, soil types, and rice varieties in paddy fields of South India. The aim was to understand how these factors influence AMF, facilitating their effective use as a biological tool in agriculture. METHODS AND RESULTS: AMF were identified through light microscopy of spores, while MSD and percentage-root-length colonization (PRLC) were measured using standard methods. Correlation and principal component analyses were performed to explore the interrelationships between AMF characteristics and various environmental, soil, and plant variables. Sixteen AMF species were identified across 29 rice varieties from three agroclimatic zones, six soil orders, and 18 soil series over two seasons. Notably, 70% of chemicalized rice fields lacked AMF spores, and only 50% exhibited root colonization. This study offers new insights into the role of AMF in rice cultivation. CONCLUSIONS: The AMF diversity and root colonization in relation to environmental variables underscores their significant impact on AMF in particular crop fields.

Adherence to the EAT-Lancet sustainable diet and ultra-processed food consumption: findings from a nationwide population-based study in Brazil.

OBJECTIVE: To evaluate the association between ultra-processed food consumption and adherence to the EAT-Lancet diet in a representative sample of the Brazilian population. DESIGN: The study used data from the Brazilian National Dietary Survey 2017-2018 and employed linear regression models to evaluate the association between ultra-processed food consumption and adherence to the EAT-Lancet diet, as measured by the Nova food system and Planetary Health Diet Index (PHDI), respectively. SETTING: Nationally representative sample of the Brazilian population. PARTICIPANTS: The study included 46 164 Brazilians ≥ 10 years old. RESULTS: The average PHDI total score was 45·9 points (95 % CI 45·6, 46·1). The ultra-processed food consumption was, with dose-response, inversely associated with the adherence to the EAT-Lancet diet. The PHDI total score was 5·38 points lower (95 % CI -6·01, -4·75) in individuals in the highest quintile of consumption of ultra-processed foods, as compared to those in the first quintile. The PHDI score was also inversely associated with the share of processed culinary ingredients and processed foods and positively associated with the share of unprocessed or minimally processed foods. CONCLUSIONS: Our study showed an inverse relationship between the consumption of ultra-processed foods and the adherence to a healthy and sustainable diet.

Sparkling Synergy: Enhancing Hydrogen Evolution with a Mesoporous CoP/FeP Interface.

The reaction kinetics is predominantly determined by the surface and interface engineering of electrocatalysts. Herein, we demonstrate the growth of cobalt monophosphide and iron monophosphide (CoP/FeP) with an effective solid interface. The surface of CoP/FeP is mesoporous, which is obtained by phosphidizing mesoporous CoFe2O4. The CoP/FeP electrode exhibits substantially superior hydrogen evolution reaction (HER) performance compared to CoP and FeP. The overpotentials (η) required to generate 10 mA cm-2 are determined to be around 98 mVRHE (CoP/FeP), 220 mVRHE (FeP), and 265 mVRHE (CoP) in an acidic electrolyte. The exchange current density and Tafel slopes suggest that CoP/FeP has better redox properties and kinetic abilities compared to FeP and CoP. Furthermore, the CoP/FeP electrode exhibits reduced electrochemical impedance and superior surface charge transport characteristics in comparison to both the CoP and FeP electrodes. In addition to having a greater number of catalytically active sites, the turnover frequency of CoP/FeP is approximately 2 and 5 times higher than that of FeP and CoP, respectively. The CoP/FeP electrode maintains a consistent current density of around 25 mA cm-2 for a continuous period of 24 h during the HER, attesting to the excellent durability of the CoP/FeP electrode. In addition, a relationship between differential hydrogen adsorption energy (ΔEH), the corresponding Gibbs free energy change (ΔGH), and the hydrogen coverage on distinct surfaces, namely, CoP, FeP, and CoP/FeP, is established. The calculation findings show that the CoP/FeP surface, which is predominantly exposed with CoP, exhibits the highest catalytic potential for the HER. The estimation of the specific HER activity of the electrodes, normalized to the electrochemically active surface area, corroborates the calculation findings.

Exploring marine compounds as potential biocontrol agents against powdery mildew for agricultural sustainability: a computer-based approach.

Powdery mildew is a pervasive fungal disease causing significant economic losses globally. Continuous use of synthetic fungicides has led to environmental concerns and resistant fungal strains. This study explores marine-derived cephalostatins from the South African Natural Compounds Database as novel fungicidal agents for managing powdery mildew. Using molecular docking techniques, we investigated the interaction between selected cephalostatins and critical proteins involved in powdery mildew pathogenesis. Compounds were selected based on drug-likeness and bioactivity, adhering to Lipinski's Rule of Five. Molecular interactions, binding affinities, and stability were analysed using AutoDock Vina, PyMOL, and Discovery Studio. Cephalostatin 17 exhibited the highest binding affinity (-10.4 kcal/mol), indicating strong potential for inhibiting fungal growth through significant hydrogen bonding and hydrophobic interactions. The study's primary limitation is the reliance on computational predictions, necessitating experimental validation. Cephalostatin 17 stands out as a promising candidate for sustainable agricultural practices.

Meat and dairy consumption in Scottish adults: insights from a national survey.

BACKGROUND: Reducing meat and dairy consumption has been advocated for environmental benefits. This study aimed to better understand meat and dairy consumption in a population with high intakes. METHODS: Dietary data were obtained from up to two online 24-h dietary recalls of adults (≥16 years) in the 2021 Scottish Health Survey, a nationally representative, repeated cross-sectional survey. The contribution of food groups to meat and dairy intake and the nutritional contributions of meat and milk products to intake of 28 nutrients were examined. Weighted mean (95% confidence interval [CI]) daily intakes were reported per capita, overall, and by demographic subgroups (age, gender and Scottish Index of Multiple Deprivation). RESULTS: Mean daily intakes of total meat and dairy were 80.4 g (95% CI 77.1-83.7) and 238.6 g (95% CI 228.9-248.3) per capita, respectively. Chicken dishes, beef dishes and sandwiches were the primary contributors to meat intake, together accounting for 56.1% of meat consumed. Liquid milk accounted for 63.4% of the dairy consumed. Meat products were an important source of selenium and zinc (accounting for 26% and 25% of intake, respectively), whereas milk products were an important source of calcium (34%), iodine (38%) and vitamin A (25%). CONCLUSIONS: Although meat and dairy consumption in Scotland is high, a number of food groups contributed to meat intake, providing several opportunities to target for a reduction in line with climate change ambitions. However, careful attention is required for replacements to ensure Scottish diets are nutritionally adequate.

Navigating the sea level rise: Exploring the interplay of climate change, sea level rise, and coastal communities in india.

This research article investigates the intricate interplay between climate change, global sea level rise (SLR), and the impacts of sea level rise on the coastal regions of India. Through an interdisciplinary approach, this paper provides an overview of the global consequences of SLR on coastal communities, exploring economic, social, and environmental impacts on agriculture, communities, and coastal areas. The study examines the displacement of communities and its impact on food security, infrastructure, tourism, and ecological loss based on a comprehensive literature review. This paper emphasizes the sustainable preservation of coastal ecosystems and the development of climate-resilient infrastructure. This research aims to offer a detailed understanding of the evolving landscape of coastal livelihoods, providing valuable insights for adaptive strategies, policy formulation, and sustainable development. Ultimately, this article contributes to the scientific discourse by shedding light on the complex dynamics between climate change, SLR, and coastal communities, guiding efforts toward a resilient and sustainable future. The insights are drawn from secondary data resources, including books, scholarly journals, and reports from organizations such as the IPCC and NOAA. Based on a thorough review of the relevant literature, it critically examines the existing and potential consequences of sea level rise induced by climate change.

Windthrow in riparian buffers affects the water quality of freshwater ecosystems in the eastern Canadian boreal forest.

Despite the wide application of riparian buffers in the managed boreal forest, their long-term effectiveness as freshwater protection tools remains unknown. Here, we evaluate windthrow incidence in riparian buffers in the eastern Canadian boreal forest and determine the effect of windthrow on the water quality index of the adjacent freshwater ecosystems. We studied 40 sites-20 riparian buffers, aged 10 to 20 years after harvesting and 20 control sites within intact riparian environments-distributed among clay and sandy (esker) soils and black spruce (Picea mariana) and jack pine (Pinus banksiana) stands. We observed more windthrow in the harvested stands (36%) relative to the control sites (16%), regardless of substrate and species. We determined that the most important factors explaining windthrow were exposition, harvesting, aquatic environment size, and stand characteristics. These factors drive wind exposure, speed, and force, which determine post-harvest windthrow risk. Furthermore, windthrow negatively affected the water quality index of the adjacent aquatic systems, i.e., greater windthrow decreased the protective effect of the riparian buffer. We recommend increasing the use of partial harvest near riparian environments and adapting riparian buffers to site conditions to ensure the long-term protection of adjacent freshwater ecosystems.

Digital economy, technological progress, and carbon emissions in Chinese provinces.

The 2023 work report of the Chinese government underscores a pivotal transition towards a "dual-control" policy, prioritizing the management of carbon emissions. This study provides an in-depth analysis of the interplay between the digital economy, technological progress, and their impact on the total volume and intensity of carbon emissions across 30 Chinese provinces from 2013 to 2021. Our findings reveal that while the expansion of the digital economy and technological progress contribute to an increase in the total carbon emissions, they also markedly decrease carbon intensity, paving the way for sustainability. Additionally, the research uncovers the positive externalities of the digital economy on carbon emission intensity and the spillover effects of technological progress on both emissions and intensity. The integration of the digital economy in industrial restructuring and the uptake of green technologies are identified as instrumental in mitigating carbon emissions. These insights underscore the potential of policy strategies that leverage the digital economy and technological innovation to meet the "dual-control" policy objectives and foster sustainable development.

Fast, sensitive, and sustainable colorimetric detection of chlorogenic acid in artichoke waste material.

Caffeoylquinic acids (CQAs) are nutraceutical polyphenols highly represented in natural sources, including artichoke waste (AW). In this study a colorimetric method for rapid and sustainable detection of a 5-CQA isomer (Chlorogenic acid) in AW extract was developed by using alkaline Tris buffer (10 mmol L-1, pH 9) to generate a yellow color associated with 5- to 3-CQA isomerization reaction, as suggested by NMR and MS analyses. The strong absorbance at 360 nm was followed by standard UV-Vis methodology. The colorimetric assay was exploited for detection of 5-CQA into leaf extract from artichoke, obtaining a value of 15.2 ± 0.3 µg/mg of dry extract, in agreement with HPLC analysis (14.3 ± 0.7 µg/mg, 106 ± 2 % recovery) used as validation technique, with excellent linear correlation and precision (R2 = 0.9996, avRSD% = 3.2 %). The method is fast and selective, offering a valuable tool for nutraceuticals identification and food waste valorization.