Dry deposition of sulfate-containing particulate at the highway intersection, coastal and suburban areas.

ABSTRACT

Sulfate-containing aerosol (SCA) dry deposition at the highway intersection, coastal location, and suburban area in Taiwan were analyzed and compared. Sampling was accomplished with a surrogate surface technique. Samples particles were coated with barium chloride (BaCl(2)) in a vacuum evaporator and then exposed to a relative humidity of 85% for 2 h to form distinctive products of SCAs. Treated samples were examined by a scanning electron microscopy. SCA dry deposition fluxes were 10.2, 4.1, 3.4 microgm(-2)s(-1) and nonsulfate-containing aerosol (NSCA) dry deposition fluxes were 23.3, 8.2, 13.5 microgm(-2)s(-1) at the highway intersection, coastal, and suburban areas. At the highway intersection, both SCA and NSCA dry deposition fluxes were much higher than those at the other two sites. The dry deposition of particles was also analyzed with a traditional technique. The number median diameters (NMDs) of SCA were 0.41, 0.82, and 1.2 mum at the highway intersection, coastal, and suburban sites, respectively. The highway intersection site had a small NMD, which showed that most sulfate-containing deposited aerosols existed in fine diameter range. The mass median diameters (MMDs) of SCA were 8.8, 19.5, and 14.9 mum at the highway intersection, coastal, and suburban sites, which were much higher than NMDs. Average numbers of SCAs in total particulate were 33%, 33%, and 22% at the highway intersection, coastal and suburban areas Most deposited particulates were nonsulfate-containing at the three sampling sites. SCAs less than 10 mum contributed 29%, 8%, and 7% to the total dry deposition at the highway intersection, coastal, and suburban areas, respectively. The contribution of fine particulate was significantly higher at the highway intersection site.