A powerful chiral counteranion motif for asymmetric catalysis.
Angew Chem Int Ed Engl
; 48(24): 4363-6, 2009.
Article
em En
| MEDLINE
| ID: mdl-19437518
ABSTRACT
Room to swing a cat A chiral disulfonimide has been designed as a powerful new motif for asymmetric catalysis. As a first illustration, a highly efficient and enantioselective Mukaiyama aldol reaction has been developed (see scheme). The actual catalyst is proposed to be an N-silyl imide which is generated in situ.
Texto completo:
1
Base de dados:
MEDLINE
Assunto principal:
Sulfonas
/
Ânions
Idioma:
En
Ano de publicação:
2009
Tipo de documento:
Article