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Rapid assembly of vinigrol's unique carbocyclic skeleton.
Morton, Jason G M; Draghici, Cristian; Kwon, Laura D; Njardarson, Jon T.
Afiliação
  • Morton JG; Department of Chemistry and Chemical Biology, Baker Laboratory, Cornell University, Ithaca, New York 14853-1301, USA.
Org Lett ; 11(20): 4492-5, 2009 Oct 15.
Article em En | MEDLINE | ID: mdl-19728692
Detailed in this account are our efforts toward the total synthesis of vinigrol. A highly expedient and convergent synthetic approach made possible by the use of a strategic oxidative dearomatization reaction coupled with a series of ensuing substrate controlled transformations is discussed.
Assuntos

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Diterpenos Idioma: En Ano de publicação: 2009 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Diterpenos Idioma: En Ano de publicação: 2009 Tipo de documento: Article