Rare oxidation-state combinations and unusual structural motifs in hexanuclear Mn complexes using 2-pyridyloximate ligands.

Stoumpos, Constantinos C; Inglis, Ross; Roubeau, Olivier; Sartzi, Harikleia; Kitos, Alexandros A; Milios, Constantinos J; Aromí, Guillem; Tasiopoulos, Anastasios J; Nastopoulos, Vasilios; Brechin, Euan K; Perlepes, Spyros P

Stoumpos, Constantinos C; Inglis, Ross; Roubeau, Olivier; Sartzi, Harikleia; Kitos, Alexandros A; Milios, Constantinos J; Aromí, Guillem; Tasiopoulos, Anastasios J; Nastopoulos, Vasilios; Brechin, Euan K; Perlepes, Spyros P.

Afiliação

Stoumpos CC; Department of Chemistry, University of Patras, 265 04 Patras, Greece.

Inorg Chem ; 49(10): 4388-90, 2010 May 17.

Article em En | MEDLINE | ID: mdl-20392125

ABSTRACT

ABSTRACT

The use of phenyl-2-pyridyl ketone oxime and di-2-pyridyl ketone oxime in Mn chemistry has led to hexanuclear clusters with unprecedented (Mn(II)(4)Mn(III)Mn(IV)) or extremely rare (Mn(II)Mn(III)(5) and Mn(II)(3)Mn(III)(3)) metal oxidation-state combinations and uncommon structural motifs.

Texto completo

Imprimir

XML

PubMed Links

Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2010 Tipo de documento: Article

Texto completo

Imprimir

XML

PubMed Links

Buscar no Google

Texto completo: 1 Base de dados: MEDLINE Idioma: En Ano de publicação: 2010 Tipo de documento: Article