Your browser doesn't support javascript.
loading
Bulk modulus of a protein active-site mimic.
Leu, Bogdan M; Sage, J Timothy; Silvernail, Nathan J; Scheidt, W Robert; Alatas, Ahmet; Alp, Ercan E; Sturhahn, Wolfgang.
Afiliação
  • Leu BM; Advanced Photon Source, Argonne National Laboratory, Argonne, Illinois, United States. leu@aps.anl.gov
J Phys Chem B ; 115(15): 4469-73, 2011 Apr 21.
Article em En | MEDLINE | ID: mdl-21434623
Flexibility is an important property of porphyrins, both natural and synthetic. We applied two synchrotron-based techniques, nuclear resonance vibrational spectroscopy and inelastic X-ray scattering, to quantify this property by measuring the bulk modulus of a protein active-site mimic [chloro(octaethylporphyrinato)iron(III)] and the resilience of the iron environment. Their values are 6.95 ± 0.24 GPa and 15.4 ± 0.5 N/m, respectively.
Assuntos

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Porfirinas / Hemeproteínas Idioma: En Ano de publicação: 2011 Tipo de documento: Article

Texto completo: 1 Base de dados: MEDLINE Assunto principal: Porfirinas / Hemeproteínas Idioma: En Ano de publicação: 2011 Tipo de documento: Article