Bis(propane-1,3-diaminium) hexa-fluoridoferrate(III) fluoride trihydrate.
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 6): m702-3, 2010 May 22.
Article
em En
| MEDLINE
| ID: mdl-21579337
ABSTRACT
The asymmetric unit of the title iron hybrid fluoride, (C(3)H(12)N(2))(2)[FeF(6)]F·3H(2)O, contains two propane-1,3-diamin-ium [(H(2)dap)(2+)] cations, an octa-hedral [FeF(6)](3-) anion, an isolated F(-) anion and three water mol-ecules of solvation. Each [FeF(6)](3-) anion is surrounded by four separate hydrogen-bonded water mol-ecules in the equatorial sites and by five separate aminium cation donor groups. The axial F atoms are only involved in N-Hâ¯F hydrogen bonds, resulting in a three-dimensional structure.
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MEDLINE
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En
Ano de publicação:
2010
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Article