Dicylopenta-dien-yl[4-(4-vinyl-benz-yloxy)pyridine-2,6-dicarboxyl-ato]titanium(IV) monohydrate.
Acta Crystallogr Sect E Struct Rep Online
; 66(Pt 7): m769-70, 2010 Jun 16.
Article
em En
| MEDLINE
| ID: mdl-21587700
ABSTRACT
The title compound, [Ti(C(5)H(5))(2)(C(16)H(11)NO(5))]·H(2)O, exhibits a titanocene unit coordinated to a styrene-substituted pyridine-2,6-dicarboxyl-ate ligand synthesized for use as a monomer for polymerization or copolymerization yielding metallocene-containing polymers. The compound crystallized as a monohydrate and the solvent water mol-ecule forms strong O-Hâ¯O hydrogen bonds with the carboxyl-ate O atoms of the Ti complex, which play an important role in the connection of adjacent mol-ecules. In addition, weak inter-molecular C-Hâ¯O hydrogen bonds also contribute to the crystal packing arrangement.
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MEDLINE
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En
Ano de publicação:
2010
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Article